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1、DesigningOrganicSynthesesAProgrammedIntroductiontotheSynthonApproachSTUARTWARRENUniversityChemicalLaboratoryCambridgeJOHNWILEY&SONS...ChichesterNewYorkBrisbaneTorontoCONTENTSWhatDoYouNeedtoKnowbeforeyouStart?...........................................1HowtoUset
2、heProgramme.........................................................................2WhyBotherwithDisconnections?................................................................2Glossary...........................................................................
3、............................4A.INTRODUCTIONTODISCONNECTIONS,...................................4frames1-9.B.ONE-GROUPDISCONNECTIONS,...............................................6frames10-83.1.DisconnectionsofSimpleAlcohols,frames10-22.2.CompoundsDerivedfromAl
4、cohols,frames23-27.3.ReviewProblems1-3,frames28-35.4.DisconnectionsofSimpleOlefins,frames36-43.5.DisconnectionsofArylKetones,frames44-48.6.Control,frames49-60.7.DisconnectionsofSimpleKetonesandAcids,frames61-72.8.SummaryandRevision,frames73-77.9.ReviewProblems4
5、-6,frames78-83.C.TWO-GROUPDISCONNECTIONS,.................................................27frames84-130.1.1,3-DioxygenatedSkeletons,frames84-111.(a)β-HydroxyCarbonylCompounds,frames84-87.(b)α,β-UnsaturatedCarbonylCompounds,frames88-93.(c)1,3-DicarbonylCompound
6、s,frames94-107.(d)ReviewProblems7-8,frames108-111.2.1,5-DicarbonylCompounds,frames112-124.(a)UseoftheMannichReaction,frames122-124.3.ReviewProblems9-11,frames125-130.D.‘ILLOGICAL’TWOGROUPDISCONNECTIONS,.........................42frames131-2091.The1,2-Dioxygenat
7、ionPattern,frames131-170.(a)α-HydroxyCarbonylCompounds,frames131-149.(b)1,2-Diols,frames150-157.(c)‘Illogical’Electrophiles,frames158-166.(d)ReviewProblems12-13,frames167-170.2.The1,4-DioxygenationPattern,frames171-193.(a)1,4-DicarbonylCompounds,frames171-178.(
8、b)γ-HydroxyCarbonylCompounds,frames179-186.(c)Other‘Illogical’Synthons,frames187-189.(d)ReviewProblems14-15,frames190-193.3.1,6-DicarbonylCompounds,frames194-202.4.ReviewSec