化工热力学课后题规范标准答案马沛生

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1ù⊝ûᑣ஺sýḄD%Eឋ0ᙳT{஺2-6.ᵨḄÿᦪḄ᝱ᳮᨵᵨḄᦪ᝱ᳮᨵZc!"ᦪ#$᜜Pitzer,-Ḅ./஺1!"ᦪḄ᝱ᳮ஺2—7.6789:;8<:pVT@AḄBC஺:DEp-y-rᐵI᝞RKSNOஹPRNOQBWRNOTUᵨV@A9:Ḅp-y-r,XYUᵨᑮ<[\ᵫ^_NO`-Ḅᨬb:c᪷ᓽ!<:Ḅ᥅g:c஺hᯠjᨵDE᝱NOklmnᙢpq9:Ḅp-K7ᐵIr〉ᵨV<:hᵨᑮ<[\tuvwmᜧḄyz஺{9:[<:Ḅ᥅g:c|᧕~஺◀\᜜ᱯ<:|cឋḄrᜧ஺◀᝱NO᜜Oj⌱ᵨᐵI;ᓄᐵINᩭA஺2-8.᝱ᳮ஺᝱ᳮ!ᙠ[CḄ᝱ᡠᨵḄᱥ⊤¢-[CḄឋ஺᝱ᳮ£〉ᵨVP-V-TᐵIᦪ᝱ᳮ¤¥Ḅ¦ᩭX§¨©〉ᵨVDEª«ឋ;¬⌴ឋḄᦪ;®EᦪḄ᝱ᳮ஺2-9.᝞°ᳮ`±ᔠ³ᑣ!µ¶⌕,-^¸ᭆºᨵ_»¼Ḅ±ᔠ³ᑣV½¾¿:ᵫVÀᑖḄÂᳮÃឋQᵫV±ᔠÄÅḄÂᳮÃឋÆÇᳮÃḄᑖÈ;ᑖ:cÈÉÊËᙢÌ¿:±ᔠᱥḄP-V"ᐵI஺᝞°Î〉ᵨV8ᱥḄ᝱NO᡽¨ᑮ½¾¿:±ᔠᱥᓄª«ÐḄ¸ªÑÒ⚪஺ÔÕÖ×ØᵨḄNÎ᝱NOÐḄᦪ⚗⊤ÚᡂÀᡂxQ8ᱥᦪ⚗ḄÝᦪ^ÝᦪᐵIÞ1!±ᔠ³ᑣ஺VrCḄ᝱NOᨵrCḄ±ᔠ³ᑣ஺ßà〉hḄ±ᔠ³ᑣ@A᝱NOÐḄᦪ⚗ÆᐸlÊËᙢ̽¾¿:±ᔠᱥḄp-v-TᐵI@A±ᔠª«ឋḄᐵã஺ᵨḄ±ᔠ³ᑣᒹå〉ᵨVæḄçèឋḄ±ᔠ³ᑣஹéêIᦪḄ±ᔠ³ᑣQ〉ᵨVëN¼᝱NOḄ±ᔠ³ᑣ஺2-10.ᙠ¸îឋḄ|ᘤÐðᐭ©ImolḄ÷8ᱥ|ᘤḄ:cønVùᱥḄ᥅g:cVc»᝞ûÆᐸüªýþḼ⚪2—1Ḅ7Ḅ12—2Ḅ⌶ᓄC஺ᓄ⊤ᙠp-V"#$%&ᙠ'(ᔜḄ*᝱,-.஺/0ᵫ2'(34#1-C-2ᩩV=%Ḅ349#ᡠ;ᙠP-U>;⊤?᝞ḄAB஺1⊤4ᘤᡠDḄᱥFḄGHIᔠᱥᵫ⛳,LG,⛳,HMNᡂ஺P129#⊤34'(஺QḼḄST#4ᘤḄ⛳,HMMUV⛳,LGMUḄWXYZᨵᡠᓄ#\ᵫ>]ᓄ^_ᜧ஺ᑮbCc#GHW☢⌲fgᜫ஺ij'(#4ᘤkᙳWḄmnM஺ᙠ᦮p#4ᘤᑁḄrs^tu'Ḅ஺

22-11.w]SO?ᙠ431K~#ஹVirialᦪᑖ?0B=-0.159m3-kmof1,C=9.0xl0-3m6kmor2,:(1)SO2ᙠ431Kஹ10Xl()5pa~Ḅ᥅MU(2)ᙠ¡¢ᑁ#IkmolSOzᵫ10Xl()5paឤ¦(431K)>⌮r¨ᑮ75Xl()5pacᡠ©Ḅª஺/0(1)⚗¬®?0„pV.BC¯Z—---=1-I----1——(A)RTVV2p=10Xl()5pa,r=431K,B=-0.1-kmoF1,C=9.0xl()-3m6³ᐭB(A)$᦮ᳮ¶00.27/3_2O.159^-9X1O^=0V+»³¼/#½¾?0V=—=3.5m3-kmor'P»³ÀÁ?0V=3.39m3-kmor'(2)r¨ª—0W=pdV(B)Äp=75Xl()5pac,ᵨ(1)Æ᪵Ḅ®È/É:

3V=0.212tn3-kmoF1V,=3.39n?.kmoP,ᓃ=0.212n?.kmo˳ᐭB(B)/É:lV=77xl05J-kmoF,2-12.p125cm3ḄÍឋ4ᘤ#ᙠ50࠷,18.745MPaḄᩩÒ~ÓÔÕᵬ×ØÙÚÛܾ?17g?ᑖᵨᳮÞßM®,RK®RK®>;ᵨáÒ஺/0ᵫ▬ãä¶ᵬ×Ḅåᦪ?07=190.56K,o0=4.599MPa,18.745x106D-----------------------------------------------U.ZUOJRT8.314x323.15Ahhᢥ᯿B2-16aZ———2.234\-hB\\+h\-h1+h,B(2—16b)஻=ñᔳVzz»³#ó½¾Z=l,»³,ÀÁô~⊤஺»³öᦪzh

4010.208310.87790.237320.88260.236030.88230.236140.88230.2361ZRT0.8823x8.314x323.15V=1.265x104m3/mol=l26.5crrf-mof1P18.745xl06125m=M——=16x=15.81gV1265>ô#ᵨRK®÷øùÛܾ஺2-13.úᙠp7810cm3ḄûüDᐭ1kgḄý×#þᙠ253.2࠷~ÿ
ḄᐰlOMPa,ᔲᐰḄឋT=369.83K,p,.=4.248MPa,=0.152c=2222=22727molM44〈=7810x6343.63xl(r6m3.mon22.727RTᵨRK"#:PV-bT0-5V(V+b)✌ᐜᵨ'()*a,ba=0.4274+2(25/=.42748x“-
ᐝ/0=1.6.o.s.-208296PamKmolcc(4.248x1o6)b=0.08664RT/p=0.08664x8314x369)3=6.2771x105/.1ᔆ1c4.248xlO63ᐭRK"#஻=9.876஻789:;lOMPa,ᦑᨵ>?ᓻ◅஺2-14.CᵨRKS"#)*DEᙠ300K,3.704XdPaGḄ⛳IJKḄ᥅MNO஺PQRSTV=6.08lx10-33.mo஺mᵫ▬WXDEḄYᦪC.=407.8K,p,.=3.640MPa,(V=0.1777[=777[=300/407.8=0.7357\=0.480+1.57%>0.17&«2=0.480+1,574x0.177-0.176x0.1772=0.7531

5a(T)=[1+m(l-7-)]2=[1+0.7531(1-0.735705)F=1.2258a(T)=a!«(T)=0.427/2,2/ᓄ,«(r)=o.42748x(8.314x(407.8)2x1.2258=1,654J(Pa-m6)/mol23.640x106b=0.0866b7[/p,=0.08664x8.314x407.8/(3.640x106)=8.0700x10-5m3/molA=c=W[[e;=009852bp_8.0700x10-5*3.704x1Q5B=0.01198~RT8.314x300Ahᢥ᯿(i2-16an--------8.2241B\\+h\-h----------τ\+hᓝfbB0.01198I((2—16b)h=—=VZZq3)*
rsTZ=l,q3v#Iwxy'⊤஺q3{ᦪZh010.0119810.91480.0131020.90700.0132130.90620.0132240.90610.0132250.90610.01322ZRT0.9061x8.314x300V=6.1015xl0-2m3/molP3.704x106i6.031—6.101
xl0-2/6.03ixIO"_%=L22-15.CᑖᵨRK"#RKS"#)*ᙠ273Kஹ1000X105paF,ḄT
QRSTZ=2.0685஺ᵫ▬WXḄYᦪ
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6,ap1.5546x1OOxlO6,A=,,------[-———=1.8264RT-5(8.314)2X(273)-5^,^763xlO-xlOQ^ip[fi==ii79iRT8.314x273ᢥ᯿((2-16a)▼,ஹ
bB1.1791I((2—16b)h=—=VZZq3)*
rsTz=2,q3v#Iwxy'⊤஺q3{ᦪZh020.5895511.8620.633222.12600.554631.69260.696640.88230.2361q3¡ᦈ£
¤ᵨRK"#X{"#:V=0.00004422m3/mol=pV4.422xIO-5x1000xlO5…Z=---=---------------------=1.9485RT8.314x273RKS"#T=7/7[,=273/1261=2.1649rm=0.480+1.574v-0.176ty2=0.480+1.574x0.040-0.176xO.O4O2=0.5427a(T)=[1+w(l-7[0-5)]2=[1+0.5427(1-2.164905)F=0.5538a(r)=«-«(r)=0.4278R27[,2/p.•

7bp_2.6763x10>5'i஺஺ḄiB==1.1791~RT8.314x273ᢥ᯿((2-16a),bB1.1791I((2—16b)h-——=—=-------VZZ½᪵q3¡ᦈ£¤ᵨRKS"#X{"#:V=0.00004512m3/molrpV4.512XW5X1000X105/—___—______________________=1.9881~RT~8.314x2732-16.Cᵨ'ᑡᔜÁ"Â)*ÃJKᙠ107.9Xl()5paஹ593K'ḄÄÅ
ÆÇÃJK⊤ÈḄᦪÉ(V=0.01681n3.kgT)ÍÎÄÏ஺(1)ᳮÑKN?Ò(2)ÓÔ"#(3)ÕÖᓄRK"#×▬WXØÃḄYᦪ(=647.13K,”
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8ã=ᓽ+@8প=-0.4026+0.345x(—0.1098=—0.4404zåæ1+ç.è1+x(-0.4404)=0.7649RT,T)0.916''rZRT0.7649x8.314x593V3.495xl0-6m3moF1=0.01942n3kg-1P107.9x1030.01687-0.01942,^,n/n/=------------------xlOO%=-15.1%0.01687(3)ÕÖᓄR-K"#1hZ(2-38a)1-h+(2-38b)éêÄeëIêÄT3ᐭÆ᦮ᳮḄ:1h1Z=--------5.621-hQ/51+஺\-hl+/zClp_0.04625hhrZὶîïðñ(q3òZ=0.7335ZRT0.7335x8.314x593V==3.3515xl0-6m3mof1=0.01862n3kg-1P107.9x10s,Ûó0.01687—0.01862.=------------------x100%=-10.4%0.01687Ã᩽ឋÏõḄᱥ2-17.Cᑖᵨ(1)vanderWaals"#(2)RK"#[(3)RKS"#)*273.15KGéCO2ᑮNO550.1cm3-mor1ᡠ◤⌕Ḅ஺RST3.090MPa஺×▬WXØCO?ḄYᦪ7[.=304.19K,p‘=7.382MPa,3=0.228(1)vanderWaals"#RTap-------------------rV-bV2(Ø:"27"/6º=ÿ
1=0.365%.m஺

9b=RT/8p=8-314x304-1^4.282xl0-5m3*-mor1rc'8x7.382x1()6ᑣRTa8.314x273.150.36557-6662=3.269x106Pa=3.2MP-V-b—V55Q1X10--4282X10-(55Q1X10)./G;I^^00%—5.79%(2)RK45RTP-V-b-T0-5V(V+b)9::a=0.4274K212.5/84274ஹ(8.314)M(3°449)—=6.459.),K05-mof2,0.08664x8.314x304.19__,b=0.08664RT,./p=---------------------=2.968x1m05mmolcc7.382X106RTaY)-------------------V-bT05V(V+b)_8.314x273.15___________________6.459955Q1x10-6—2968xIO"(73.15)05x55(llxl0-6x(550.1+29.68)xl0-62=3.138xl06Pa=3.138VlPa)“3.090-3.138+uu”./%=-------------x100%=-1.55%3.090(3)RKS45RTa(T)P-V-h~V(V+Z?)9:+a(T)=a-a(T)=0.4278R27;2/p-a(T)c«(n=[i+/«(i-r05)]2rA+m=0.480+1.573-0.176ty2=0.480+1.574x0.228-0.176x(0.22Ẇ=0.829720.5\ᑣ+஽(T)nU+ma—qaS)]:M273.15l+0.8297x1-=1.0891304.19

100.42748x8.314
2xU304.19
2a#T$=a-aUTV=0.4274K2#/0.WXᱏxl.0897.382xl06=0.403330a-m3mor'0.08664x8.314x304.196=0.08664/?./஻,==2.968x10-5m3"mol7.382x1
6RTaU7j_8.314x273.15_____________0.40335-V-b-Vfy+b~5511x10-6—2968x10-6QIO-6xU5511+29.68
x1O-6551X=3.099x106Pa=3.09^VlPa3090-3099./%=[u*100%=-0.291%3.090\]^_45Ḅabcd+ef+vanderWaals45Ḅab./ᨬᜧ+RKS45Ḅabijᨬk஺RK45Ḅabijlem஺2-18.nopqr0.3n?Ḅstuvᑁxyz+{jr290Kஹ|}r25X|()5pa,~yzᑮ479K,b|}r[MyzḄᦪrMT-305.32K,p,.=4.872MPa,co=0.099c:T=TJT=290/305.32=0.95p=pjp=2.5/48.72=0.513rXcrlcᦑᵨ2-11,ᵨᓄᦪab
4??ᓽ=0.083—0.422/7L6=0.083—,M=-0.375rU0.95V'6n17?Bw=0.139—0.172/¢2=UM39M=-0.074U0.95V2Z=1+”=1+UB£+¤প
/&]=1+-0.375-0.099x0.074
x^^-=0.7935RT'TJ0.95஻=%=03=3922(mol)V76.5x10-5¦+§ᵨRK45¨©ab஺ᐸ:MT=479K,᥅¬pqᯠrV=76.5x1Ofn?mo¯+✌ᐜab:a=0.4274K2K2.5/஻0.4274&U8.314
2xU305.32V”=9.879UPa-m6K0-5-mor2
4.872x106

