介孔材料(mesoporous material)

介孔材料(mesoporous material)

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时间:2018-08-05

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1、介孔材料(Mesoporousmaterial)classificationAccordingtotheclassificationofchemicalcomposition,mesoporousmaterialscangenerallybedividedintotwomajorcategories:siliconandnonsilicon.1.siliconbasedmesoporousmaterialshavenarrowporesizedistribution,regularporestructureandmaturetechnology.Siliconmaterialsare

2、availableforcatalysis,separationandpurification,drugencapsulation,slowrelease,gassensingandotherfields.Siliconbasedmaterialscanbedividedintotwogroupsaccordingtopuresiliconandotherelements.Theclassificationcanbecarriedoutaccordingtothekindsofdopedelementsandthenumberofdifferentelements.Heteroato

3、mdopingcanberegardedasheteroatominsteadofsiliconatoms,introducingdifferentheteroatomswillbringmanynewpropertiestothematerial,suchasstability,changesofhydrophilichydrophobicpropertiesandthechangeofcatalyticactivitychangeandsoon.2.nonsiliconmesoporousmaterialsmainlyincludetransitionmetaloxides,ph

4、osphatesandsulfides.Becauseoftheirexistenceofvariablevalencestates,itispossibletoopennewapplicationfieldsformesoporousmaterialsanddemonstratethepotentialapplicationsofsilicon-basedmesoporousmaterials.Forexample:aluminumphosphatemolecularsievePmaterialshavebeenreplacedbySiaftertheformationofsili

5、conaluminiumphosphate(silicon-aluminophosphate,SAPOs),aluminumphosphateintroducedtwovalentmetalinthearchitecture(metal-substitutedAIPOsMAPOs)hasbeenwidelyusedinadsorption,catalyst,acidcatalysis,oxidationcatalysts(suchasmethanolOlefinationofhydrocarbonsoxidation)etc..Activatedcarbonwithlargesurf

6、aceareaandhighporevolumehasbecomethemainindustrialadsorbentbecauseofitshighadsorptioncapacityandtheadsorptionofdifferenttypesofcompoundsfromthegasandliquid.Inaddition,thechargestoragecapacityofthedoublelayercapacitormaterialmadeofmesoporouscarbonishigherthanthatofthemetaloxideparticle,andthecap

7、acitanceismuchhigherthanthatofthecommercialmetaloxidedoublelayercapacitor.Titaniabasedmesoporousmaterialshavemanyadvantagessuchashighphotocatalyticactivityandhighcatalyticcapacity.Manystudieshavebeendoneontheirstructure,properties

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