电导率、ph与氨浓度关系(the relationship between conductivity, ph and ammonia concentration)

电导率、ph与氨浓度关系(the relationship between conductivity, ph and ammonia concentration)

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时间:2018-07-19

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1、电导率、ph与氨浓度关系(Therelationshipbetweenconductivity,pHandammoniaconcentration)RelationshipbetweenconductivityandpH,ammoniaconcentrationinultrapurewater1.introductionIntheconstructionofChina'spowerplants,300MWand600MWgradeoftheunithasbeenthemainforceunitinthermal

2、powerplant,withlargecapacityunits,steamparametersgenerallyrequireasubcriticalorsupercriticalwithsuitable,andlargecapacityandhighparameterunitare100%condensationwatertreatmentprocess.Moderncondensatetreatmenttechnology,thepreparationofultrapurewaterabove10Moh

3、mcmhasbecomecommonplace.By100%thesettingofthermodynamicsystemofwatertreatment,watertreatmentisgenerallyusedinthecorrectionapproachofAVT(i.e.,ammoniaandhydrazineallvolatiletreatmentmethod)orbyOT(orCWT)way(i.e.combinedwatertreatment),nomatterwhatkindoftreatmen

4、tmethod,mustbeaddedinammoniainordertocontrolthewatersupply,waterpHvalueismaintainedinacertainrange.PH,ammoniacontentsandconductivityofwatermonitoringisaveryimportantwork.Atthescene,pH,commonlyusedinstrumentforcontinuousconductivitydetermination,anddeterminat

5、ionofammoniacontentsusuallyadoptsmanualcolorimetricmethod.Infact,the100%condensatewatertreatmentsystem,thecontentinthermalsystemofcarbondioxidecanbeconsideredapproximatelyequaltozero,whiletheconcentrationofotherequivalentconductancelargercationsandanionshave

6、reachedafewmicrogramsperliterorevensubmicrogramlevel,inthiscase,therearestrictmathematicalrelationshipsbetweenammoniacontentsofconductivitypH,water.Wecangettherelationshipbetweenthethreebystrictmathematicaldeduction,soaslongaswemeasureonedata,wecanfindtwooth

7、erdata.Generallyspeaking,ItisdifficulttomeasurethepHvalueofultrapurewater,becausetheresistanceofultrapurewaterisverylarge,almostaninsulator.Itisalsotroublesometousecolorimetricmethodtomeasuretheconcentrationofammonia.Incontrast,theconductivityofultrapurewate

8、risarelativelyeasytomeasureandeasytomeasuredata,andthemeterpriceischeaper.Therefore,aslongaswemeasureacorrectconductivitydata,calculateaccordingtotheformulaorfindoutaccordingtothecurveandtheform

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