11.CCONN/DT,0.08664x8.314x305.32(\b=0.08664RT./p=--------------------;--------=4.514x105Im3-moltcc4.872xlO6''²ᐭRK45M_RTaP-V-b~´y(y+b)_8.314x479_________________9.879_______________765.0x10-6—45]4xi0-6(479)05XI-6(5o+5J)-67650X0x7644X10=4.804x106Pa=4.804MPa2-19.᝞d¶·22.7kgḄyºᙠ294K¼½ᐭ0.085n?Ḅ¾¿:+À|}r[MÁ▬ÃÄÅÆyºḄᦪrMT=282.34K,=5.041MPa,co=0.085c*ᔁ3஺7(M1᥅¬pqÈVÉn0.085104.8x1O-6(m3-mor1)n81Q7§ᵨRK45¨©ab஺✌ᐜabMa=0.42748R27;25/p=S42748x(8.3@,2823Ê=785jfpa-m6-K05-moF2),'5.04lx106+,,CCOZ,DT,0.08664x8.314x282.34ËÌ”,/3b=0.08664RT/p=-----------------------------=4.034xlOin55Im-mol11°‘5.041xlO6''²ᐭRK45MRTaP~V-bT°5V(V+஺)_8.314x294_________________7.851_______________104.8x10-6-40.34x1OM(29Í+104.8x10-6x(104.8+40.34)x10-6x=7.817xl06Pa=7.817MPa2-20(ᵫÏ]ÐᓫḕᶍÔ+ÕᶍÖaÔ)2-21.ᵨPitzerḄᓄᐵ9abᵬzᙠ323.16K¼ÛḄ|}஺ÜÝᵬzḄ᥅¬pqr1.25X10—4m3,|}ḄÞßàr1.875X107Pa»MÁ▬ÃÄÅÆᵬzḄᦪrM(=190.56K,Pc=4.599MPa,=0.011ீ=77(=323.16/19056=1.696Mãäp,Öåæçab+◤⌕/abP=Z/?T/V=ZX8.314X323.16/(1.25X10^)=2.149X107Z

12êë஻==4.599x1()6p,+cᔠíî9ÆMz=4599x10”021ï(A)2.149xl07PitzerḄᓄᐵ9rMZ=Z(°)+@Z">(B)᪷ö(A)ஹ(B)î9¨©÷²+ø5rM(1)ùZà+ᯠ¦²ᐭ(A)9úûG;(2)᪷ö7;p,àÅ(2-9)(2-10)ÆᑮZযZপ;(3)ÅÆᑮḄZ£Zপà²ᐭ(B)9úÆZà;(4)\]ZḄabàýÞßà+᝞dþ/]ᜧ+ᑣ²ᐭ(A)9ÿ
ᑮᦈ஺p,=4.06Z=0.877ᑣp=p-p=4.599x106p=4.599x106x4.06=1.867x107Pacrr!(1.875-1.867)x107/1.875x107=0.43%2-22.%ᵨRK)*
+,ᓄ./01Ḅ3ᑖ56ᔠᱥᙠ1510c/13.78MPaAḄ᥅CDE஺F
ᡠ◤Ḅᦪᑡ⊤᝞AMᐗT/Kp,xlO-5/PaVOxl06/(m3-mor')Zca/(Pa•m6-K(>-5-mof)/?/(m3-mof1)cCO(1)304.273.8294.00.2746.4602.968XIO-525CH(2)369.842.482000.27718.296.271XIO'3812335.454.72140.411.12ᵫ(2-51a)/(2-51b)Za=+2%y2a12+£஺22=஺.52x6.460+2x0.5x0.5x11.12+0.52x18.29M=11.75Pa-m6-K05mof2b=+yb=0.5x2.968x10-5+0.5x6.27lx10-5=4.415x10-5(m3-mof')M2211.75x13.78x10-A=06322R2T23(8.314)2X(424.15)2-5

134.415x1O-x13.78x1O'BRT8.314x424.15ᢥ᯿^a2-16ab(A)bB0.1725/^(2-16b)(B)ὶfgF)*aAbஹbaBbij
Z:lᦪZh010.172510.67760.254620.60930.283130.59870.288140.59760.288750.59750.2887mnᓃZ=0.5975,/?=0.2887rs=0.5975x8.314x42415“52xi4”l/6ᔠᱥZ᥅CDE:(r?wp13.78x1062-23.6ᔠz{Ḅឋ{}~ᨵᐶḄẆ⚪஺%ᵨRKS᝱)*
ᵫR12aCC1Fb22/R22aCHC1FbMᡂḄ3᥅C6ᔠz{Dᙠ400K/l.OMPa,2.0MPa,3.0MPa,4.0MPa2/5.0MPaḄ᥅CDE஺+ᐗ6ᔠᱥḄᵨᦪ2=0a
b஺
ᡠᵨḄᦪ᝞A⊤Mᐗa/-bCD4/KplMPacR22(1)369.24.9750.215R12(2)3854.2240.176F
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¡¢£MᑖḄRKS¤ᦪ¥ᵫ6ᔠ¦ᑣ§Z6ᔠᱥḄRKS¤ᦪ¨ij
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஺ᡠZḄᑡ¯A⊤:77K400Mᡂ°=)'2=RKS)*¤ᦪMᑖ(1)a=0.7568b=5.346X10°Mᑖ(2)a=1.007b=6.565XIO-5

146ᔠᱥa=0.8774b=5.956X10$/?/MPa12345Vcai/(cm3•mol")3114.01442.3877.0585.5399.32-24.%ᵨAᑡ)³
ᵫ30%a᥅CµbḄ¶a1b/70%·¸1a2bᡠMᡂḄ+ᐗ6ᔠᱥᙠ462Kஹ69Xlab5paAḄ᥅CDE஺a1bᵨPitzerªᦪ¼½m5ᐵὶ^a2bᵨRK)*ᐸᦪ⚗,0.08664WT,.ᔣ=-------------Pci0.427480-2Ä%=--------------Peija3bᵨª⚗ÅÆ)*ÅÆÇᦪÈÉÊg1=14x10',B=-265X10^,2242=—9.5*10^,aBḄᓫÐm3.moÓb஺Q=1.3x10"%C=3.025xl0-9,n2C“2=495x1aT9,03=7.27x10-9acḄᓫÐ.moFb஺Õֶ׷¸1Ḅᦪ/Ørm5N=126.10K,%=3.394MPa,CD=0.0402nCH7O=425.12K,p‘=3.796MPa,

15V=^=-987X8.314X462=".m°F)p6.9xlO6''(2)RK)*_1a(h\z~~^h~bRT'5ll+AO஻=2=5VZRT”=/2ᓽ+2yy2ai2+îµb=°ï+y2b20.4274lðMᐗT/KPcX10-5/Paᓃxl()6/(m3moP)Zca/(Pam6-K05-mor2)Z?/(m3mol1)11126.1033.9490.10.2921.5552.676XIO-522425.1237.962550.27429.018.067XIO-512231.5334.37158.50.2837.012a=0.32x1.555+2x0.3x0.7x7.012+0.72x29.01=17.30Pa-m6-K05-mot2Mb=0.3x2.676x1Of0.7x8.067x10-5=6.450x1033-mofM+m1_afhy__J______________17.30__________(_h_\1-hbRT'5[1+h)~\-h6.450x10~5x8.314x(462)15Ub___bp__6.450x10-5x69x1()5_0.1159V-7RT—öZx8.314x462——Zij%!ZZ=0.7466=0.156-÷ø”4ù…")(3)ª⚗ḄÅÆ)*:pVBC7xZ=---=1H----1--7RTVV2

16BM+2yyB+ylB=(0.32x(14)+2x0.3x0.7x(-9.5)+0.72x(-265)]x10-6t2t222=-1.326xl0-4(m3-mor')C"=Gu+3°y2cli2++3°ü2G22+%஺222ijk=[0.33x(130஺+3x0.32x0.7x(495஺+3x0.3x0.7?x7270+0.73x(3025()]x10-12=1.455xl0-3(m6-mor2)þᐭ⚗69x1O'v1.326X10-41.455x10-3----------=1------------+----------8.314x462VV2V=4.25xl0-4m3mor12-25.%&'()*+,ᜐᳮ454kgᵬ2342Ḅ6᥅89ᔠᱥ஺=>ᙠ50Xl()5paஹ422KFGH&'()IGH&'(Ḅ=>>JK᳛MNOCH?+7?9ᔠᱥḄᑖUVMM=+0.5M,=0.5x16.04+0.5x30.07=23.06r/9ᔠᱥḄK᳛M஻=6^=19.7(kmolN)ᑭᵨKay`ᑣbcdefᦪ=0.5x19056+0.5x305.32=247.94KiP”=05x4.599+0.5x4.872=4.73flVlPaT422bcklᩩnMT=—=------=1.702prT247.94Pcᵨo2-11ᑨq)rstᵨ)uvᡠ◤ᦪyᑡ{F⊤)ᐸ~ᦪyᢥ᯿(2-48a)~(2-48e)஺V3Pci/MPaVcij/(m3-kmor1)ZCDCl]u11190.564.5990.098600.2860.01122305.324.8720.14550.2790.09912241.214.7010.12050.28250.055ᵨ▤⚗Ḅvirial9ᔠᱥḄឋ)◤⌕9ᔠᱥḄvirialᦪ,F⊤,

17uBপ/(m3-kmol1)11-0.03530.133-0.0116522-0.1680.0948-0.0828712-0.08940.1226-0.03528ᵫ(2—46)B=+2yyB+yB=0.52x(-0.01165)+2x0.5x0.5x(-0.03528)+0.52x(-0.08287)Ml2l222=-0.04127(m3-kmor')RT8.314xl03x422..„.,__,,__,7ஹV=-----FBn=----------------------0.04127=0n.6604x1033(/m33-kmol)p5.0xlO6>JK᳛7V=19.7x0.6604=13.0l(m3•@)72-26.%N2Ḅ9ᔠᱥ)ᢥᔠᡂrḄᓄVl)ᐭᑮrᘤ~N+3H=2NH2239ᔠᱥ£rᘤḄ&¤M600X105Pa,¥¦M298K,K᳛M6m3-h-1„ᐸ~15%ḄN2§ᓄMNl,GHrᘤḄ=>¨ᑖG©)ªrḄ=>«¬tᵨ)(1)*+,ᡂNO®¯NH3?(2)°rᘤ±²ᱥK(³N%Ḅ9ᔠᱥ)Ḅ&¤M550X10Spaஹ¥¦M451K,IᙠᑁµD=0.05m¶ᑁḄK·MNO¸(1)¹º%»ᐗ9ᔠᱥpVTḄI⚪஺tᵨRK£J___hZ=1-hbRT'511+ha=yQu+2y,ya+y^a2l222b=yA+yb220.4274¾2%¿ᐗT/KPcX10-5/Paᓃxl()6/(m3.moP)Zca/(Pam6K05mor2"(m'-mol1)511(N)126.1033.9490.10.2921.5552.676XI0-2

18522(H)33.1813.1364.20.3050.14271.820X10'21264.6821.0376.450.2990.4727a=0.252x1.555+2x0.25x0.75x0.4727+0.752x0.1427=0.354Ta-m6-K05-mol-2Mb=0.25x2.676x10-5+0.75x1.820x10-5=2.034x10-5m3-moF1M1ah1____________0.3547________(hஹZ=\-hbRT'5\\+h\-h2.034x1O-5x8.314x(298)'5[l+h,hஹ--0.407I-/?l+/z?_b___bp__2.034x10-5x600x1()5_04926h”9—-Zx8.314x298%—Z£ÁÂZ=1.424/Ã0.346^1.424x8.314x298..v===588xl06(m3morl)p60xl06''᥅8K᳛n=6xl0-=1.020x105(molh-1)58.8'7N2Ḅ᥅8K᳛M=0.25x1.020x1=2.55lx104(mol-h-1)ᡂḄNHVM2.55lxl04x0.15x2=7.653xIO3(mol-h-1)3Ä2Źº%»ᐗ9ᔠᱥpVTḄI⚪஺ÇÈtᵨRK£rᘤ±²ᱥK¿ᡂÊᐭ²lmolN2MËÌN1—0.15=0.852H3—3X0.15=2.552NH0.15X2=0.303ᑣÎᱥḄVM0.85+0.30+2.55=3.75ᔜᱥḄ᥅8ᑖ᳛M0.85Зy=-----=0.230N“3.75255y=—=0.689H-/3.75_0-30_nn2i>NHA--0.081ÊNH3ÑM¿ᐗ)⊡ᐙᦪy᝞F:¿ᐗT/K²xIO-Öᓃxl06/(m3.moÃ)Zea/(Pam6K05mor2Z?/(m3moF)

