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ID:28712308
大小:13.60 MB
页数:56页
时间:2018-12-13
《南四湖水源水基于臭氧氧化的溴酸盐生成及控制研究-市政工程专业毕业论文》由会员上传分享,免费在线阅读,更多相关内容在学术论文-天天文库。
1、山东建筑大学硕士学位论文影响,其中长时间吸附时,水中Br能与Br03’产生竞争吸附,使GAC对Br03"的吸附量下降,且Br_浓度越高,GAC对Br03的吸附量越低。pH值对GAC吸附Br03"的影响较大,低pH值条件下其吸附效果较高pH值条件下好。再者GAC吸附过程中,DOC能与Br03"产生竞争吸附,减少其对Br03的吸附。关键词:臭氧,南四湖,Br03。,C12-NH3臭氧氧化,活性炭吸附万方数据山东建筑大学硕士学位论文ThebromatecontrolofNansiLakebasedonozonationTUZonghui(MunicipalEngineerin
2、g)DirectedbyLIUJianguangprofessorABSTRACTOzonebiologicalactivatedcarbon(03一BAC)asanefficienttechnologyfordrinkingwatertreatmentiswidelyusedindomesticwaterplant.Butitmayproducecarcinogenicbromateinozoneoxidationprocessduringthewaterinthehighbromideconcentration,whichneedstobesolvedurgentl
3、yatpresent.TheinfluencefactorsofbromateformationindeionizedwaterandNansiLakeinozoneoxidationprocesswereinvestigatedinthestudy.Andthepathwayofbromateformationwereproposedinozoneoxidationprocess.ThecontrolmechanismofbromateformationduringozonationofNansiLakeWaterwereinvestigatedonthebasiso
4、fC12-NH3process.Andthetreatmenteffectofactivatedcarbononbromategeneratedwereinvestigated.TheresultsshowedthatItexertatremendousinfluenceofbromationformationindifferentwaterquality,whichmayinhibitthebromateformationorpromoteit.Andthesamekindofmaterialindifferentconcentrationshavedifferent
5、effectonbromatedformation.HumicacidinwaterandH202/03molarratiohasgreatinfluenceonbromateformation.Theresultsshowedthatwithouthumicacid,H202couldpromotebromateformationduringH202/03molarratiowaslessthan5:1,andthepromotioneffectfirstincreasesandthendecreases.ThevalueofH202/03wascanmosteffe
6、ctivelypromotethebromateformation.Nevertheless,thevalueofH202/03wasgreaterthan6:1,H202couldinhibitthebromatedformation.Ozonationaloneinthepresenceofhumicacid,ItpromotedthebromateformationduringtheconcentrationofDOCwaslmg‘L~.ItcouldinhibitthegenerationofbromateduringtheconcentrationofDOCw
7、asmorethan2mg。L~(including2mg’L‘1).InH202/03oxidationinthepresenceofhumicacid,LowconcentrationofH202couldinhibitthebromateformation.ItCanpromotetlleformationofBr03‘duringH202/03molarratiowaslessthan1undertheconditionthatwithouthumicacidandammoniaconcentrationwas0.3mg·L~.万
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