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ID:33362962
大小:2.81 MB
页数:73页
时间:2019-02-25
《稀土对低碳钢耐大气腐蚀性能影响的研究》由会员上传分享,免费在线阅读,更多相关内容在学术论文-天天文库。
1、昆明理工大举硕士学位论文摘要稀土元素可以提高钢的耐大气腐蚀性能,但其中的作用机理尚不十分清楚,例如稀土对锈层形成过程、对锈层结构的影响及稀土在腐蚀产物中的最终存在形式等问题。为进一步研究稀土对钢耐大气腐蚀性能影响及探讨稀土提高钢耐大气腐蚀性机理,本文采用四种不同稀土含量的低碳钢,利用实验室加速腐蚀试验一周期浸泡试验和盐雾试验方法和电化学试验方法,观察和分析了不同加速腐蚀试验时问试验钢的锈层形貌、锈层构成、锈层致密性、腐蚀后稀土的存在方式和计算了不同加速腐蚀试验时间试验钢的腐蚀率,并测量和计算了未经加速腐蚀试验的试验钢的腐蚀率。研究
2、结果表明:①在模拟C1-环境中,稀土对低碳钢的耐蚀性能影响不显著;仅高稀土含量低碳钢(0.12%RE)的耐蚀性一直好于不含稀土低碳钢(0.0%RE)。四种试验钢锈层非常疏松、粘附性小、保护性很小。②在模拟工业大气环境中,稀I一能明显地提高低碳钢的耐大气腐蚀性能。经288小时周期浸泡试验后,高稀土含量低碳钢(0.12%RE)腐蚀率比无稀土低碳钢(o.0%RE)腐蚀率降低32%。③在模拟.[业大气环境中,稀土促进Y.FeOOH/y—Fe203向稳定的保护性a.FeOOH转变,从而提高了锈层的粘附性及致密性。关键词:稀士:低碳钢:耐大气
3、腐蚀昆明理工大学硕士学位论文RareEarth(RE)elementscouldimprovetheatmosphericcorrosionresistancepropertiesofsteels,buttheeffectivemechanismwasnotclearandtherewerenotyetenoughevidencetOshowhowtheREtoaffectontheformingprocessandthestructureoftherustlayer,andwhatistheultimatestateofREin
4、therustlayer.Inthispaper,indooracceleratingcorrosiontest--alternateimmersioncorrosiontestandsaltspraytest,andelectrochemistrytestweredesignedtoinvestigatetheroleofREonimprovingatmosphericcorrosionresistanceofsteelsandtoresearchthemechanismwhytheadditionofREcouldimprov
5、eatmosphericcorrosionresistanceofsteels.Themorphologies,composingandcompactnessoftherustlayerhavebeenobservedandanalyzedafterdifferenttimeofindooracceleratingcorrosiontest,thecorrosionratehasbeencalculatedafterdifferenttimeofindooracceleratingcorrosiontest,andthecorro
6、sionrateoftestedsteelsatnon—acceleratingcorrosiontesthasbeentestedandcalculatedtOprovidecomparisonandanalysis.TheresearchresuItshaveshownthat:①InCI。environmentsimulationcondition,theadditionofREinsteelscouldnotevidentlyimprovethecorrosionresistanceofmildsteels,whileth
7、ecorrosionresistanceofmildsteelcontaining0.12%REwasalwaysbetterthanthatofmildsteelwithoutREafterdifferenttimesfogcorrosiontest.Onthiscondition,therustlayeroftestedsteelswasveryloose,lessadhesiveandnon—protective②Inindustrialenvironmentsimulationcondition,theadditionof
8、REcouldremarkably'improveatmosphericcorrosionresistanceofmildsteels,andthecorrosionrateofmildsteelcontainingO.12%REwas32%low
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