1933(NH)405.65112.7872.50.2428.6832.591X10-5313226.1762.081.00.2673.66623116.0138.668.30.2741.109+M஽2+Ø஺33+2%ÙÚ2+2ÙÛ3G3+2y2y3a23=0.232xl.555+0.6892X0.1427+0.0812x8.683+2x0.23x0.689x0.4727+2x0.23x0.08lx3.666+2x0.08lx0.689x1.109=0.61XPam6-K05-mor2)b=yfy+yb+=(0.23x2.676+0.689x1.820+0.081x2.591)x105M22=2.079xl0-5(m3-mor')1_a(hA__J_____________0.617_________(1ஹ1-hbRT'5[l+h)\-h2.079x10-5x8.314x(455U+ᓰ-஺ÄÝÅ,bbp2.079X10-5X550X1050.3050-V-ZRT-Zx8.314x451-Z£ÁÂZ=1.250/?=0.244I,ZRT1.250x8.314x451,n-6/3V-------=-----------------------=85.22x10Im-molIp55x106'7ᡠÊÊ£²N2MImolÑËÌᐭ²ÎᱥḄVMl+3+0=4mol±²ÎᱥḄVM:IX(1-0.15)+3X(1-0.15)+lX0.15X2=3.7molßàḄ᥅8K᳛Mrᱥ᥅8K᳛X3.7/4=1.022X105X3/4=9.45X104(m3moF1)ßàḄ>JK᳛M85.22x10^x9.45xlO4=8.O53(m3-h-')·%᳛u-%V=--8-.0-5-3--8.053=4103.4(m•h-1)=1.140(m-s-1)A⁐xD஺3.14/4x0.05242-27.âᜩᯠ=Ä᥅8¿ᡂMC%84%ஹN9%,CH7%Åᙠ&¤9.27MPaஹ¥¦37.8࠷226FḄæᙳ,·M25m3.hT஺ᵨFéêᙠ᪗ÌìíFḄ=>K·஺Ä1Åᳮî=>Ä2ÅbcdeïᦪÄ3ÅDaltonóôõöᓄ&'÷Uo;

20Ä4ÅAmagatóôõöᓄ&'÷Uo஺Ä1Åᢥᳮî=>ì᝱᪗ÌìíF=>K·_PM59.27x25x273=2010n3-h-1v(273K,0.1013MPa)T\Pi(37.8+273)x0.1013Ä2Åbcdeïᦪê✌ᐜtᵨKay`ᑣ±bcḄde¥¦de&¤)ᑡ⊤᝞F:¿ᑖ᥅8/%T/KPc/MPa”/Ky/MPacᵬ20.84190.564.599160.073.863þ=0.09126.103.39411.350.305420.07305.324.87221.370.341ᔠ1.00192.794.510bcde¥¦M192.79K,&¤M4.510MPa,9ᔠᱥḄæᙳ&'÷Uÿᵫ
ᑡT37.8+273…9.27…T=------------=1.61,p=------=2.055rr192.794.510!"ᦪ$%ᓄ'()*+Z=0.89m.'()/ᐭ12pV=ZRTC:V=4=0.89x8.314x(3J.8+273)=91:.)248p9.27xlO6''n=-=-----------=1.008x105molh_1=100.8kmol-h-1V2.481xIO-4ᙠ᪗EF᝱
H'()Z=l,(IJKL᳛N9+ᑮ,RTinn஺-I8.314x273”(TU3.-iv-n-v7-n----=10(18x10x------------=22585m-hp0.1013xl06(3)DaltonYZ$%ᓄ'()$%ᓄ'()*[Hᔜᱥ^Ḅ`ᵨᑖcᑖZV/Z,-TTPi=pyipjT=—IPeᵬf1.637.7871.6930.900.756gh2.460.8340.2460.980.0882if1.0280.6490.1330.960.0672

21ᔠk0.9114.'()/ᐭ12pV=ZRT+:mn=°.9LI4x(37.8+273)=k஺o4p2541p9.27x106''஻='=-------:——-=9.839x104mol•h"=98.39kmolhrV2.541xlO-4ᙠ᪗EF᝱
H'()Z=l,(IJKL᳛N9+ᑮT,RT,C38.314x273___._3,1.v=n-V=n-----=98.39x1()3----------------22045mhxp0.1013xl06(4)AmagatYZ$%ᓄ'()ᐜ+ᔜᱥ^Ḅ'()Ht`ᵨᑖJKYZuvkwcᑖTzy(2-13b)uvkwH+Ḅ᝞
ij%/KPcij1MPaV/(m3-kmor1)Zcij%

2211304.27.3820.09400.2740.22822369.84.2480.20000.2770.15212335.45.4720.14040.27550.190cᐗa/(Pa-m6-Ka5-mor2)Z?/(m3moP)5CO(1)6.4602.968XIO-25CH(2)18.296.271X10-381211.12ᵫ(2—51a)(2—51b)+a=y¥஺”+2yy2a12+ylci=0.352x6.460+2x0.35x0.65x11.12+0.652x18.29M22=13.58Pa-m6-K05-mor2h+y/?=0.35x2.968xl0-5+0.65x6.27lxW5=5.115xl0-5(m3-mor')M22ᑶR8460A=᝞஻_5.115x10-5x1378x1()6B=0.2119~RT8.314x400ᢥ᯿¦©2-16aª(A)b__B_0.2119¦(2—16b)h(B)Vm~ZZὶ®12©Aªஹª©Bªuv°/kw+:°/±ᦪZh010.211910.57090.371220.50960.415830.53940.392840.52110.406650.53130.398860.52520.403570.52870.4008

23(IZ=0.5287,/?=0.4008ᔠᱥ+᥅JK³V=-=85287x8.31+x400=11-43,-i276xQmmolp13.78xl06(2)PitzerḄ$%ᓄ'()ᐵ¦ᔠᱥḄ¸¹ºᦪ஻=VK+%12=0.35x3042+0.65x3698=3468Kp=yp+yPc2-0.35x7.382+0.65x4.248=5.345MPaI>clcX2T400=1.15pr=346813.78=2.585.345*2—92—10+Z(o)=0.480,Z(1)=0.025CD=yco+y2G2=0.35x0.228+0.65x0.152=0.179}xᑣZ=Z<0)+coZm=0.48+0.179x0.025=0.4845ᵨ4:0.4845X8.314X4஺஺="693x1஺/H.)p13.78xl06''2-29.}kwᵬf(1)ஹf(2)¼½f(3)Ḅ¾᥅ᐗJᙠ373K
ḄB஺À:373K
=-20cm3-moÁHB=-241cm3-moÁ,B——61cm3-mol-12233B=-75cm3-mol-1,Â=-122cm3-moÁHB=-39Sbm3-mol-1]223ᵫ¦(2-45)ᓃ4஻ÄᐗJ+iJ8,”=y¥x8"+y¥xB+y¥x+2yyxB+2Å%x5+2y2y3xB”2212n13=(1/3)2X(-20)+(1/3)2x(-241)+(l/3)2x(-621)+2xl/3xl/3x(-75)+2xl/3xl/3x(-122)+2xl/3xl/3x(-399)=-233.44(cm3-mor1)2—29.}kwᔠᱥCO2(1)-n-CH|(2)ᙠ344.26K6.48MPa[ḄÉJJK஺À:40ᔠᱥÊCOḄ᥅ᑖᦪ³ᜐ=0.502,ÉJ᥅JKḄÌͳ2

24Vz=9.913xio-5m3molÎ▬ÊCO2(1)11-C4H10(2)Ḅ"ᦪ᝞
:ᱥ^TJK3ZcCD/MPaV¥./(cm-mor')co304.27.38294.00.2740.2282n-CdHio425.123.7962550.2740.166`ᵨ¦(2-63)V=4£ÒÓkw1HPa)¦ÊÔÕᱥ^ḄZRA`ᵨZc/ÖH×IZR.=Ø=0.2740.502x94.0ᵫ¦(2—65c)+—2ᓃÓ/ு2Úᓃ,=0.27090.502x94.0+0.498x255%=1oy=1-0.2709=0.72911-0=8M/ᓃ,Û/(ᔩ3+Ý3Þ=0(94x255)஺=09505ஹ/(94|/3+2551/3)05(12=(1-ᓰ2),Hx2=(304.2X425.12)x0.9505=341.8&=ZZà&=â&+ã&+2஺ä&iJ=O.27O92x304.2+0.729fx425.12+2x0.2709x0.729lx341.8=383.34KT344.260.8981383.34å^9ឌ/1=8.314x0.502x304.20.498x425.12X0.27è+(J"8981)2TᨨêE7.382xl06+3.796x106

252-2.ᳮ^_6ḄᱯabcdefᎷhᑖjḄᜧl᝞mnop᪵ᑖjr-sᙠuvYᵨᵫw᪵ḄᑖjxᡂḄ_6z{ᳮ^_6஺|}ᙢᳮ^_6-sᙠḄᙠ᩽Ḅ_6ᳮ^_6ḄYᳮ^_6ᜐᳮ/ᓄ⚪஺ᳮ^_6᝱.ᨬᓫḄ᝱.fpV=RT2-3.QjḄᭆLbcdbc⌕wᭆLdᔩdefᱥḄQj᪷<ᱥḄ_ᩭh¡Ḅ஺¢£᝱56¤¥⛳=_Ḅ¤ᦪ§¤¥¨NḄ᎔ᦪᕈ«¬ᐵ?ᓽ®ᔠflogpE=a-j]ᐸ·ps=—r¤¸-mḄ56aᐹᨵ-mḄº஺»Pitzer¢£ᓫ56ÁÂஹÃஹḄᡠᨵ_ᦪ<ÅᙠÆmᩩ¬ÈɬÁ=0.7,logpE=-1wp஺¤¸Íh56¤¥_άḄÏÐÑᵨᙠ7E=0.7Ḅ56§ÒஹÓஹÔÁᓫᳫÖᑖj×ḄlogpEºØᩭ⊤a஺PitzerÚwغh¡Qj0,ᓽᗂ=—log”f—1.00Þ=0.7×ßo56Ḅ0º,-ḄᙳᵫÉ56Ḅáâ¨N7Eஹáâp,ºã=0.7äḄ⛳=_psᩭåh஺2-4.ᱥḄ⛳=ç6Ḅ᥅é6êëḼ¨Nᓣîïᜧ⛳=_Ḅ᥅é6êëḼ¨NḄᓣîðlᔩdefñå஺ᵫᱥḄp-VòÈḄ⛳=_=⛳=ç6άó஺2-5.m¨NᱥḄ⛳=ç6§⛳=_Ḅឋᙳ-mᔩdefm¨NᱥḄ⛳=ç6§⛳=_ḄGibbs)ᵫumḄwᱥ_çõ⊝÷ᑣ஺_ùḄឋᙳ-m஺2-6.ᵨḄûüᦪḄ¤ý᝱þᳮᨵÿ
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26/᝱LMjklmᙢop89Ḅp-V-TᐵGq〉ᵨT;9f.ᵨᑮ;YZstuvlᜧḄxy஺z89Y;9Ḅ᥅e9a{᧕}~஺◀Z᜜ᱯ;9{aឋḄqᜧ஺◀/᝱LM᜜Mh⌱ᵨᐵG:ᓄᐵGLᩭ@஺2-8../᝱ᳮ஺᝱ᳮᙠYBḄ/᝱ᡠᨵḄᱥ⊤*YBḄឋ஺᝱ᳮ¡〉ᵨTp-V-TᐵGᦪ᝱ᳮ¢£Ḅ¤ᩭV¥¦§〉ᵨTCD¨©ឋ:ª⌴ឋḄᦪ:¬DᦪḄ᝱ᳮ஺2-9.᝞ᳮ^®ᔠ°ᑣ²³⌕)*\µᭆ·ᨵ¸]¹ºḄ®ᔠ°ᑣT»¼½9ᵫT¾ᑖḄÀᳮÁឋOᵫT®ᔠÂÃḄÀᳮÁឋÄÅᳮÁḄᑖ~Æ:ᑖ9a~ÆÇÈÉᙢʽ9®ᔠᱥḄp-V-TᐵG஺᝞Ë〉ᵨT7ᱥḄ/᝱LM᡽¦ᑮ»¼½9®ᔠᱥᓄ¨©ÍḄµ¨ÎÏ⚪஺ÑÒÓÔÕᵨḄLË/᝱LMÍḄᦪ⚗⊤×ᡂ¾ᡂxO7ᱥᦪ⚗ḄÙᦪ\
ÙᦪᐵGÚ-®ᔠ°ᑣ஺TqBḄ/᝱LMᨵqBḄ®ᔠ°ᑣ஺ÛÜ〉fḄ®ᔠ°ᑣ?@/᝱LMÍḄᦪ⚗ÄᐸkÈÉᙢÊ»¼½9®ᔠᱥḄp-V7ᐵG?@®ᔠ¨©ឋḄᐵÞ஺ᵨḄ®ᔠ°ᑣᒹà〉ᵨTáḄâãឋḄ®ᔠ°ᑣஹäåGᦪḄ®ᔠ°ᑣO〉ᵨTæLº/᝱LMḄ®ᔠ°ᑣ஺2-10.ᙠµçឋḄ{ᘤÍéᐭ§ImolḄë7ᱥ{ᘤḄ9aìmTíᱥḄ᥅e9aZ஺᝞îÄᐸï¨ðñḼó⚪á2—1Ḅp-TáÍḄlfC—2Ḅ⌶õöᓄCÎ஺÷ËíöᓄøM⊤×ᙠp-VáðÊᙠï¨øMÍᔜÎḄ/᝱:ú஺^ᵫTï¨øM{øM1—C-2ᩩü=ᓃḄ{ÿᡠᙠ0-⊤᝞Ḅ஺1⊤ᘤᡠḄᱥḄᔠᱥᵫ⛳⛳!"ᡂ$஺%1&2'⊤()*+,஺-Ḽ+,Ḅ/0ᘤḄ⛳!!12⛳!1Ḅ3456ᨵᡠ8ᓄ:ᵫ;8ᓄ<=ᜧ஺ᑮ@ABCC3B☢⌲FGᜫ஺IJ)*ᘤ&Kᙳ3ḄMABN!஺ᙠ᦮P+,ᘤᑁḄRS

272-11.[;SO?ᙠ431KbcdஹcfViriallᦪᑖopB=-0.159m3kmor1,C=9.0xl0-3m6kmor2,}~p(3)SO2ᙠ431KஹlOxdPabḄ᥅!1(4)ᙠlᑁIkmolSO2ᵫlOxdPaឤ(431K)⌮Rᑮ75Xl()5paCᡠḄ஺p(1)f⚗,pZ=£K=1+O+K(A)RTVV2p=10Xl()5pa,r=431K,B=-0.159m3-kmoF1,C=9.0xl(T3m'¡ᐭ(A)£᦮ᳮ¥p0.27

