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1、AnalyticalElectrochemistry,SecondEdition.JosephWangCopyright#2000Wiley-VCHISBNs:0-471-28272-3(Hardback);0-471-22823-0(Electronic)ANALYTICALELECTROCHEMISTRYSECONDEDITIONANALYTICALELECTROCHEMISTRYSecondEditionJOSEPHWANGAJOHNWILEY&SONS,INC.,PUBLICATIONNewYo
2、rk=Chichester=Weinheim=Brisbane=Singapore=TorontoCopyright#2001byWiley-VCH.Allrightsreserved.Nopartofthispublicationmaybereproduced,storedinaretrievalsystemortransmittedinanyformorbyanymeans,electronicormechanical,includinguploading,downloading,printing,
3、decompiling,recordingorotherwise,exceptaspermittedunderSections107or108ofthe1976UnitedStatesCopyrightAct,withoutthepriorwrittenpermissionofthePublisher.RequeststothePublisherforpermissionshouldbeaddressedtothePermissionsDepartment,JohnWiley&Sons,Inc.,605
4、ThirdAvenue,NewYork,NY10158-0012,(212)850-6011,fax(212)850-6008,E-Mail:PERMREQ@WILEY.COM.Thispublicationisdesignedtoprovideaccurateandauthoritativeinformationinregardtothesubjectmattercovered.Itissoldwiththeunderstandingthatthepublisherisnotengagedinrend
5、eringprofessionalservices.Ifprofessionaladviceorotherexpertassistanceisrequired,theservicesofacompetentprofessionalpersonshouldbesought.ISBN0-471-22823-0.ThistitleisalsoavailableinprintasISBN0-471-28272-3.FormoreinformationaboutWileyproducts,visitourwebs
6、iteatwww.Wiley.com.Dedicatedtothememoryofmyparents,ElkaandMosheWangCONTENTSPREFACExiABBREVIATIONSANDSYMBOLSxiii1FUNDAMENTALCONCEPTS11-1WhyElectroanalysis?=11-2FaradaicProcesses=31-2.1MassTransport-ControlledReactions=41-2.1.1PotentialStepExperiment=71-2.
7、1.2Potential-SweepExperiments=81-2.2ReactionsControlledbytheRateofElectronTransfer=111-2.2.1ActivatedComplexTheory=161-3TheElectricalDoubleLayer=181-4ElectrocapillaryEffect=22SupplementaryReading=25References=26Questions=262STUDYOFELECTRODEREACTIONS282-1
8、CyclicVoltammetry=282-1.1DataInterpretation=30viiviiiCONTENTS2-1.1.1ReversibleSystems=312-1.1.2IrreversibleandQuasi-ReversibleSystems=322-1.2StudyofReactionMechanisms=332-1.3StudyofAdsorptionProcesses=362-1.4QuantitativeAp
