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1、TheClaisenRearrangementEditedbyMartinHiersemannandUdoNubbemeyer1807–2007KnowledgeforGenerationsEachgenerationhasitsuniqueneedsandaspirations.WhenCharlesWileyfirstopenedhissmallprintingshopinlowerManhattanin1807,itwasagenerationofboundlesspotentialsearchingforanidentity.Andwewerethere,helping
2、todefineanewAmericanliterarytradition.Overhalfacenturylater,inthemidstoftheSecondIndustrialRevolution,itwasagenerationfocusedonbuildingthefuture.Onceagain,wewerethere,supplyingthecriticalscientific,technical,andengineeringknowledgethathelpedframetheworld.Throughoutthe20thCentury,andintothene
3、wmillennium,nationsbegantoreachoutbeyondtheirownbordersandanewinternationalcommunitywasborn.Wileywasthere,ex-pandingitsoperationsaroundtheworldtoenableaglobalexchangeofideas,opinions,andknow-how.For200years,Wileyhasbeenanintegralpartofeachgenerationsjourney,enablingtheflowofinformationandund
4、erstandingnecessarytomeettheirneedsandfulfilltheiraspirations.Today,boldnewtechnologiesarechangingthewayweliveandlearn.Wileywillbethere,providingyouthemust-haveknowledgeyouneedtoimaginenewworlds,newpossibilities,andnewoppor-tunities.Generationscomeandgo,butyoucanalwayscountonWileytoprovideyo
5、utheknowledgeyouneed,whenandwhereyouneedit!WilliamJ.PescePeterBoothWileyPresidentandChiefExecutiveOfficerChairmanoftheBoardTheClaisenRearrangementMethodsandApplicationsEditedbyMartinHiersemannandUdoNubbemeyerEditors:&AllbookspublishedbyWiley-VCHarecarefullyproduced.Nevertheless,authors,edito
6、rs,andPriv.-Doz.Dr.MartinHiersemannpublisherdonotwarranttheinformationcon-InstituteofOrganicChemistrytainedinthesebooks,includingthisbook,tobeUniversityofDortmundfreeoferrors.ReadersareadvisedtokeepinmindOtto-Hahn-Strasse6thatstatements,data,illustrations,procedural44227Dortmunddetailsorothe
7、ritemsmayinadvertentlybeGermanyinaccurate.LibraryofCongressCardNo.:appliedforProf.Dr.UdoNubbemeyerBritishLibraryCataloguing-in-PublicationDataInstituteofOrganicChemistryAcataloguerecordforthisbookisavailableUniversityofMainzfromtheBritishLibraryDue