28pᵫ▬Öf×¥ᵬÊḄABØᦪp=190.56K,p,.=4.599MPa,=----------------------------U.ZUoJRT8.314x323.15ᢥ᯿2-16a
Z=----A_1=_L__2.2342—l-/z+1-h\l+â3,bB0.20832—16b
h===Vzz§¡~㩪Z=l,§¡+,¬äb⊤஺§¡åᦪZh010.208310.87790.237320.88260.236030.88230.236140.88230.2361TZZRT0.8823x8.314x^23-15=1.265x10-4m3/mo1V=------=--------------------l=126.5cnimoFp18.745x1

29..V©,125m=M!=16x-------=15.81gV1265äᵨRK,~æçèÎϪ஺2-13.éᙠ&P7810cm3Ḅêëᐭ1kgḄìÊíᙠ253.2࠷bâîêëḄïᐰâRSlOMPa,ñᔲïᐰóp×¥ìÊḄABឋp=369.83K,p,=4.248MPa,஺=0.152m1000n=—=------=22.727molM447810X1Q-6=343.63xl0-6m3-mor'n22.727RTaôᵨRK,:V-h~T0-5V(V+b)✌ᐜᵨb~”ha=0.42748R2q25/pc8.3142X369.83250.4274&=18.296Pam6-K05-mor2(4.248x106)=0.08664x834x36983=6ml]()-5m3,/?=0.08664x4.248xlO6¡ᐭRK,¥pp=9.S10MPaøùçèúlOMPa,ᦑᨵ&üᓻ◅஺2-14.}ᵨRKS,~ÿ
ᙠ300K,3.704XQpaḄ⛳Ḅ᥅஺V=6.08lx10-3m3,mof1஺ᵫ▬
ḄᦪT=407.8K,p‘=3.640MPa,(V=0.177cT=T/(=300/407.8=0.7357r/«=0.480+1.574y-0.176ty2=0.480+1.574x0.177-0.176x0.1772=0.7531a(T)=[1+m(\-T,0-5)]2=[1+0.7531(1-0.735705)F=1.2258(8.3(407.8)2xl.2258=1.6548(Pa-m6)/mol2a(T)=a!«(T)=0.427$/.«(r)=o.42748xp3.640x106h=0.0866(7)/p=0.08664x8.314x407.8/(3.640x106)=8.0700x10-5m3/mol(

30A=ᑶ+5,;./=஺.஺912=8.070(X10-5x3.704xl᮱no,B=RT8.314x300ᢥ᯿+(2-16a)▼,ஹ=bB0.01198+(2—16b)h=—=VZZABCD=EFz=l,ABIJKLMN⊤஺ABPᦪZh010.0119810.91480.0131020.90700.0132130.90620.0132240.90610.0132250.90610.01322VY0.9061x8.314x300=6.1015x10-2m3/molP3.704x106Z[(6.031-6.1015)x10~2/6.03lx10-2=—1.2%2-15.\ᑖ^ᵨRKbJcRKSbJCDᙠ273Kஹ1000Xl()5paN=fḄghij=Z=2.0685஺ᵫ▬fḄᦪ(=126.10K,Pc=3.394MPa,co=0.040(1)RKbJa=0.4274n212.5/=042748K(8.3oᡭx?2610.$=554fl>a.n?.K஺$.moF''3.394x106,_0.08664x8.314x126.10C_b=0.08664RT./p=--------------------------------=2.6763x1i0n5m3-mol°03.394xlO6,ap1.5546x100x106…A===)------^—7~~~=1.8264R-T2i(8.314)-x(273)-5bp_2.6763x10-5x1OOOx105D—.1/jz1RT8.314x273

31|Ahhᢥ᯿+(2-16a)Z=--------------1.548\-h5114-/?\-h1+/?<.=bB1.1791+(2—16b)h=—uVZZABCD=EFZ=2,ABIJKLMN⊤஺ABPᦪZh020.5895511.8620.633222.12600.554631.69260.696640.88230.2361ABvᦈx=yᵨRKbJPbJ:V=0.00004422m3/molZ/V4.422x1Of*1000x1()5=1.9485~~RT~8.314x273RKSbJT=7/7),=273/1261=2.1649rw=0.480+1.574y-0.1=0.480+1.574x0.040-0.176xO.O4O2=0.5427a(T)=[1+w(l-[8)]2=[1+0.5427(1-2.164905)]2=0.5538a(T)=«-a(T)=0.4278R27),2//?.-«(r)=0.42748xfc^^|^i-x0.5538=0.07666=(Pa-m6)/mol(b=0.0866(/=0.0866E8.314x1261/(3.394x106)=2.6763x10-5m3/molap0.076663<1000xl05A=1.4882R2T2(8.31@2*(273)2bp_2.6763x10-5*i஺஺i(pᵱBRT8.314x273Ahᢥ᯿+2-16az=-----1.2621஻811+஻\-h+(2—16b)=41Vzz

32᪵ABvᦈxyᵨRKSbJPbJ:V=0.00004512m3/molrpV4.512X10-5X1000X105/—___=______________________=1.9881~RT~8.314x2732-16.\ᵨNᑡᔜbCDᙠ107.9Xl()5paஹ593KNḄ,¡¢⊤£Ḅᦪ¤(V=0.01681n3.kgT)¨©ª஺(1)ᳮ¬®(2)¯°bJ(3)±²ᓄRKbJ´▬µḄᦪ(=647.13K,p,=22.055MPa,CD=0.345(1)ᳮ¬®RT8.314x593V=4.569x1Ofm'=0.025381?1p107.9xl05bH0.01687-0.02538Z[u------------------xlOO%=-50.5%0.01687(4)¯°bJ593=0.916647.13p107.9X105P,7T-22.055x1060.489¹ᵨ±²ᓄḄºu¯°»ᦪ:0.422=0.083—0.422/(L6=0.083—=-0.402671.60.172B{'}=0.139-0.172/7)42=0.139--0.10967)4-2½=+coB<'}=-0.4026+0.345x(-0.109^=-0.4404RT(Z=1+J=1+K.=i+x(-0.4404)=0.7649RTRT0.916''C

33ZRT0.7649x8.314x593V3.495x1CT6m3.mo¿=0.01942n3kg-1107.9xl03P0.01687-0.01942irin/Z[=-----------------xl00%=-15.1%0.01687(5)±²ᓄR-KbJiQ,,hz(2-38a)1-h$T+h(2-38b)ÀÁ.ÂÁgÃBᐭ¡᦮ᳮḄ:1h1Z=------5.621-h+6l-/z1+஻,Clp0.04625hrn=-----=--------ZTZrὶÇÈÉÊ+AB$Z=0.7335ZRT0.7335x8.314x593=3.3515xl0-6m3mof1=0.01862n3-kg-'V107.9x10sP“0.01687-0.01862iᜩ[=-------------------x100%=-10.4%0.01687Î᩽ឋªÑḄᱥÓ2-17.\ᑖ^ᵨ(1)vanderWaalsbJ)(2)RKbJ)(3)RKSbJCD273.15KÀCO2ghᑮ550.1cm3-mof1ᡠ◤⌕ḄgÃ஺3.090MPa»´▬µCOaḄᦪT=304.19K,p,=7.382MPa,0=0.228c(4)vanderWaalsbJRTaP~V^b~VTݵa=27R27X(8.314)-X(304.19)2=0.3655Pa-m3-mof2/64A=64x7.382xl061PT,Q8.314x304.19.-531-1b=RI'/8஻=-------------=4.282x]1n0m-mol"c8x7.382x1()6RTa_8.314x273.150.3655269x106Pa=3.2p=------6-6=3MV-bV755Q1X10-4282X10(55Q1X10-6)-

34%=3.090-3.269O=5.79%1(X)%3.090(5)RKbJRTa77-----------------V-bT°-5V(V+b)+µa=0.4274P2ß/04274&(83àx(304.19)=6.459á11?.K05-mol2cc7.382X1O6,_0.08664x8.314x304.19__,3b=0.08664RT,/஻,=---------------------=2.9n6A8Qx1i0n5mmol7.382xlO6RT________aP~V-b7=(â+஺)_8.314x273.15___________________6.4599_________________55Q1x10_6_29.68x1O'(73.15)05x55QlxlO-6x(55O.l+29.68)xlO-62=3.138xlO6Pa=3.138MPaanon_a1aoZ[%=X100%=-1.55%3.090(6)RKSbJRTa(T)P~V-h~v(y+h)+µ=a(T)=a-a(T)=0.4278R2?)2/p-a(T)ca(T)=[l+/n(l-T,05)]2ã=m=0.480+1.574y-0.176y2=0.480+1.574x0.228-0.176x(0.228)2=0.829720.5ஹᑣ=a(T)=[l+m(l_7)°6)F=273.15l+0.8297x1-=1.089304.197a(T)=a-c(7j=0.4274S?27)2/p■00஺4274&(8.314)(304.19)*jcQ89''''''7,382xl06=0.403330am3mof1,CCQAODT/0.08664x8.314x304.19__…b=0.08664RT/p=--------------)------=2.968x1i0n5m3-mol=c7.382xlO6_RT_a(T)8.314x273.15_____________0.40335=P—V-b—Vfy+b)—55(11x10-6—2968x10-655ft110-6x(55Q1+29.68)x10-6x=3.099x106Pa=3.09^VlPa

353090-3099%=3u”uxl00%=-0.291%3.090ªêbJḄCDKL=ëM=vanderWaalsbJḄCDZ[ᨬᜧ=RKSbJḄCDîÂᨬï஺RKbJḄCDîÂðëñ஺2-18.ò(Un?Ḅóôõöᑁøù
=.Â290KஹgÃ25Xl()5pa,úÀù
ûüᑮ479K,\ýDgÃÀþÿ
Ḅᦪ7=305.32K,p=4.872MPa,=0.099cT=TJT=290/305.32=0.95p=pjp=2.5/48.72=0.513rXcricᦑᵨ2-11,ᵨᓄᦪ!"n4??B(0>=0.083-0.422/716=0.083-=-0.375r(0.95)'60τ7?Bw=0.139-0.172/%=o.139-'=-0.074zx(0.95)-2Z=1+(=1+(B<0)+—|=l+(-0.375-0.099x0.074)x^^-=0.7935RT\(Tr)0.95^05935x8314x90.v==2=765xl()5(m3morl)p25x10s'7஻=%=—,_=3922(mol)rV76.5x10-5/0123ᵨRK4567!"஺ᐸ:T=479K,᥅<=>?ᯠV=76.5x10.5nrLmoA2✌ᐜ!"a=0.42748R2/2,5/0.4274&(8.31Dx?05.32)-=9.87E.n?.K0-5-moF2)''4.872x106G),CCOZ,DT,0.08664x8.314x305.32,/Hஹb=0.08664/p=-----------------------------=4.5C1]/4txlO]n55Im3-mol)4.872x106'7JᐭRK45RT_______aP~V-b5V(V+b)_8.314x479_________________9.879_______________765.0X10-6-45.14X10-6(479)05x765.0xl0-6x(765.0+45.14)xIO-6=4.804x106Pa=4.804MPa2-19.᝞MNOP22.7kgḄQᙠ294KSTᐭ0.085m3ḄUV:2WXYZ

36[▬]^_`QḄᦪT=282.34K,p,.=5.041MPa,co=0.085cm22.7x103n=——=--------81Q7(mol)M28᥅<=>V=ᓃn="q=104.8x10-6(m3.)n81Q7'73ᵨRK4567!"஺✌ᐜ!"a=0.4274vw“4274&(8.3ভx(2823{=7.851(Pa-m6K05.mor2)5.04IxlO6ஹ7,CCQAODT/0.08664x8.314x282.341\b=0.08664RT/p=--------------------=4.034xlOIm3-molI,c5.(Mlxl06')JᐭRK45_RTaP~V-b5V(V+._8.314x294__________________7.851_________________104.8x10-6—4034x1-6(292104.8x1(T6x(104.8+40.34)x10-60x=7.817xl06Pa=7.817MPa2-20(ᵫᓫḕᶍ2ᶍ!)2-21.ᵨPitzerḄᓄᐵ!"ᵬᙠ323.16KSwnḄXY஺ᵬḄ᥅<=>1.25Xio-4m2,morl,XYḄE1.875XI07Pao[▬]^_`ᵬḄᦪ7=190.56K,o’=4.599MPa,+@Zপ(B)᪷²³A
ஹ³B
67´J2µ5³5
¶ZE2ᯠ1Jᐭ³A
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37(6)᪷²7p,E_(2-9)(2-10)`ᑮZযZপ(7)P_`ᑮḄZ¼ZপEJᐭ(B)·`ZE(8)¾ZḄ!"E¿E2᝞MÀ¥ᜧ2ᑣJᐭ(A)ÃÄ!"2ᑮ´JᦈÆ஺Dz¬È´JªMp,=4.06S2Z=0.877Éijp=p-p,.=4.599x106/?,=4.599X106x4.06=1.867x107PacÎ¥(1.875-1.867)X107/1.875X107=0.43%2—22.¤ᵨRK45!"ÐᓄÑÒḄÓᑖÕᔠᱥᙠ151࠷13.78MPaØḄ᥅<=>஺!"ᡠ◤Ḅᦪ²ᑡ⊤᝞ØÜᐗT/KPcX10-5/PaVxl06/(m3-mor')Z,«/(Pa-m6-K0-5moP)fe/(m3-moF1)5CO(1)304.273.8294.00.2746.4602.968XIO-25C3H8ফ369.842.482000.27718.296.271XIO-12335.454.72140.411.12ᵫ(2-51a)(2-51b)`a=y஺”+2y,y«|+y\a=0.5'x6.460+2x0.5x0.5x11.12+0.52x18.29M2222=11.75Pam6-K05moF2b+yZ?=0.5x2.968x10-5+0.5x6.27lx10-5=4.415x105(m3-mof1)M2211.75x13.78x10^A=Q6322R2T25(8.314)-x(424.15)2sR»MP_4.415x10-5x13.78x106D—U.1/NDᢥ᯿(2-16a)-3.608bB0.1725(2—16b)ὶí·45(A)ஹ)(B)67´J!"`:´Jïᦪ

