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ID:17367530
大小:4.42 MB
页数:66页
时间:2018-08-30
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1、Chapter1FundamentalConceptsofCrystal11)DefinitionofCrystal1-1.BasicConceptsofCrystalWhatisCrystal?CrystalandAmorphous2Peoplerealizedthattherearetwokindsofmineralinnature:CrystalandAmorphous.Aretheresomecommonnessforcrystals?Regularexternalshapes,flat-geometricfaceThecrystalfirstlyfoundwasquart
2、zwithregularshape.Quartzwithgeometricalpolyhedronshapewascalledascrystal.Quartz3Later,allsolidswithgeometricalpolyhedronshapeweredefinedcrystal,suchassalt,calcite,magnetite.SaltCalcitemagnetiteRuby/CorundumDiamondZircon4SaltQuartzBerylRedBeryl5Thebuildingblocksofthesetwoareidentical,butdiffere
3、ntcrystalfacesaredevelopedCrystalStructureCleavingacrystalofrocksalt6Theexternalappearanceofcrystalsareallcharacterizedbyflatboundingplaneswhichintersectatcharacteristicangles.Whymanyroundedstonesandman-madecastsolidobjectswithnoexternalevidenceareobserved?Question:78DefinitionofcrystalCrystal
4、sarebuiltupofregulararrangementsofatoms,moleculesorionsinthreedimensions.晶体是内部质点在三维空间呈周期性重复排列的固体;或者说,晶体是具有格子构造的固体。82)SpaceLatticeandEquivalentPointsEquivalentPoint:IdenticalSurroundingsthegroupingoflatticepointsaboutanygivenpointisidenticaltothegroupingaboutanyotherpointinthelattice.9Equivalen
5、tPoints,SpaceLatticeperiodicarrayofpointsinthreedimension——SpaceLatticeLatticePointsEquivalentPoint:Identicalpositionandidenticalsurroundingi.e.Cl-center、Na+center、betweenCl-&Na+Geometricpoint,NoweightandsizeSpacelatticewith3Dperiodrepeatingpatternisbuiltbyabstractionequivalentpointincrystalst
6、ructure,whichshows.10LatticeLattice=Aninfinitearrayofpointsinspace,inwhicheachpointhasidenticalsurroundingstoallothers.ItcanbedescribedbyassociatingwitheachlatticepointagroupofatomscalledtheMotif(Basis)CrystalStructure=Theperiodicarrangementofatomsinthecrystal.11Lattice:Periodicrepeatingarray?
7、=?=12Lattice,Basis,CrystalStructureDon'tmixupatomswithlatticepointsLatticepointsareinfinitesimalpointsinspaceAtomsarephysicalobjectsLatticePointsdonotnecessarilylieatthecentreofatoms13DifferencesofLatticeandCrystalStructureLatticeAnarra
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