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1、Graphene:newbridgebetweencondensedmatterphysicsandquantumelectrodynamicsM.I.Katsnelson1andK.S.Novoselov21InstituteforMoleculesandMaterials,RadboudUniversityNijmegen,6525EDNijmegen,TheNetherlands2ManchesterCentreforMesoscienceandNanotechnology,UniversityofMa
2、nchester,ManchesterM139PL,UKAbstractGrapheneisthefirstexampleoftrulytwo-dimensionalcrystals-it’sjustonelayerofcarbonatoms.Itturnsouttobeagaplesssemiconductorwithuniqueelectronicpropertiesresultingfromthefactthatchargecarriersingraphenedemonstratecharge-conju
3、gationsymmetrybetweenelec-tronsandholesandpossessaninternaldegreeoffreedomsimilarto“chirality”forultrarelativisticelementaryparticles.Itprovidesunexpectedbridgebetweencondensedmatterphysicsandquan-tumelectrodynamics(QED).Inparticular,therelativisticZitterbe
4、wegungleadstotheminimumconductivityoforderofconductancequantume2/hinthelimitofzerodoping;theconceptofKleinparadox(tunnelingofrelativisticparticles)providesanessentialinsightintoelectronprop-agationthroughpotentialbarriers;vacuumpolarizationaroundchargeimpur
5、itiesisessentialforunderstandingofhighelectronmobilityingraphene;indextheoremexplainsanomalousquantumHalleffect.arXiv:cond-mat/0703374v114Mar2007Keywords:Graphene;TransportProperties;ElectronMobility;ScatteringProcesses;QuantumHallEffect;IndexTheorem;MinimalC
6、onductivity;Tunneling;KleinParadox;Zitterbewegung.1IntroductionThevarietyofcrystallographicformsofcarbonplacesthiselementintothefocusofattentionbothintermsofbasicresearchaswellasapplications.Thetree-dimensionalcrystallographicforms-graphiteanddiamond-arekno
7、wnfromtheancienttimes,andarewidelyusedinindustrialapplications.Recentlydiscoveredzero-dimensional(fullerenesorcagemolecules1,2,3)andone-dimensional(carbonnanotubes4)formsarenowextensivelystudiedduetoits’remarkableand,often,uniquemechanicalandelectronicprope
8、rties.Atthesametime,despiteveryintensiveresearchinthearea,noanytwo-dimensionalformofcarbonhasbeenknownuntilveryrecently.Ironically,thiselusivetwo-dimensionalform(dubbedgraphene),is,probably,thebesttheo