38010.172510.67760.254620.60930.283130.59870.288140.59760.288750.59750.2887Z=0.5975,/?=0.2887ZRT0.5975x8.314x424.15,c2,Õᔠᱥ`᥅<=>:V=------=-----------------------------=1.52x10m3-molp13.78x1()62-23.ÕᔠðñḄឋñóôᨵᐶ÷ḄẆùú⚪஺¤ᵨRKSü᝱45!"ᵫR12(CC1F)22R22CCHC1F2)ÜᡂḄÓ᥅<Õᔠðñÿᙠ400Kl.OMPa,2.0MPa,3.0MPa,4.0MPa5.0MPaḄ᥅஺ᐗᔠᱥḄ!"#ᵨ%ᦪᑠ2=0(*+,-./01)஺013ᡠ5ᵨḄ67%ᦪ᝞9⊤Dᐗ(/,)COᓅ/Kp!MPacR22(1)369.24.9750.215R12(2)3854.2240.176;<01=>?ᐜ01ABCDᑖḄRKSHᦪIJᵫᔠLᑣNOᔠᱥḄRKSHᦪWIXYZ[01I\];^_`>Ḅ᪷஺*+ᜧc,->dXY01஺ᡠOḄefᑡh9⊤:77K400DᡂX=%=S55RKS`>HᦪDᑖ(1)Iᐸ3%ᦪ⚗<_0.08664CR7,hPa

390.427480Wry&=-------------------Pcij(3)5ᵨ^⚗`>Iᦪgτ=14x10",B--265X10^,22B=-9.5x10^,(BḄᓫm3.morl)஺Q=1.3xl0-9,C=3.025xl0"9,i2222C=4.95x10-9,=7.27x10-9(cḄᓫ.mo-)஺wxyzḄ67ll2C|22%ᦪN7=126.1OK,.=3.394MPa,CD=0.0402nCHio(=425.12K,p=3.796MPa,0=0.1994c;<(1)᪷KayLᑣ]ᔠᱥḄ¡¢67%ᦪ4=03X12610+0.7X425.12=335.41Kip=Zy,Pc,=03x3.394+0.7x3.796=3.675MPaIKico==0.3X0.040+0.7x0.199=0.1513¡¢£¤ᩩ/a=+2«%%2+¥°22b=yᔣ+y2b2

400.4274®2¯OPc\2DᐗT/KpcxlO5/PaVcxlO6/(m3-mor1)Z.a/(Pam6-K05-mor2)Z?/(m3mof1)11126.1033.9490.10.2921.5552.676X10-522425.1237.962550.27429.018.067XI0-512231.5334.37158.50.2837.012a=0.32x1.555+2x0.3x0.7x7.012+0.72x29.01=17.30Pa-m6-K05-mot2Mb=0.3x2.676x10-5+0.7x8.067xl0-5=6.450x10-5m3-mol-1MZ__J__a(_h_\__J______________17.30__________(hஹ~l-hbRT'5\\+h)\-h6.450xl0-5x8.314x(462)''5[l+h,b___bp__6.450x10-5x69x1()5_0.1159V-Z^T--Zx8.314x462—-ZXYu¹Z[OO<69x1()5v1.326x1()71.455x10-3----------=1-------------1-----------8.314x462VV2u¹];O

412-25.ÆÇIÈÉᜐᳮ454kgᵬzÏzḄÐ᥅ᔠᱥ஺Ñᙠ50Xl()5paஹ422K9ÒÓÇIuÔÒÓÇḄÑÕ᳛×ØCH?ÉÆ|?;<ᔠᱥḄᑖÚM=+0.5M„=0.5x16.04+0.5x30.07=23.06rᔠᱥḄÕ᳛IâÁᡠ◤ᦪᑡh9⊤Iᐸ3ä^Yᦪᢥ᯿(2-48a)~(2-48e)01஺iJ7/KPc/MPaV.../(m3-kmor1)Zcij%11190.564.5990.098600.2860.01122305.324.8720.14550.2790.09912241.214.7010.12050.28250.055èᵨ▤ê⚗Ḅvirial`>01ᔠᱥḄឋìI◤⌕01ᔠᱥḄî"ävirialᦪ,01efï9⊤Ið)ijBy/(m3kmol1)11-0.03530.133-0.0116522-0.1680.0948-0.0828712-0.08940.1226-0.03528ᵫ(2—46)O

422-26.&N2ḄᔠᱥIᢥᔠᡂö÷áḄᓄù0Ú¤Iúᐭᑮ÷áᘤ3N+3H=2NH,22ᔠᱥX÷áᘤḄý600X105Pa,þÿ298K,᳛6mᐸ15%ḄN?ᓄN%,ᘤḄᑖḄ!"ᵨ$%&'(1)*+,-ᡂ/012N%?(5)4ᘤ56ᱥ(8N%Ḅ9ᔠᱥ)Ḅ;<550Xl()5paஹCD451K,$FᙠᑁID=0.05mMᑁḄN/0OP'(1)QRSTUᐗ9ᔠᱥWpVTḄ%&F⚪஺"ᵨRK]^_`%&~T^h~bRT'5117A,<aVZRTa=y%u+2yy2a12+£%b=b4+y2b204274᱐2]dPc\2eᐗT/KPcX10-5/Pa^.xl06/(m3mor')Z,a/(Pa-m6K05moI2'஺/(m’•moF1)c511(N)126.1033.9490.10.2921.5552.676XIO-2522(H)33.1813.1364.20.3050.14271.820XIO-21264.6821.0376.450.2990.4727a=0.252x1.555+2x0.25x0.75x0.4727+0.752x0.1427=0.354Ta-m6-K05-mol2Mb=0.25x2.676x10-5+075x1.820x10-5=2.034x10-5m3-mof1MZ_J__a(_h_\_J____________0.3547________(hஹ~\-hbRTX5\\+hJ\-h2.034x10-5x8.314x(298)1'5<1+/?>b___bp__2.034x10-5x600x1()5_0.4926V--Zx8.314x298-SZ_`$nopq'Z=1.424r=0.346

43-*…)᥅t᳛n-,Xi஺=1.020x10'(mol-h-1)58.8N2Ḅ᥅t᳛'=0.25X1.020x1o5=2.55lx104(mol-h-1)-ᡂḄNHu'2.55lxl04x0.15x2=7.653xIO3(mol-h-1)3v2wQRSTxᐗ9ᔠᱥWpVTḄ%&F⚪஺yz"ᵨRK]^_`%&ᘤ56ᱥeᡂ'{ᐭ6lmolN2~N'1—0.15=0.852H'3—3X0.15=2.552NH'0.15X2=0.303ᑣᱥḄu'0.85+0.30+2.55=3.75ᔜᱥḄ᥅tᑖ᳛:0.85=0.230-7752.55y»2-=0.6893/75_0.30_nn2]"+S^^75S°08i{NH3xeᐗ⊡ᐙᦪ᝞:eᐗT/KZe«/(Pa-m6-K05mor2'Z?/(m3-mof1)Xm/Paᓃxl06/(m3.mo)c33(NH)405.65112.7872.50.2428.6832.591X10-5313226.1762.081.00.2673.66623116.0138.668.30.2741.109+᱄+஺33+2bb42+2Mᐜ3+2y2y3a23=0.232xl.555+0.6892x0.1427+0.0812x8.683+2x0.23x0.689x0.4727+2x0.23x0.08lx3.666+2x0.08lx0.689x1.109=0.617(Pam6-K05mor2)b=yᔣ+yb+=(0.23x2.676+0.689x1.820+0.081x2.591)x10-5M22=2.079xl0-5(m3-mol1)

44J___MJ___________Q-617(gZ=l-hbRt^l=+h)\-h2.079x10-5x8.314x(451)211+/1=---0.372f1-/?U+/J£=_bp_=2.079x10-5x550x1Q5=0.3050~V~Z^T-Zx8.314x451—¦Z_`$nopq'Z=1.250§0.244ZRT1.250x8.314x451¨”,-Z3ᵨvn6V-------=--------------d------=85.22x10Im-molIp55xl06''ᡠ{{_6N2Imol~ᐭ6ᱥḄu'l+3+0=4mol56ᱥḄu:IX(1-0.15)+3X(1-0.15)+lX0.15X2=3.7mol®Ḅ᥅t᳛'ᱥ᥅t᳛X3.7/4=1.022Xl()5x3/4=9.45X104(m3-mo)®Ḅ¯᳛'85.22x10^x9.45xlO4=8.O53(m3-h-1)v_8.0538.053=4103.4(m•h-1)=1.140(m-s-1)N᳛U771c23.14/4x0.052—xD-42-27.´qᜩᯠv᥅teᡂCFU84%ஹN?9%ஹCH7%wᙠ;<9.27MPaஹCD37.8C26Ḅ¹ᙳ,N25m3.hT஺$ᵨ»]¼%&ᙠ᪗¾¿ḄN஺v1wᳮÁ]^dv2wÂÃÄÅÆᦪdv3wDaltonÈÉÊËÌᓄ;ÍÎÏÐdv4wAmagatÈÉÊËÌᓄ;ÍÎÏÐ஺P'v1wᢥᳮÁ¾᝱]^d᪗¾¿NPM/9.27x25x273v(273K,0.1013MPa)=201(h?-hTZPi(37.8+273)x0.1013v2wÂÃÄÅÆᦪ¼✌ᐜ"ᵨKay×ᑣØ5ÂÃḄÄÅCDÊÄÅ;<%&ÙÚᑡ⊤᝞:eᑖ᥅t/%£/Kpc/MPayTcfKypc/MPaᵬß0.84190.564.599160.073.863

45ä0.09126.103.39411.350.305åß0.07305.324.87221.370.341ᔠ%1.00192.794.510ÂÃÄÅCD192.79K,;<4.5IOMPa,9ᔠᱥḄ¹ᙳ;ÍÎÏàᵫᑡâãCDÊâã;<Ø5'.37.8+2739.27…uT.=------------=1.61,p,=-----=2.055r192.794.510èéÆᦪËÌᓄ;ÍÎÏÐq'ê;ÍÎÏpᐭ]^=q:V=ë=0.89x8.3ᜐí+273)={1஺S/.r')248mop9.27x106'7n--=----------=1.008x10smol-h-1=100.8kmol-h-1V2.481xIO-4ᙠ᪗¾᝱;ÍÎÏZ=l,Îï¯᳛à{qᑮ'I,RTice஺1rV8.314x2733.-1v-n-V-n---=10(18x10x-----------=22585mhp0.1013xl06(6)DaltonÈÉÊËÌᓄ;ÍÎÏèËÌᓄ;ÍÎÏÐ,ᔜᱥḄ;<"ᵨᑖ;eᑖZyizXiTT=—TP,=PMZPcᵬß1.637.7871.6930.900.756ä2.460.8340.2460.980.0882åß1.0280.6490.1330.960.0672ᔠ%0.9114ê;ÍÎÏpᐭ]^pV=ZRTC:V=ë=0.91ᐚ8.314ឌ7.8+õ)=஺ö.)2541x1p9.27x106''n=-=———~-=9.839xl04molh-'=98.39kmol•§V2.541xlO-4ᙠ᪗¾᝱;ÍÎÏZ=1,Îï¯᳛à{qᑮ'v=n-V=n---=98.39x1()3----------=22045mhxp0.1013xl06

46(7)AmagatÈÉÊËÌᓄ;ÍÎÏᐜèqᔜᱥḄ;ÍÎÏ÷"ᵨᑖ¯ÈÉ_`%&eᑖzyiZiTT=—Tp,=»DPcᵬß1.632.0160.880.739ä2.462.7310.990.0891åß1.0281.9030.320.0224ᔠ%0.8507஺ZjRT0.8507x8.314x(37.8+273)^øᑘ=ZxU=2.37lx104m3•mol-1p9.27xlO6n=—=——=------=9.839x104mo1.k=105.44kmolV2.371x10-4ᙠ᪗¾᝱;ÍÎÏZ=l,Îï¯᳛à{qᑮ'v=n-V=n——=105.44x1()3X—------------=23625m3-h-1p0.1013xl0ft2-28.$ᑖúᵨ»]¼%&CO2(1)Êûß(2){3.5'6.5Ḅ᥅tã9ᔠḄ9ᔠᱥᙠ400KÊ13.78MPaḄ᥅t¯஺(1)RK]^üᵨPrausnitzýþḄ9ᔠ×ᑣ(ÿ=0.1)(2)PitzerḄᓄᐵᦪ஺(1)RKᵫ▬CO(1)(2)Ḅᦪ!"#$ᐭ(2-48a)&(22-48e)'((2—13a)ஹ(2-13b)*+,-.Ḅ/0᝞2U%/KPc"/MPaV./(m3-kmol')ZciCIJ%11304.27.3820.09400.2740.22822369.84.2480.20000.2770.15212335.45.4720.14040.27550.19035ᐗ^/(Pa-m6-K°5-mof2)Z?/(m3•mof1)5CO(1)6.4602.968XI0-2CMIs(2)18.296.271XlO-51211.12

47ᵫ(2-51a)(2-51b)a=y12ali+2yya+yla=0.352x6.460+2xO.35xO.65xl1.12+0.652x18.29M{2n22=13.58Pa-m6-K05mor2b+y^=0.35x2.968x10-5+0.65x6.27lx10-3=5.115x10-5(m3-mol1)M22A=?/UH/2”P_5.115x10-5x13.78x1()6B==0.2119~RT8.314x4001A(h\ᢥ᯿BC2-16aET^h~~B\J+h)(A)0.2119B(2-16b)(B)ᓃZZὶIJCAEஹECBE*+K$,-:K$NᦪZh010.211910.57090.371220.50960.415830.53940.392840.52110.406650.53130.398860.52520.403570.52870.4008W:Z=0.5287,஻=0.4008.[\t4c33T,ZRT0.5287x8.314x400_,,._-g]ᔠᱥ1H᥅abdeV=------=-------------------------=1.276x104m-mofp13.78xl06(2)PitzerḄᓄᐵBJ.]ᔠᱥḄnopᦪ஻=q+%(2=0.35x3042+0.65x3698=3468Kp.=yp+yP-0.35x7.382+0.65x4.248=5.343vlPa/x1cl2c2

