活性炭纤维吸附低浓度苯的实验研究

活性炭纤维吸附低浓度苯的实验研究

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时间:2019-05-10

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1、北京交通大学硕士学位论文活性炭纤维吸附低浓度苯的实验研究姓名:邵琳申请学位级别:硕士专业:环境工程指导教师:贾力20080601ABSTRACT:Volatileorganiccompoundscomprisethemajorityofindoorairpollutionandthehazardousairpollutantsemittedbyindustrialsources.Studyonthetreatmentoforganicgaspollutionhasbecomeoneofthehotspotsinthefieldo

2、fheatandmasstransferandthefieldofindoorenvironment.Theemissionofwastegascontainingbenzeneisverycommon,andithasgreatdamagestoenvironmentandhumanhealth.Activatedcarbonadsorptionismostlyadoptedforthetreatmentofbenzene.AndactivatedCal"bonfiber(ACF),anewactivatedcarbonmat

3、erial,isgettingmoreandmoreapplicationsinwastegastreatmentduetoitshi.ghefficiencyadsorptionanddesorptionproperties.Theuseofactivatedcarbonfiberadsorbentisacyclicregenerationprocess,buttheexistingresearcheshavepaidmuchmoreattentionontheadsorptionoforganicgas,whereaslit

4、tleresearchWasdoneondesorptionregeneration.Therefore,allexploratorystudyondesorptionandcyclicadsorption/desorptionwereinvestigatedinthispaper.Meanwhile,thepropertiesofactivatedcarbonfiberandbenzeneadsorptionwerealsostudiedcarefully.Thepropertiesoftheactivatedcarbonfi

5、bersampleswereanalyzedbynitrogenadsorptionmethodat77K(ASAP2010).ThenitrogenadsorptionisothermsofACFsamplesexhibitedatypeIisotherm,whichisindicativeofmicroporousmaterials.ThesurfaceareasofACFsamplescanbemeasuredusingtheLangmuirequationandtheBETequation.Theexternalsurf

6、acesareaandmicroporevolumeswereobtainedbyt-plot.AlsotheporedistributionsofACFsamplesweredeterminedbyH—Kmethod,andthefractaldimensionswerealsocalculatedinthispaper.Theresultsshowthatmicroporevolumesincreasewiththeincreaseofsurfacearea,buttheACTsamplewiththesmallestsur

7、faceareahadthehighestfractaldimension,andthefractaldimensionWasconsistentwithporedistribution.Inthispaper,experimentsweredoneontheself-builtexperimentalplatform.Thebenzeneadsorption,desorptionandcyclicadsorption/desorptionwercmeasuredthermogravimetricaUyusingaTGA/SDT

8、A851。.TheLangmuir,FreundlichandDRequationswereusedtomodeltheexperimentaladsorptiondata.TheresultsshowthattheFreundlichandDRequation

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