fundamentals of organic chemistry_6th_2006

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1、StructuresofSomeCommonFunctionalGroupsNameStructureaNameendingExampleAlkene-eneH2CUCH2(doublebond)CCEtheneAlkyneXCmCX-yneHCqCH(triplebond)EthyneAreneNone(aromaticring)BenzeneHalideXNoneCH3ClCChloromethane(X
F,Cl,Br,I)AlcoholOH-olCH3OHCMethanolEtherOetherCH3OCH3CCDim

2、ethyletherOphosphateCHOPO2
Monophosphate33MethylphosphateCPOO
O
DiphosphateOOdiphosphateCH3OP2O63
MethyldiphosphateCPPOOO
O
O
Amine-amineCH3NH2MethylamineNCImineNNoneNH(Schiffbase)CCH3CCH3CCAcetoneimineNitrileXCqN-nitrileCH3CmNEthanenitrileThiolSH-thiolCH3SHCMethane

3、thiolaThebondswhoseconnectionsaren’tspecifiedareassumedtobeattachedtocarbonorhydrogenatomsintherestofthemolecule.NameStructureaNameendingExampleSulfideSsulfideCH3SCH3CCDimethylsulfideDisulfideSCdisulfideCH3SSCH3CSDimethyldisulfide
SulfoxideO
sulfoxideOSCH3SCH3CCDimethyls

4、ulfoxideAldehydeO-alOCCH3CHHEthanalKetoneO-oneOCCH3CCH3CCPropanoneCarboxylicacidO-oicacidOCCH3COHCOHEthanoicacidEsterO-oateOCCCH3COCH3COMethylethanoateThioesterO-thioateOCCCH3CSCH3CSMethylethanethioateAmideO-amideOCCH3CNH2CNEthanamideAcidchlorideO-oylchlorideOCCH3CC

5、lCClEthanoylchloridewww.thomsonedu.comwww.thomsonedu.comistheWorldWideWebsiteforThomsonBrooks/Coleandisyourdirectsourcetodozensofonlineresources.Atwww.thomsonedu.comyoucanfindoutaboutsupplements,demonstrationsoftware,andstudentresources.Youcanalsosende-mailtomanyofou

6、rauthorsandpreviewnewpublicationsandexcitingnewtechnologies.www.thomsonedu.comChangingthewaytheworldlearns®ThispageintentionallyleftblankFundamentalsofOrganicChemistrySixthEditionJohnMcMurryCornellUniversityEricSimanekTexasA&MUniversityAustralia•Canada•Mexico•Singap

7、ore•SpainUnitedKingdom•UnitedStatesFundamentalsofOrganicChemistry,SixthEditionJohnMcMurryandEricSimanekPublisher,PhysicalSciences:DavidHarrisPermissionsEditor:JooheeLeeSeniorDevelopmentEditor:SandraKiselicaProductionService:GraphicWorldInc.AssistantEditor:EllenBitte

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