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1、ThermodynamicsofCrystallineStates.MinoruFujimotoThermodynamicsofCrystallineStatesMinoruFujimotoDepartmentofPhysicsUniversityofGuelphGuelph,ONN1G2W1,Canadaminorufuji@rogers.comISBN978-1-4419-6687-2e-ISBN978-1-4419-6688-9DOI10.1007/978-1-4419-6688-9SpringerNewYorkHeidelbergDordrechtLondonL
2、ibraryofCongressControlNumber:2010935845#SpringerScienceþBusinessMedia,LLC2010Allrightsreserved.Thisworkmaynotbetranslatedorcopiedinwholeorinpartwithoutthewrittenpermissionofthepublisher(SpringerScience+BusinessMedia,LLC,233SpringStreet,NewYork,NY10013,USA),exceptforbriefexcerptsinconnec
3、tionwithreviewsorscholarlyanalysis.Useinconnectionwithanyformofinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilarmethodologynowknownorhereafterdevelopedisforbidden.Theuseinthispublicationoftradenames,trademarks,servicemarks,andsimilarterms,evenif
4、theyarenotidentifiedassuch,isnottobetakenasanexpressionofopinionastowhetherornottheyaresubjecttoproprietaryrights.Printedonacid-freepaperSpringerispartofSpringerScience+BusinessMedia(www.springer.com)PrefaceOriginatedfromstudiesonsteamengines,thermodynamicsisformulatedtradition-allyforhom
5、ogeneousmaterials.Applyingtocondensedmattershowever,lawsofthermodynamicshavetobeevaluatedwithrespecttothestructuraldetail.Follow-ingafterKirkwood’schemicalthermodynamics,theauthor’sattemptistodiscusslatticedynamicsincrystallinestatesinlightofthetraditionallaws.Itisnotedthatlatticesymmetr
6、yremainsasimplicitincrystallinestatesifassumedashomoge-neous,whereasdeformedcrystalswithdisruptedsymmetryarenotnecessarilystableandinhomogeneous,exhibitingmesoscopicproperties.Inthiscontext,thelatticedynamicsinuniformcrystallinestatesshouldaccordinglyberevised.Althoughmostlypresumptivein
7、theliterature,suchattemptsshouldbeformulatedwithfundamentalprinciplesformodernthermodynamics.Ihaveselectedstructuralchangesandsuperconductingtransitionsforthisbooktodiscussasbasicphenome-naincrystalsinthermalenvironment.BornandHuanghavelaidgroundforthermodynamicsofcrystal