48400=1.15T3468pc3=2.585.345r2—92—10Zt=0.480,Zপ=0.025(o=yco+ya)=0.35x0.228+0.65x0.152=0.179]i22ᑣ᧤”Z=Z<0)+gxᵨτ+ygxB+ygxB+2yyx5+2M3xB+2yyxB2233t212l32323=(1/3)2x(-20)+(1/3)2x(-241)+(l/3)2x(-621)+2xl/3xl/3x(-75)+2xl/3xl/3x(-122)+2xl/3xl/3x(-399)=-233.44(cm3-moF1)2-29.|,-]ᔠᱥCO2(1)-n-CH(2)ᙠ344.26K6.48MPaḄbbd஺4l0]ᔠᱥCOḄ᥅aᑖᦪeX]=0.502,b᥅abdḄe2W=9.913xio-5m3-mol▬CO2(1)11-C4H10(2)Ḅᦪ᝞2:ᱥTJKp!MPaVg./(cm3-mor1)ZcCDcco304.27.38294.00.2740.2282n-CqHio425.123.7962550.2740.166஻=£¡¢”JT,-ᵨB(2-63)Pei)B¤¥ᱥḄZRAᵨZc$¦ᑣZR.=ZX,ZR4=0.274

490.502x94.0ᵫB(2—65c):§=2ᓃ“/»/0.27090.502x94.0+0.498x2554=1-4=1-0.2709=0.7291I2=(1_(2)Jᑐ®2=(304.2X425.12¯x0.9505=341.8&=஺c+±£+2᪻£=0.2704x304.2+0.729fx425.12+2x0.2709x0.729lx341.8=383.34K344.26=0.8981383.340.502x304.20.498*425.12ஹxo.27/+(i$98i)2"]V=RX=8.314x---------------------7-----1-----------------------7----I7.382xl063.796x106)i=88.76xl0-6(m3moF1)QQ1Q_QQ76¸¹%=X100%=10.46%99.13º⚪3-1.ᓫ5ᐗ½bḄ¾¿ÀÁÂᐵBᨵÄ#ÅÆᓫ5ᐗ½bḄ¾¿ÀᐵᒹÈ'2ÉÊC1E¾¿ÀÁÂËÌ〉ᵨÎÏÐËÌÑ'ᵨᓫÒᡈÔÒÐ஺dU^TdS-pdVd”=7US+VdpdA^-pdV-SdTdG^Vdp-SdTC3EØÙÚÛCMaxwellEᐵB

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)05256xl(r”(72y)=70250J-mol-1SASMWn£+C?dT...0.1013~.o8.3141n--------+8o.31410.13XP6615(3.056+5.3708x10-3T-0.8098x10-5T~+0.5693xl0-87,3-0.15256x10-"T4)—J255.15v773.056xIn1^+5.3708x10-3x(7
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2)+Xxc…0.1013°c,,8.3141n--------+8.314x10.130.15256_^_,4j^^10-◘3_xl()llx47=-38.287+17.897=-20.39U-mol_1K-1H="|+AH=H
H+H2=0+0+70250-42336=279L4(J-mo)S2=S|+AS=S1-S+ASᩩ@5,,-ᓄ.ᜐCᳮEF᝱ḄᯚHI8377J-moN9I25.86JmoPQ◤⌕*+Tᩩ@5,-ᓄ.ḄᒕVᯚWX;<,-ᓄ.ḄYZ[ᦪI=304.19K,p<.=7.382MPa,6)=0.228473230T=———=1.556,p=-------=4.064r304.19r7.382᪷bc2—11,eTfᵨ%&ᓄḄᯚgcW᱘gcij*+,kc(3—4)>(3—6),(3—8),(3—10),ᑖnoᑮ:

60T=S85,*324ᵫt(3-87)o:Jᒹ1+e1-1.75+0.228x(-0.1)=-1.773RT

61᝱I”f=o,sf=o366.152.026᝱Tr2==1.1992,pr2=0.4158305.324.872᪷bc2-11,eTfᵨ%&ᓄḄ,¡ᦪ*+஺Bw=0.083—^^=0.083—,=-0.23267
(1.1992)1-6Bপ=0.139—^=0.139--~—=0.0588C#2(1.199042dB(0)_0.675_0.675=0.4209dT~T26(1.199§6rrᔳ=©஺.72,807dT
T
2Qi9«2ᵫt(3-78)oHK_FB(0)dB(0)(B(,)dᓽ1-~RT~Pr~TdT^+((\ydjfJrr=0.41J-0-2126_0.4209+0.09j®¯0.28071]51.1992\1.1992)\=-0.2652HR=-0.2652x8.314x36615=-807.3OJ-mot'ᵫt(3-79)oSR----~~Prr´+co=^—=-0.4158(0.4209+0.099x0.2807)=-0.1866RdqdTrSR=-0.1866x8.314=-1.55Iffmor1-K-1(2)*+ᳮEḄᰚ¸W¹¸=P(ITJT)P=6"(10.83+239.304x10-3T-73.358x10-6T2)dTJ255.15ஹ/=33VT)+»¼½Y)¿ÀÁy)=857677J-mor'

62..D.(*366.15CS'g=0+ASf—^dTppJ255.15T2=8.3141n01013+I'"”(10.083+239.304x10-3T-73.358x1(T6T2)Â2.026"s'7T=2.7386Fmor'K-1(3)*+᝱Ḅᵫt(2—30)W(2—31)o:/=ᘊ=1+3Ä+Å).Æஹ="(°2326+0஺99஺.஺588஺)><◌=஺ᑜ4Ê=0.9214X8.314X36615]஺Ë.nwN)=1384xp2.026x106''2ÌÍH?=Hஹ+AH=H_H+\Hig+H=0+0+857677-807.30=776947஺•moF)S?=S|+AS=S]-Sf+S+Sf=0+0+2.7686-1.5511=1.217^Jmor'-K'1)t/=/7-pV=7769.47-2.026xl06x1.384xlO-32222=4965.5(J.molt)3—12.1kgÐÑÒÓᙠÔᨵÖ×ḄØÙÚI6.89XlO^Pa,I260࠷஺᝞ÝÐÑÞßàá⌮ãäᑮ2.41X105Pa»æÑÒçḄèIéêëᙠÍìíÚÑᔾᦈḄðIéêëQ:ñF᝱I=26(JC,P]=6.89*1"Pa
᝱It,=26(JC,p=2.41xlO5Pa]kÐÑÞòñ᝱W᝱ᙳIìÑF᝱kìÐÑ⊤஺⚪ÚḄWHö÷ìkøìÐÑ⊤ùᑁúoᑮ÷ìk⊤Wᑁú*+oᑮU௃=273398kJkgS,=7.1775kJkg-'-K-1U=2745.24kJ-kg_1,S=7.6814kJkg-1-K-122᪷bûü¡ýḄþÿAU=Q+W
⌮ᡠ

632=TAS=(260+273.1^x(7.6814-7.1775)=26&65kJkg-'=(274524-273298)-268.65=-257.4kJ-kgTᦑḄ257.4kJ,ᙠᔾᦈḄ268.65kJ3-13.ᘤᑁ!᝱#$ᙠIMPa%&'ᜐ)*⊝,᝱-IkgoᎷ/ᘤᑁ!᝱$ᔜᓰ23456ᘤᑁḄ!᝱#$Ḅ7ᯏ஺::/ᨵ!3mkg,ᑣᨵ(1-m)kg>⛳$#⊤ᙠIMPa'⛳$$!3ḄABᑖD4=5.144kg-m-3,Pi=887.15kg-m-3ᑣ34ᑖD3.l4tH-OO/.IDE᯿⚪H=1I5.144887.156:JK=0.9942kg,ᓽᨵ⛳$!30.9942kg>⛳$#⊤JᑮᙠIMPa'$!3ḄᯚOᑖD:H=27777kJ-kg_1,H,=76288kJ-kg-1xᑣ7ᯚOH=H(1-m)+H,m=27777x(l-0.9942)+76288x0.9942v=774.46kJ1dV3-14.K$᜛ᑖDQ%RSᦪ$UVSᦪᐸXYZ=Vydp0஺\)]^,᝱'Ḅ!3K$᜛_QT$2Ḅ`aᦪᙠT,pbᓄefQgᜧḄᩩj'klᜐᳮᡂ^ᦪ஺op!3q(r“A)bᓄᑮ(t,P2)ᐸ34qᓃbᓄᑮᑣInᓃ■=z(♦—7])—K(P2—P஺

64(dvyಘ"”=0\)!3$Kkl^ᦪᦑq(7],ᓃ)E᜛2,ᓃ)4ᑖJ:ln£=4஺—A)—K(P2—PI)[3-15].ᙠT-S$1”Hឋᙢ'ᑡ(1)%ᓾᓾᡂ!3(2)⛳$⌮%R(3)k⛳$,᝱Ḅ!ᔠᱥKஹᡂ(4)⛳$!3ᑖD¢$£UVᡂ¤஺(5)!3%Kᡂ஺3-16.¦ᙠUV§¨©⌮UV஺¢᝱ªBA230Kஹ%&0101.3Xl()5pa஺(1)±⌕6ᙠUV³r´fµ!¶5³%fJ·)¸¹º(2)±³%1.013Xl()5pa,¦!»¼¸¹º³ª¸¹ºUV§\᜜¾¸¹º(3)±¿¢᝱]⁚Á▀UV1.013Xl()5pa,³ª¸¹º:(1)>¦ḄT-SᐸÃ᝱71=230K,“=101.3Xl()5pa,>JÄ=96kcal-kg-1M⌮QÆÇÈḼ£ÊqÃ᝱ᑮË᝱⛳$!3(ᓽÌ)⛳$!»Ê´)´%&>J:P2=8atm(2)±ÈḼ£Êᑮ%&latm´ᑣᑮr!ᐳÑÒ>J´T2=84KÔ´“2=62kcal-kgT,⛳$,᝱ḄᰚOᑖDH,=22kcalkg-',=69kcalkg-,

65HÖx/r+(i-×”/62=xx69+(1-x)x22x=0.851ᓽ!»¼1-0.851=0.149ᵫ&ÛÜX´z//=Ý="2-”1=62-96=TAkcalkgjUV§\᜜¾34kcal-kg-'(3)±Q]⁚Á▀UVᓽQÆᯚqÃ᝱ᯚUV%&1.013Xl()5pa,³ª192KÞ⚪3-1,ᓫàᐗÁ3Ḅ&ÛâãᐵSᨵåæºçᓫàᐗÁ3Ḅ&ÛᐵSᒹé'êë(1)&Ûâãìíî〉ᵨ)ñòSóíîᵨ)ᓫ»ᡈ¸»Só஺dU^TdS-pdVd஻=7US+Va஻dA^-pdV-SdTdG^Vdp-SdT(2)Helmholtzì,ᓽûḄüᦪ7=
1asJp(¦)Y1=-s=(M=(3)ýþÿ(Maxwell)ᐵτBUM⚪('=(MHST)P\dP\3-2.ஹ!"#”ஹSḄ'()*+,ᨵ#஺Ḅ'(/0123ஹ!"#”ஹSḄ'(ᵫ5U=஻—“V,ᙠ=>?@ABḄpVTᐵ᪷FGHIᑖḄᑁLஹ!"#UḄ'(MNOPMᙢRS஺3-3.᝞UᳮRᒕXឋZ/)*+⌕\]G^ᭆ`/01ᡠbᒕXឋZcdBᙠefg᝱iḄj"kឋZlᙠm>ஹ!"idBᜐ5ᳮodBg᝱ij"kឋZpqḄrsᓽ1

66MR=M(T,p)-Mi8(T,p)Mlu&ᑖw⊤ymm!iefABlᳮodBḄzj"kឋZḄ᥅|}᝞kUஹHஹSG஺◤⌕ḄcᒕXឋZc>^ᎷoḄᭆ`ᵨG^ᭆ`NO⊤y]efg᝱lᎷoḄᳮodBg᝱pqj"kឋZḄrsNOPMᙢ]efg᝱idBḄj"kឋZ஺ᒕXឋZG>^ᭆ`cᵫ5efABḄᰚஹ◤⌕ᵨᑮefABḄjLᐵ#5efABᐸjLc!"Ḅᦪ,ᨵḄᐵὶ)RS⚪\]ᒕXឋZḄᭆ`G᪵NOᑭᵨG>ᭆ`PMᙢRSefABஹ!"ᓄḄᰚஹ⚪஺3-4.j"kឋZ¢⊤£⌕ᨵ¤¥¦§/᝞UᑭᵨB¨©ª«Ḅᱯᙠᔜ¯¢=°j"kḄg᝱/01±²]Ḅj"kឋZ¢ᨵ³>ᓃp-T,H-TஹT—Sஹlnp—Hஹ”>S¢ᐸµ஻>¶¢p-T¢ᙠ·Ḅ¸¹±@º»¼½¾¿)j"kᐵ⊤ÀÁcª=ÃÄÅÆᦪÇḄ¢஺ᙠª=Èᵨᙢj"kឋZ¢ᨵ1¨1«ᯏ¢¨ËH-T¢«OH)Íᙶ᪗T)Ðᙶ᪗஺¨2«᱘¢¨ËT-S¢«OT)Íᙶ᪗S)Ðᙶ᪗஺¨3«!ᯚ¢¨Ë1Ó>”¢«OInp)Íᙶ᪗)Ðᙶ᪗஺¨4«Ö×¢¨ËMollier¢">S¢«OH)Íᙶ᪗S)Ðᙶ᪗஺ÜÝÞ⊤cᦈàᨬzâஹᨬãᗐḄ>¯j"kឋZ⊤஺j"kឋZ¢Ḅᑴ¿NOæçÆ)è¨ᓽéê«ë᝞ìíÈᵨḄ஻ஹSé)îᱥZ>129࠷ḄòB஺NOᑭᵨ>¥fóᦪF᜜õNO᪷FB©ªḄᱯᑭᵨᔜ¯j"kéᐵ᝞j"kឋZᐵஹp—V—TᦪFö÷஺ᑴ¿øᱥZ¨ᒹúûd«j"kឋZ¢⊤c>^üÈýᩖḄ©ªᑴ¢µÿᐭḄᨵ▲ḄᜧḄᦪ⌱ᵨᔠ〉ḄᑮḄ஺◤⌕ᔜᓫ!"#$%ᐳ'"Ḅp—*+,ᦪ-◤⌕./ᙠ12ᩩ45Ḅ6789:Ạᦪ᝞=>7@ஹᰚ>TஹCDEᦪFஹP,#ᓃ஺m3-5.NOP5QRS7ஹ*TUVWXYZF1\]Wx,y,z,2=/Fx,jy\ᑏgzḄᐰiᑖTZF12=k\l+ndyx

