chemical-thermodynamics

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1、Chemical Thermodynamics Leo Lue Download free books at LeoLueChemicalThermodynamics2ChemicalThermodynamics©2009LeoLue&VentusPublishingApSISBN978-87-7681-497-73ChemicalThermodynamicsContentsContents1Introduction81.1Basicconcepts81.1.1Statefunctionversuspathfunction81.1.2Intensivepropertyve

2、rsusextensiveproperty81.2Briefreviewofthermodynamics81.2.1Thefirstlawofthermodynamics81.2.2Thesecondlawofthermodynamics91.3Thefundamentalequationofthermodynamics91.4Thecalculusofthermodynamics111.5Opensystems131.6Legendretransformsandfreeenergies142Singlecomponentsystems172.1Generalphasebe

3、havior172.2Conditionsforphaseequilibrium182.3TheClapeyronequation20what‘smissinginthisequation?YoucouldbeoneofourfuturetalentsPleaseclicktheadvertmaeRsKinteRnationaLteChnoLogY&sCienCePRogRammeAreyouabouttograduateasanengineerorgeoscientist?Orhaveyoualreadygraduated?Ifso,theremaybeanexciti

4、ngfutureforyouwithA.P.Moller-Maersk.www.maersk.com/mitas4ChemicalThermodynamicsContents3Multicomponentsystems223.1Thermodynamicsofmulticomponentsystems223.1.1Thefundamentalequationofthermodynamics223.1.2Phaseequilibria223.1.3Gibbsphaserule233.2Binarymixtures253.2.1Vapor-liquidequilibrium2

5、53.2.2Liquid-liquidequilibria303.2.3Vapor-liquid-liquidequilibria313.3Ternarymixtures344Theidealsolutionmodel364.1Definitionoftheidealsolutionmodel364.2DerivationofRaoult’slaw375Partialmolarproperties405.1Definition405.2Relationshipbetweentotalpropertiesandpartialmolarproperties415.3Propert

6、ieschangesonmixing435.4Graphicalrepresentationforbinarysystems43Pleaseclicktheadvertwww.job.oticon.dk5ChemicalThermodynamicsContents6Nonidealsolutions476.1DeviationsfromRaoult’slawandtheactivitycoefficient476.2ModifiedRaoult’slaw486.3Empiricalactivitycoefficientmodels516.4TheGibbs-Duhemequat

7、ion526.5Azeotropicsystems537Stability567.1Introduction567.2Liquid-liquidequilibrium608Solid-liquidequilibrium628.1Introduction628.2Phasebehavior628.3Conditionsforequilibrium629GassolubilityandHenry’slaw669.1Henry’slaw669.2Activitycoefficients67Experiencetheforcesofwi