脱硫石油焦渣性能与应用分析

脱硫石油焦渣性能与应用分析

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时间:2019-02-01

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1、AbstractPetroleumcoke,produced嬲by-productsinPetrochemicalindustry,canbedividedintohigh-sulfur(above3percent)andlow-sulfur(1essthan3percent).Howtoutilizethehigh—sulfurpetroleumcokecleanly,andcreateeconomicbenefitsaregenerallyconcemedbydomesticPetrochemicalindustry.Inrecentyears,thecir

2、culatingfluidizedbedtechnologydevelopsrapidly.Thistechnologyallows11igh·sulfurpetroleumcokeasanefficient,low-pollutionfuel.TheSO.calleddesulfurizationpetroleumcokeresiduesistheformationofCaS04andothercomburentmixturewithoutsulfurelementwhichisobtainedbyhi曲sulfurpetroleumcokeandlimest

3、onewhoareburnedintheboiler.ThesubjectisbasedOlltheprogramoftheresearchoftheapplicationofmilledhigh-sulfurpetroleumcokedesulfurationresidues,andmainlyincludesthefollowingcomponents:(1)Basicpropertiesofpetroleumcokedesulfurationresidues,includingchemicalcompositon,mineralconstituent,no

4、rmalconsistencywaterconsumptionandsettingtime(2)ResearchtheHydrationmechanismofdesulfurizedpetroleumcokedesulfurationresiduesatdifferenttemperatures,andofautoclavedaeratedconcrete.(3)Preparingtheaeratedconcretewitllpetroleumcokedesulfurationresiduesinsteadoflime笛calcareousmaterialsan

5、dflyashandpulverizedsand硒siliceousmaterials.Firstly,designmatrixtest,andelecthighs仃engthratiofurthertodohairairtest.Secondly,discussthestrengthoftheratioofwaterandaluminumpowdercontent.Finally,wediscussthestrengthofaeratedconcreteblock,whicharepreparedbymixing晰tllsodiumandheatingthes

6、lurry.(4)Selectthegoodtestradiotoconductacostanalysis,andcleartheeconomicviabilityofthepreparationofaeratedconcrete晰tlldesulfurizationofpetroleumcokeresidue.Theresultsare弱follows:(1)thecontentofCaOinpetroleumcokedesulfurationresiduesisreachupto55-60percentandCaS04isreachupto35-40perc

7、ent.(2)TheDigestionrateisfastandcallreachtheMaximumtemperaturein3minutes.(3)Atdifferenttemperature,CaOexitinginpetroleumcokedesulfurationresiduescanturnintoCa(OH)2aftermixedwithwater,onlyat20"CcuringconditionsCanasmallpartCaS04hydrateintoCaS04。2H20.(4)Intheautoclavecuringconditions,t

8、herearelarge

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