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1、淡江大學96學年度第1學期課程教學計畫表(格式二)壹、科目名稱：S.T.inAdv.Org.Chem.,ThrMolecularOrbitalsandTheirApplicationtoOrganicChemicalReactions貳、授課老師：Lin,Yun-shan參、開課系所班級：StudentsforPh.D.andM.S.Programs肆、必選修：election伍、學分數：3陸、先修科目：OrganicandPhysicalChemistry柒、教學內容及進度：I.InteractionofTwoAtomicOrbitalsonDiffe
2、rentCenters1)Basicapproximations2)ConstructionofMOs3)Applicationtosomesimplediatomicmolecules4)Overlapandsymmetry5)ApplicationofsymmetryideastosomepolyatomicmoleculesII.TheFragmentOrbitalMethod;ApplicationofSomeModelSystems1)Molecularorbitalsofsomemodels,Hn2)Influenceofelectonega
3、tivityontheformandenergyoftheMol.OrbitalsIII.InteractionsBetweenTwoFragmentOrbitals:LinearAH2,TrigonalAH3,andTetrahedralAH4IV.InteractionsBetweenThreeFragments:AH,BentAH2andPyramidalAH31)Rulesfortheinteractionofthreeorbitals2)ElectronicstructureofAHmolecules3)BentAH2molecules4)Py
4、ramidalAH3moleclulesV.InteractionsBetweenFourFragmentOrbitals:ThediatomicmoleculesA2&ABVI.LargeMolecules1)MOsofacetylene,ethyleneandethane2)Conjugatedpolenes:allyl,butadiene,cyclopropenyl,cyclobutadieneandbenzene1)Aromatic,antiaromaticcompoundsandHuckelruleVII.OrbitalCorrelationD
5、iagrams:TheModelSystemsH3+andH3-VIII.GeometryofAH2andAH3MoleculesIX.MolecularGeometryUsingFragmentMolecularOrbitalsX.IntroductiontoStudyofChemicalReactivity1)Thefrontierorbitalapproximation2)Cycloadditionreactions3)Ionicreactionsa)Nucleophilicadditionreactionsb)Displacementreacti
6、onsi)Nucleophilicsubstitutionii)Electrophilicsubstitution捌、授課方式：LectureandDiscussion玖、教學設備：Projector拾、教材課本：YvesJean,F.Volatron&J.Burdett,AnIntroductiontoMolecularOrbitals,OxfordUniv.Press,NewYork,1993拾壹、參考書籍：1)T.A.Albright,J.K.Burdett&M.H.Whangbo,OrbialInteractionsinChemistry,Joh
7、nWileyandSons,NewYork19852)ArviHouk,OrbitalInteractionTheoryofOrganicChemistry,JohnWiley&Sons,NewYork19943)JohnM.Tedder&AnthonyNechvatal,PictorialOrbitalTheory,Pitman,London1985拾貳、成績考核方式：平時成績：50％HomeExercise期中考成績：％期末考成績：50％Take-homeExamination讀書報告：％其他（）：％拾參、備考：1.本表格式請參考使用，教學計畫表格有
8、兩種，授課教師可至教務處首頁「表格下載」中取得，任擇一種使用。2.自製格式請具備