67opZA=/(T,V)dA=-SdT-pdVᵫᐰiᑖឋxZ(y)=((2)dU=TdS-pdVz{R|}ᙠឤḄT52◀PḄdV:(஻3—6.XY(a)P*TWᯚWTXYZP7ஹVTWᯏWT-ᵫd"=7US+Vd஻(B)

68zFB
R|}ᙠឤḄV52◀PḄdT:M=7@v+yMzC
R#FD
RFA
R:ᓽZRXb
PpஹVTWᯚWTXYZPpஹVTWᯏWT-ᵫd"=7US+Vap(B)zFB
R|}ᙠឤḄV52◀PḄdp:

69zFB
R|}ᙠឤḄ8p52◀PḄdV:□5zFC
R#FD
RFA
RZ"IᓽZRX3-7.ᵨ5ᑡ¡¢$Ḅ£¤¥¦ᦪᙠ573.2K#506.63kPa5¢$ḄZஹ/oSR77K563.2573.2583.2B/cm3moP-125-119-113§Z7=573.2K,B=-119cm3-mor',p=506.63kPaᵫR(2-10b)Z-119x102x50663^Z=+=0.98718.314x563.2ᵫR3—64
:_dBHR—p-DB-1----dTT

70RSZ¨©ª«3¬ߟ)-7HRp-B-T—=50663x1x(-119xl0-6-573.2x6.0x10)dTT=-234.53(J-mor')ᵫR(3-65):SK=-.^-=-506.63x103x6.0X10-7=0.304(J-mol-1-K-1)p3-8.ᑭᵨᔠ〉Ḅ«³ᓄᐵὶRIkmolḄ1,3+·¸2.53MPaஹ400K¹º12.67MPaஹ550KḄAV,»"஺¼½1,3+·ᙠᳮ¿ÀÁ᝱Ḅឤ7ÃTZ=22738+2.228x1()77—7.388x10-572kj.kmol1K1,1,3+·ḄCDEᦪÄÅlÆÇT7@=425K,p,.=4.32MPa,Vc=221XIO_6m3-mol-1,fy=0.193%400K,2.53MPaA/7,AS550K,12.67MPa5Z-Sfᳮ¿Àᳮ¿À400K,2.53MPa550KJ2.67MPaAW/g,AS/g§:400253È᝱|=3=0.941,p=-=0.585ri"425"4.32„550.,12.67,meT-=----=1.294Xp=-------=2.929rr22’24254.32É᯿Ë2-11,È᝱ᵨ£Virial¦ᦪᐵ¦RÌ᝱ᵨÍÉᦪË(1)0.4220422ᓽ=0.083—0083-7-6-=—0.3821.6(0.941)160.1720172Bপ=0.139-=0.139-7Î=-0.083#2(0.941)42

71dBÐ_0.675_0.675=0.791dT~T2(X~(0.941)26rrdB'l)_0.722_0.722Õ7-TH—(0.941ÖᵫR(3—78)Z=68ØÙ+0.791+0Ú91-Û-0991=-0.8221=-0.822lx8.314x400=-27339J-mof'ᵫR(3-79)Zß+=+஻--+ft?--=-0.585(0.791+0.193x0.991)=-0.5746R[dT6TrrS_=-0.5746x8.314=^.7774-mot1-KJᵫR(2-30)#(2-31):äFᓽ"ᓽ\.åW93X0.083ç=0.7526(2)ᳮ¿ÀḄᰚW#èW\H>S=PC^dTMp=£^(22.738+222796xlO^T-73.879x1Q-6T2)dT222796x10-*73.879x10-6=22.738x(7@-7@)+x(r2-r)Fí-î223=16760mor1n,,366.15Cf»S'g=ASf+ASZf=RlnA+f—^dTPpJ255.15T2=8.3141n+ô”‘(22.738+222796xl0-3T-73.879xlO-6T2)—12.67%00'/T=22.0021-mof1K1(3)ᵫ7@2=1294,p,2=2929øË(2-9)#(2-10)ZZÐ=0.64,Zপ=0.20

72Z=Z(°)+ûপ=0.64+0.193x0.20=0.67862ZRT,0.6786X8.314X5503QV,=—2~-=------------------------=244.91x10Im-moF•p,12.67xl06'7øË(3—4)ஹ(3-6)^(3—8)^(3—10),ᑖüᑮ:-1.2,-0.45RᵫR(3-87):HQHL=-2.1+0.193x(-0.5)=-2.197RTRTRT,CCHR=—2.197xR7@=-2.197x8.314x425=-776L22(J-mot')2ᵫR(3—88)Zý+——1.2+0.193x(—0.45)——1.287RRRSR=-1.287xR=-1.287x8.314=-10.699(J-moF'-K-')2(4)AH=-H+AHig+”ª=27339+16760-776L22=lL733xIO3஺•moÿ)A5=—Sf+A5'"+Sf=4.7774+22.002-10.699=16.080^-moC'-K-')AV=ᓃ=(244.91-989.21)x10^=-7443x10^(/«3-mor')U=AH-A(pV)=AH-(P2ᓃPM)=11.733x103-(12.67xl06x244.9lxIO-6-2.53x106x989.21xl0-6)=11.132xl03(j-mor')3—9.Ꮇᙠ300Kஹ1.013XGPaḄᰚ0,500Kஹ1.013XUPaḄᯚ஺ᑖ!

73300K,0.1013MPa----------------------------------------500K,10.13MPa0qRSf1ᳮ+,-ᳮ+,-300K,0J013MPa------------------->500K,10.13MPa56Ḅ789ᦪT-417.15K,Pc=7.711MPa,CO=0.069c3000.1013T”=0.719,=0.0131417.15-7.7117=⁐22_=1.199,஻,=IU=L3142417.157.711F᝱HIJKLH;=0,Sf=0᪷NO2—11,Q᝱RSTᵨVWᓄḄᯚYOZYO[\,]O(3—4)ஹ(3—6)ஹ(3—8)ஹ(3—10),ᑖ_`ᑮM°_12RT,RT,ᔠK஺72fcl-03RRᵫd(3-87)`QS"=-1.2+0.069x(-0.3)=-1.221RTRT,RTeCHR=-L221XR£=—1.22lx8.314x417.15=T2336(Jmo,)ᵫd(3-88)`qRi)°(c«Y—=+=-0.72+0.069x(-0.3)=-0.699RRRv'SK=-0.699xH=-0.699x8.314=-5.81Lmo,K)]▬opL,Ḅᳮ+,-qr⊤tdCvf=/?(3.056+5.3708X10-3T-0.8098X10-5T2+0.5693X10-8T3-0.15256<10-"T4)

74=8.314x£™'(3.O56+5.37O8xlO-3T-0.8098x1O-5?,2+0.5693x10-8T3-0.15256xl0-l,T4)dT3.056x(7—)+|ᗸ"~ᓝ”ᔩ(%5)+=8.314x0.5693x10-8g—IvL)05256xl(r”(72y)=70250J-mol-1SASMWn£+C?dT...0.1013~.o8.3141n--------+8o.31410.13XP6615(3.056+5.3708x10-3T-0.8098x10-5T~+0.5693xl0-87,3-0.15256x10-"T4)—J255.15v773.056xIn1^+5.3708x10-3x(7v-T,)-Q-8^98ig-5(7^2-Tv2)+Xxc…0.1013°c,,8.3141n--------+8.314x10.130.15256_^_,4j^^10-◘3_xl()llx47=-38.287+17.897=-20.39U-mol_1K-1H="|+AH=H
H+H2=0+0+70250-42336=279L4(J-mo)S2=S|+AS=S1-S+AS(3—6),(3—8),(3—10),ᑖ_`ᑮ:

75T=S85,*324ᵫd(3-87)`:Jᒹ1+e1-1.75+0.228x(-0.1)=-1.773RT

76F᝱HI¿HL”f=o,sf=o366.152.026Q᝱Tr2==1.1992,pr2=0.4158305.324.872᪷NO2-11,RSTᵨVWᓄḄÁÂÃÄᦪ஺Bw=0.083—^^=0.083—,=-0.23267v(1.1992)1-6Bপ=0.139—^=0.139--~—=0.0588C#2(1.199042dB(0)_0.675_0.675=0.4209dT~T26(1.199É6rrᔳ=Ë஺.72,807dTvTv2Qi9Í2ᵫd(3-78)`HK_FB(0)dB(0)(B(,)dᓽ1-~RT~Pr~TdT^+((\ydjfJrr=0.41J-0-2126_0.4209+0.09jÐÑ0.28071]51.1992\1.1992)\=-0.2652HR=-0.2652x8.314x36615=-807.3OJ-mot'ᵫd(3-79)`SR----~~PrrÖ+co=^—=-0.4158(0.4209+0.099x0.2807)=-0.1866RdqdTrSR=-0.1866x8.314=-1.55Iffmor1-K-1(2)ᳮ+,-ḄᰚÙZÙ=P(ITJT)P=6"(10.83+239.304x10-3T-73.358x10-6T2)dTJ255.15ஹ/=33¡T)+ÚÛÜY)ÝÞßy)=857677J-mor'

77..D.(*366.15CS'g=0+ASf—^dTppJ255.15T2=8.3141n01013+I'"”(10.083+239.304x10-3T-73.358x1(T6T2)à2.026"s'7T=2.7386Fmor'K-1(3)Q᝱Ḅ-¯ᵫd(2—30)(2—31)`:/=ᘊ=1+3â+ã).äஹ="(°2326+0஺99L஺.஺588஺)><◌=஺ᑜ4ç=0.9214X8.314X36615]஺è.nw)=1384xp2.026x106''2éêH?=Hஹ+AH=H_H+\Hig+H=0+0+857677-807.30=776947஺•moF)S?=S|+AS=S]-Sf+S+Sf=0+0+2.7686-1.5511=1.217^Jmor'-K'1)t/=/7-pV=7769.47-2.026xl06x1.384xlO-32222=4965.5(J.molt)3—12.1kgíîïðᙠñᨵóôḄõö÷LHI6.89XlO^Pa,»¼260࠷஺᝞ùíî,úûü»ý⌮ÿᑮ2.41X105Pa»ḄᙠᔾᦈḄ:"#$᝱&=26(JC,P]=6.89*1"Pa'(᝱&t,=26(JC,p=2.41xlO5Pa])*+,-#᝱.(᝱ᙳ$᝱-)*⊤஺⚪Ḅ34.56789:);*⊤<ᑁ>?ᑮ-:)⊤.ᑁ>@A?ᑮ&U௃=273398kJkg-S,=7.1775kJkg-'-K-1U=2745.24kJ-kg_1,S=7.6814kJkg-1-K-122᪷CDEFGḄ6HIJKLAU=Q+WMN⌮-ᡠQ

782=TAS=(260+273.1^x(7.6814-7.1775)=26&65kJkg-'=(274524-273298)-268.65=-257.4kJ-kgTᦑ&Ḅ257.4kJ,ᙠᔾᦈḄ268.65kJ3-13.JVᘤᑁX᝱*.ᙠIMPa56Yᜐ[\⊝$᝱-^IkgoᎷ`VᘤᑁX᝱.ᔜᓰJcde-fgVᘤᑁḄX᝱*.Ḅhᯏ஺:`ᨵXdmkg,ᑣᨵ(1-m)kg)⛳.*⊤-ᙠIMPaY⛳..XdḄm4ᑖo4=5.144kg-m-3,Pi=887.15kg-m-3ᑣdeᑖo&3.l4tH-OO/.IDp᯿⚪r&=1s5.144887.15g?&t=0.9942kg,ᓽᨵ⛳.Xd0.9942kg)⛳.*⊤NQ?ᑮ&ᙠIMPaY-.XdḄᯚ7ᑖo:H=27777kJ-kg_1,H,=76288kJ-kg-1xᑣ-hᯚ7&H=H(1-m)+H,m=27777x(l-0.9942)+76288x0.9942v=774.46kJ1dV3-14.K.᜛ᑖox5yFᦪ.{Fᦪ-ᐸK}~=Vydp0஺[:$᝱YḄXd-K.᜛xT.2Ḅᦪ-ᙠT,pᓄxᜧḄᩩY-NQᜐᳮᡂᦪ஺Xd(“A)ᓄᑮ(,P2)-ᐸdeᓃᓄᑮᑣInᓃ■=(♦—7])—K(P2—P-஺

79(dvyಘ"¢”=0[Xd-¤.Kᦪ-ᦑ¥¦(7]§,ᓃ)¨p᜛2,ᓃ)eᑖ?:ln£=4஺—A)—K(P2—PI)[3-15].ᙠT-S¬.1J”¥®rឋᙢ±§Yᑡ(5)³5´ᓾ-´¶-´ᓾᡂ´Xd'(6)⛳.N⌮¸5y¨'(7)¹⛳.$᝱ḄXºᔠᱥ-³Vtஹ+ᡂ'(8)⛳.Xdᑖo³¿.³À{ᡂÁ஺(5)´Xd³5tᡂ஺3-16.Âᙠ{ÃÄŸN⌮{஺#᝱34A230Kஹ560101.3Xl()5pa஺(1)É⌕gᙠ{Ȩ̈,XÍ-fË5?Î[(2)ÉË51.013Xl()5pa,ÂXÏÐË3{Ã᜜Ò(3)ÉÓ#᝱:⁚Õ▀{¨1.013Xl()5pa,Ë3&(1))ÂḄT-S¬-ᐸ"᝱71=230K,“=101.3Xl()5pa,)?×=96kcal-kg-1M¸N⌮xJÙ³ÚÛḼ³ÀÝ"᝱ᑮ(᝱⛳.Xd(ᓽÞ[⛳.XÏÝÌ)-Ì56N)?:P2=8atm(5)ÉÛḼ³ÀÝᑮ56latmÌ-ᑣᑮXᐳâã-)?ÌT2=84KåÌ“2=62kcal-kgT,⛳.$᝱Ḅᰚ7ᑖo&H,=22kcalkg-',=69kcalkg-,

