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ID:36377032
大小:3.63 MB
页数:53页
时间:2019-05-10
《活性炭纤维吸附低浓度苯的实验研究》由会员上传分享,免费在线阅读,更多相关内容在学术论文-天天文库。
1、北京交通大学硕士学位论文活性炭纤维吸附低浓度苯的实验研究姓名:邵琳申请学位级别:硕士专业:环境工程指导教师:贾力20080601ABSTRACT:Volatileorganiccompoundscomprisethemajorityofindoorairpollutionandthehazardousairpollutantsemittedbyindustrialsources.Studyonthetreatmentoforganicgaspollutionhasbecomeoneofthehotspotsinthefieldo
2、fheatandmasstransferandthefieldofindoorenvironment.Theemissionofwastegascontainingbenzeneisverycommon,andithasgreatdamagestoenvironmentandhumanhealth.Activatedcarbonadsorptionismostlyadoptedforthetreatmentofbenzene.AndactivatedCal"bonfiber(ACF),anewactivatedcarbonmat
3、erial,isgettingmoreandmoreapplicationsinwastegastreatmentduetoitshi.ghefficiencyadsorptionanddesorptionproperties.Theuseofactivatedcarbonfiberadsorbentisacyclicregenerationprocess,buttheexistingresearcheshavepaidmuchmoreattentionontheadsorptionoforganicgas,whereaslit
4、tleresearchWasdoneondesorptionregeneration.Therefore,allexploratorystudyondesorptionandcyclicadsorption/desorptionwereinvestigatedinthispaper.Meanwhile,thepropertiesofactivatedcarbonfiberandbenzeneadsorptionwerealsostudiedcarefully.Thepropertiesoftheactivatedcarbonfi
5、bersampleswereanalyzedbynitrogenadsorptionmethodat77K(ASAP2010).ThenitrogenadsorptionisothermsofACFsamplesexhibitedatypeIisotherm,whichisindicativeofmicroporousmaterials.ThesurfaceareasofACFsamplescanbemeasuredusingtheLangmuirequationandtheBETequation.Theexternalsurf
6、acesareaandmicroporevolumeswereobtainedbyt-plot.AlsotheporedistributionsofACFsamplesweredeterminedbyH—Kmethod,andthefractaldimensionswerealsocalculatedinthispaper.Theresultsshowthatmicroporevolumesincreasewiththeincreaseofsurfacearea,buttheACTsamplewiththesmallestsur
7、faceareahadthehighestfractaldimension,andthefractaldimensionWasconsistentwithporedistribution.Inthispaper,experimentsweredoneontheself-builtexperimentalplatform.Thebenzeneadsorption,desorptionandcyclicadsorption/desorptionwercmeasuredthermogravimetricaUyusingaTGA/SDT
8、A851。.TheLangmuir,FreundlichandDRequationswereusedtomodeltheexperimentaladsorptiondata.TheresultsshowthattheFreundlichandDRequation
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