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1、ThispageintentionallyleftblankSTATISTICALPHYSICSOFLIQUIDSATFREEZINGANDBEYONDExploringimportanttheoriesforunderstandingfreezingandtheliquidglasstransition,thisbookisusefulforgraduatestudentsandresearchersinsoft-condensed-matterphysics,chemicalphysics,andmaterialsscience.Itdetails
2、recentideasandkeydevelopments,providinganup-to-dateviewofcurrentunderstanding.Thestandardtoolsofstatisticalphysicsforthedenseliquidstatearecovered.Thefreezingtransitionisdescribedfromtheclassicaldensity-functionalapproach.Classicalnucleationtheoryaswellasapplicationsofdensity-fu
3、nctionalmethodsfornucleationofcrystalsfromthemeltarediscussed,andcomparedwithresultsfromcomputersimulationofsimplesystems.Discussionsofsupercooledliquidsformamajorpartofthebook.The-oriesofslowdynamicsandthedynamicalheterogeneitiesoftheglassystatearepresented,aswellasnonequilibri
4、umdynamicsandthermodynamicphasetransitionsatdeepsuper-cooling.Mathematicaltreatmentsaregiveninfulldetailsothatreaderscanlearnthebasictechniques.SHANKARPRASADDASisProfessorofPhysicsatJawaharlalNehruUniversity,NewDelhi.Duringthecourseofhiscareer,hehasmadesignificantcontributionstot
5、hefieldofslowdynamicsinsupercooledliquidsandtheglasstransition.STATISTICALPHYSICSOFLIQUIDSATFREEZINGANDBEYONDShankarP.DasJawaharlalNehruUniversityNewDelhi,IndiaCAMBRIDGEUNIVERSITYPRESSCambridge,NewYork,Melbourne,Madrid,CapeTown,Singapore,SãoPaulo,Delhi,Dubai,Tokyo,MexicoCityCambr
6、idgeUniversityPressTheEdinburghBuilding,CambridgeCB28RU,UKPublishedintheUnitedStatesofAmericabyCambridgeUniversityPress,NewYorkwww.cambridge.orgInformationonthistitle:www.cambridge.org/9780521858397cS.Das2011Thispublicationisincopyright.Subjecttostatutoryexceptionandtotheprovis
7、ionsofrelevantcollectivelicensingagreements,noreproductionofanypartmaytakeplacewithoutthewrittenpermissionofCambridgeUniversityPress.Firstpublished2011PrintedintheUnitedKingdomattheUniversityPress,CambridgeAcatalogrecordforthispublicationisavailablefromtheBritishLibraryLibraryof
8、CongressCataloging-in-PublicationDataDas,Shanka