80H=xHv62=xx69+(1-x)x22x-0.851ᓽXÏÐ1-0.851=0.149ᵫ6HIJKL-ÌA"=Ws="2-“1=62-96=-34ᓃ஺/î7{Ã᜜ÒMkcaLkg-[(6)Éx:⁚Õ▀{-ᓽxJÙ³ᯏ"᝱³ᯚ{¨561.013XlO'Ta,Ë3&192K4-11&(1)ñò”=30QX]+45Ἄ2+ᑁõ2(252+10%2)(A)ᵫ[᳝=l-x2ᦑ”=30(kj+45Qr+xx(25x+10x)2l2l2=30(k]+450(1-.)+M(1-û)[25%+10(1-2)]—450-14QV]+5x1-1(B)—dH᪷CH=H+(1—ÿ)()pox177_rr"Hஹ=H_ox{AHᐸ(J)”=T40+l-45xdxxᑣ:H=450-14(k,+5x-15x+(1-x,)(-140+1Or,-45x)y=310+1Ox,-50^+30^(C)ᨴ2=450-14"+5*_15x—ᑁ(—140+1Qx,-45x)=450—5x+3Qx'(D)(2))*=1+᳝=0ᑖ./ᐭ1(B),345ᐗḄᯚ”9:H=300/-mol}H=45Q/"/2

81=3>?59@;Bᢣᙠ᳝=0+᳝=1EḄὡ9GḄ᩽▲J஺)᳝=0/ᐭ1=C>3Hf=310஺/)L=1/ᐭ1=D>3Y=475J-mol4-13M'᪷O᥅QឋSTU᥅QឋSVḄᐵX3-T7ஹdMMM+(I-%1)---s,=M-X]%dXy^M=VE77T7XdMg=V+dZ1)daXy-dMᓃT7ᓝ2ghiV=109.4—16.8x,-2.64xdVdV--3n=—16.8—5.28o)y+q/ᐭᓃ9rḄ⊤t1dXydx}3r=92.6—5.2▢+2.64x'(A)%=109.4+2.64XN(B)ᵫ1=A>^ᵨ->1E,3X=89.96ᵫ1=B>^z>0E3ᓃ=109.4{|}V=Zx=4_ᓃ>ᡠ=—>+/=%—ᓃ>=%(92.6—5.2+2.64*-89.96)+(1-x,)(109.4+2.64x,2-109.4)=2.64X1-5.2&r+2.64x+2.64x—2.64xf=2.64%1—2.64x=2.64X](1—%,)

82=2.64%/24-14M'᪷OGibbs-Duhem(XjdMJr—03ឤឤXit+xdM=022“dM,dM,dM,ᡈx----L=-x-----=x-----122d\-d\x2^=,•ECX⁠vaXydx௃hiH=a+Z?jxf[{H=a+&x22sߟ^24+24᳝dx]MdHX[-----=-2Z?,%1+2b[X=2b]X](2-1)=-2Z?xxll2d%dH,dH,ᨵ^=%Eod%3஺4-15,ᙠ25࠷ᵫ22.5kgH2sO4T90kg50%£ᑖᦪ>H2s஺4¥¦§¨©ªᔠEḄ¬ᦔ®஺M'90kg50%ḄH2s஺4¥¦§ᨵ:H2s஺445kg,HO45kg2ªᔠ¦§ᨵ'H2s஺422.5+45=67.5^HO45Ag2ᐳ1125᱐

83ªᔠHSOḄ±²|X100%=60%24ᵫ³ᑭᵨᨵᐵḄHSO-HOḄᯚ±µ¶¨©஺242᪷O·¸¹ᑣ)/⊤25࠷50%H2s஺4Ḅ·¸º»¶¼½t=60࠷,¾²ᓽ|À¬ªᔠÁÂᐸîḄᯏJ|195kJ/kgÅ325࠷60%¦§ḄᯚJ|275kJ/kgᑣ஺=”Æ=1125x(—275+195)=—9000U4-17,ᵨᔠ〉ḄÈ᝱ÊËdÌᙠ460K,1.5x106஺EḄ⍎²T⍎²Xᦪ஺M'Å▬ÏÐ3'T=425.12/^P=3.796MPaÑ=0.199ceŵ2-11,(ஹᓃ»Òᙠµ2-11ᑖÓ¸Ôᦑ〉ᵨÖ×ØᓄÚÛÜXᦪᐵὶ1஺0422ᵫ1(2-30)3B(0)=0.083-=-0.2891AQOL61.082"0.172Bপ=0.139-0.0151.08216O1(4-86)ln4ß+Ñ8প]à0395ᑣln4.=Ô஽><(-0.28%0.19%0.019=-0.1041.082ã=0.9009ä==0.9009x1.5xl06=1.351x1wPa4-18,å1-dæçèᙠ478Kஹ6.88x10"PaEḄ⍎²஺M'Å▬ÏÐ31-dæḄéÓêᦪq=419.5Kx=4.02MPcÑ=0.187r,,“…eT478…ëcP6.SSMPa,ìᑣíî²íîä|T=—=-------=1.131P=—=-------------=1.711T41SP4.02MPaccê᯿µ2-11×ØᓄᐵX〉ᵨñµ[ஹᓃ»ÒᙠᑖÓ¸〉ᵨÖ×ØᓄµÅµ4-3~4-63'óß=0.700ô=1.091

84OIn4=Inõ°)+win÷Ina=In0.700+0.1871nl.091=-0.3405=0.7114/.==6.88x106x0.7114=4.894x1yPa4-19,ᙠ25࠷ஹ20஺஻஻ᩩúᵫ5ᐗ195ᐗ25ᡂḄᐗ§üªᔠᱥ5ᐗ1Ḅ⍎²þᵫ1ÿzஹ—50%1-80X|~+4Qv
ᐗ1Ḅ᥅ᑖᦪ£Ḅᓫ஺஺ᙠ7P(1)#ᐗ1Ḅ⍎%&
(2)#ᐗ1Ḅ⍎%(ᦪ
(3)ᐗ1Ḅ*ᑭ,ᦪ(4).□0ᦪḄ1%(ᦪ4Ḅ⊤3(ᐗ14Lewis-Randall@ᑣ᪗C᝱)஺Eᙠ25࠷ஹ20atm,1=502—80x
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(2)In/
(3)In.
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85Ew=£ߟjRT„_.bPᡈV=Z?H----ᡈZ=]4--------PRTdp(1)lᔠᱥḄ⍎%(ᦪ|}ᑏln0=J
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86x,(TஹPឤJ)xdxdIn2{

87•••´=Q+RTlnX|ᦑX^_=RT(7ஹ2ឤJ)Jinx,ᵫ஽=1(¹R஻2=G2)ºᑖᑮ¼½ᡂNV//-G=7?T(lnx-In1)222ᓽ/z=G+RT

88x2224-22EপÁInA=("+4Ã)ln&=A(%+y
Ã)ᐸᮞ=2g2-B“-3”=-9.5x2-14+265=232cm3-mol'N,InJ=——(14+0.72x232)x10-6=0.2332218.3145x4613ஹ=1.2626n-QHIn4=——(-265+0.32x232)x1O-6=-0.4458m41028.3145x461/=0.6403B=)\B[[+2_^]^2^12+y2-^228=0.32X14—2x0.3X0.7x9.5—0.72X265=—1325&C7??.“Ï)Vজ„8.3145x461-132.58x10-6=4]499x10-6஺/./"I)+B=-------
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89,0.08664^7
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90=(iM=a-0.634)x24.4“2694Yi=Px?e(1ä᳝)10.05x(1-0.3)(2)᪷TGE=RTXx

91/iiVG£=8.3145x318(0.31n2.2361+0.7In1.269^=10798(7-mor')᪷TAG=HTZxJn4VAG=RTZXjIn/xj-

92(yx)+xln(/x)]xx222=8.3145x31ὡo.31n(2.236lx0.3)+0.71n(1.2694x0.7)]=—535.3(J•஺w)AH(3)ìí——=0.437RTT᳤=³RTRTLJEVä=0.437/?T..a(G")_HE_0.437/?Lïw-x721_E0.437R,ᓝänஹ:/௄)------dT(ឤP,x)Tñ&=318K,7
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)

93=(a+b)(x_2)=(Q+b)(l-22)w02(aw஺)•.pôõ|ᙠöM¥øù஺4-25ìí---=AX,X,jᐗ1RT192.d(nGE/RT)fAþ/In%=[——------]TPdn1ᵫkÿ=—x=—2nnnGl_A/%…ᑣin”.()=(1)onnnnnx2ᡈIn%=AX(1—%)=Ajq2ᳮ!"ᐗ2,ln/2&4-1ᡠ*+In%,In/,G^/RT1+23ᦪḄᐵ7&89&:A=L᪗=᝱Ḅ⌱@!AB"ᐗCDLewis-RandallJᑣ+K=LMNOPQRḄ⌱@S஺UVGibbsXᵫZᙠ᳝=0,a=1AᜐC+_஺AB`a7ᦪbᔠdef⌕ᩩilimyl=1஺Xj->14-26noপᳮqrst=u⚗w=/(rP)=zᦪ{|}~஺(2)┯஺/'=(),\uid=0,\Hid=0wAG'"=RTZx,lnx,.஺0A5m=-7?Xx,lnx,.0(3)}~஺M*=AM—AM/!ᳮqrsME=AM”_AAT”=0(4)┯஺PfO,lim=lPf0P4-27noIn஺=y%(1+%)=(1-(1+%)=(1N£)%=%N

94MIn஺Ḅ᥅᪷In.=111_%^^=2_f1_3W=2£dy2=e1'%:¡=f4.,41=¢£ᳮln4=ln0+l-%¤¥=+-+1-f1-3¦=1-3£+2£u2./=*-3/2£=4%/-3ḕ2¤¨=f=0.5©o/=2.56&WPa£=3.29¬P,4-28no¤®NsA¯°⊝©²³´f-=f-µ᪗V,Iᑖ¸ᢣḄM®¯,s¯஺º®¯»¼+ᳮq½¾ᑣ7¿ḄÀuÁÂÃs¯Ḅ᪗=᝱⍎au'=£*,ᑣᨵ3ᵯ=y"tPy,=yPxii᝞ÈÉᙠឤËᱥᓽy.=Xj!Îᐗᱥ7ᩭÐᑣᨵÑ=D/Ò2!Ó⚪᝞Õ,=S67QE×Ø——=0.5XXRTAARB1d(nGE/RT)ஹ2••Iny.-[-]T.P.„-OS/Sy=e°.Aᳮ/“=e°5®

95%=e05ᵫß)=0.67YBnoX.=0.90560

96In/]=⌳'31_%)28910%0஺61-)2(18.82—14.93)28.3145x35Q889X1+100r(0.816%]+x)222,In%=."(%-0110989X2)2(18.82-14.93)20.5655r1KL8.3145x350889x,+100r2X3+1.224᝕252ᙠឤ89%,=0.525,x=0.47520.4617x0.4752'•In%==0.1276=1.1361(0.8165x0.525+0.475)20.5655x0.5252In/=0.1273%=1.1357(0.5255+1.2247x0473;<=ᦪ?213@ABCᜧ஺(3)EF=0.8Gx=0.22ᡭIJ,0.1635x0.22mᵨVanLaarNOPIn/.=------------------7=0.002544y1=1.0025(1.7543x0.8+0.2)2,0.0932x0.82Iny=-----------------------7=0.07140/=1.07402(0.8+0.5700x0.2)22RS21.0025x99.40x0.8”ny=----------=-----------------------------=0./9p101.3ᵨScatchardXHildebrandNO:=0.4617x0.2--0.02537/,=1.02569(0.8165x0.8+0.2)2”655x0.823]5/=1.39302(0.8+1.2247x0.2)22_ᶭ21.02569x99.40x0.8noiy=------=--------------------=O.o1p101.34-30c:᪷eWilsonNOln%=lTn(ZA/p-ZឌJk'kjXjijklᵨmnᐗ=pqirsḄᔜvᦪwᐭᓽz{|}nᐗ=pᔜ~ᑖḄ;<=ᦪP

97in/j=1-In(%)+XA+%A)-------------------------2I23I3X]+XA|2+3]32XAI343122IXA+%,+X3A23%,A+X2A32+x213]30.34=l-ln(0.34+0.33x0.5088)-0.34+0.33x0.7189+0.33x0.50880.33x1.18160.33x0.9751=0.030.34X1.1816+0.33+0.33x0.52290.34x0.9751+0.33x0.5793+0.33ᦑ4=1.03X]A]2x*3A322ln&=1-In^Aji+x+XA)-2323X,+XA+XA]2|+%2+X3A23%|A+%A+%2123|3312323_________0.34x0,7189=l-ln(0.34X1.1816+0.33+O.33x0.5229)-0.34+0.33x0.7189+0.33x0.50880.330.33x0.57930.34X1.1816+0.33+0.33x0.52290.34x0.9751+0.33x0.5793+0.33=0.183ᦑ=1.20X]A]3ln^=1?(ᑁ31+XA+)232+XA|+I3]322*2A23^,A+x+I3423X,A|+XX+X32123232_________0.34x0,5088l-ln(0.34x0.9751+0.33x0.5793+0.33)-0.34+0.33x0.7189+0.33x0.50880.33x0.52290.330.34X1.1816+0.33+0.33x0.52290.34x0.9751+0.33x0.5793+0.33=0.348ᦑq=1.42ᙠ50࠷}nᐗ=ḄPP=4%ᱏ°+ᵯ8+ߟ=(1.03x0.34x81.82+1.20x0.33x78.05+1.42x0.33x55.58)KPa

98=85.59KPa⊝GḄ~ᡂP1.03x81.82x0.34Xஹ…P----------------=0.33585.59r,P%1.20x78.05x0.33Xஹ…y=--=----------------=0.3612p85.591.42x55.58x0.33,ஹ=----------------=0.304y^=-P85.59