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1、PERIODICCHARTOFTHEELEMENTSCopyright©2007,1997,1990,1980byTheMcGraw-HillCompanies,Inc.Clickherefortermsofuse.SCHAUM’SOUTLINEOFTheoryandProblemsofCOLLEGECHEMISTRYThispageintentionallyleftblankSCHAUM’SOUTLINEOFTheoryandProblemsofCOLLEGECHEMISTRYNinthEditionJEROMEL.ROSENBERG,Ph
2、.D.ProfessorofBiologicalSciences,EmeritusUniversityofPittsburghLAWRENCEM.EPSTEIN,Ph.D.AssociateProfessorofChemistry,EmeritusUniversityofPittsburghPETERJ.KRIEGER,Ed.D.ProfessorofNaturalSciences,andChairoftheChemistry/PhysicsDepartmentPalmBeachCommunityCollegeSchaum’sOutlineS
3、eriesMcGRAW-HILLNewYorkChicagoSanFranciscoLisbonLondonMadridMexicoCityMilanNewDelhiSanJuanSeoulSingaporeSydneyTorontoPREFACEThisbookisdesignedtohelpthestudentofcollegechemistrybysummarizingthechemicalprinciplesofeachtopicandrelatingthesolutionofquantitativeproblemstothosefu
4、ndamentals.Althoughthebookisnotintendedtoreplaceatextbook,itssolvedproblems,withcompleteanddetailedsolutions,docovermostofthesubjectmatterofafirstcourseincollegechemistry.ThestudentisreferredtooneofthemanystandardGeneralChemistrytextbooksforsuchmattersasfulltreatmentofnomenc
5、lature,descriptivechemistryoftheelements,andmoreextensiveexpositionandillustrationofprinciples.Boththesolvedandthesupplementaryproblemsarearrangedtoallowaprogressionindifficultywithineachtopic.Severalimportantfeatureshavebeenintroducedintothesixthedition,notablythekineticthe
6、oryofgases,amoreformaltreatmentofthermochemistry,amoderntreatmentofatomicpropertiesandchemicalbonding,andachapteronchemicalkinetics.Intheseventheditiontheearlychapterswererevisedtoconformmorecloselytothemethodsusedincurrenttextbookstointroducecalculationalskillstothebeginni
7、ngstudent.Somechangesinnotationweremade,andtheusageofSIunitswasexpanded.Anattemptwasmadetoincreasethevarietyofstoichiometryproblems,especiallyinthechaptersongasesandsolutions,whileeliminatingsomeoftheverycomplexproblemsthatariseingaseousandaqueousequilibria.Inthetreatmentof
8、chemicalbondingthesubjectofmolecularorbitalswasde-emphasizedinfavorofVSEPRtheory.A