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时间:2019-08-01
《Metal-organic frameworks a new class of porous materials》由会员上传分享,免费在线阅读,更多相关内容在学术论文-天天文库。
1、MicroporousandMesoporousMaterials73(2004)3–14www.elsevier.com/locate/micromesoReviewMetal–organicframeworks:anewclassofporousmaterialsJesseL.C.Rowsell*,OmarM.Yaghi*DepartmentofChemistry,UniversityofMichigan,930NorthUniversityAvenue,AnnArbor,MI48109,USAReceived12March2004;accepted
2、12March2004Availableonline19June2004AbstractAreviewofthesynthesis,structure,andpropertiesofmetal–organicframeworks(MOFs)ispresented,highlightingtheimportantadvancesintheirresearchoverthepastdecade.Thisnewclassofporousmaterialsisattractingattentionduetodem-onstrationsoftheirlargep
3、oresizes,highapparentsurfaceareas,selectiveuptakeofsmallmolecules,andopticalormagneticre-sponsestotheinclusionofguests.Moreimportantly,theirsynthesisfrommolecularbuildingblocksholdsthepotentialfordirectedtailoringoftheseproperties.Ó2004ElsevierInc.Allrightsreserved.Keywords:Metal
4、–organicframeworks;Porosity;Adsorption;Gasstorage;FunctionalmaterialsContents1.Introduction.............................................................................32.Terminology.............................................................................43.Synthesis.........
5、.......................................................................54.Structures...............................................................................65.Properties..............................................................................106.Outlook...............
6、................................................................11Acknowledgements...........................................................................11References.................................................................................121.Introductionrialsistolinkt
7、ogethermolecularbuildingblocksexhibitingthedesiredproperty.ToproducearobustTraditionally,solidswithoutstandingpropertiessuchporousmaterialonecouldenvisionconstructingtheashighporosityhavebeenproducedbydiscovery-basedequivalentofa‘‘molecularscaffold’’byconnectingrigidsyntheticchemi
8、stry.Alogicalandseeminglysimplewayrod-li
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