高物课后习题-何曼君版

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ᑖḄ᪀1ᑏᵫḄ1,3ᱥCH^CH=CH-CH=CH-COOCH„ᑮḄᔠᱥ!ὃ⇋ᓫ%Ḅ1,4-ᡂ'ᓫ%ᜮ-*+,ᑣᳮ/01ᨵ345%6᪀%789:ᓫ%1,4-;

1ᐸ¡ᜧ¢10919I910P}ᵫf0igᑣF£J4ᓫ%ᙠᐳᱥḄ¤ᑡᑖ¦1ᑮop/789£J4ᓫ%ᙠᐳᱥBḄ᣸ᑡmnᨵ¨4©ª«ᓄ¬!ὃ⇋Dᓫᐗ:(D)------V——V——V———V—V—D------------D—D—V------------D-----D-----D------£¨4᣸ᑡmnḄ8ᱥᑖ9zghᑮ£¨48ᱥḄ®ᡂq10:1:1:10,1LᐳᱥB⌕:D—D—D—Ḅ¤ᑡᑖ¦zᐸ¯J4©ªḄ°Q⁚²|.46´ᔠ⌕ᨵ1,4-'3,4-mnghµ¶⌕8ᱥḄ®ᡂ·ᔠḄᡂm¸ᨵ¹tᐵº஺S»µ¶ᜩᯠ¾¿Ḅ8ᱥBḄ¡96.693.4,Àf0igᑣÁᜩᯠ¾¿B6´Ḅᡂmn1ᑮop/7896´1,4-ᡂᑣ8ᱥ9C3】——3,4-ᡂᑣ8ᱥ:

2[ᵫghigÂ⍝A:B=96.6:3.4,1ᙠᜩᯠ¾¿B6´ᓫ%⌕qf1,4-ᡂmnr,zᡂ஺5ÎTÏÐÑᵫÒÓᐸÔÕÖ×ÁGaussᑖ¦Üᦪ<»ÂC-CNÞ1.54A,Nß109.5°,âã9পᔠå5xl04ḄTḄèᙳÔÕÖஹᙳmÔÕÖ'ᨬ13ÔÕÖ;ফÔÕÖᙠ+ioA'+1001ᜐ[Ḅ3᳛஺89পফᵫexp(-/2஻2)4n/22h0(±10A)=3.5X10-6(A)T0(±100A)=3.37x10-4(A)-1ᓽᙠ±100AᜐḄ3᳛ᙠ±10AᜐḄ3᳛ᜧ஺6ûKKa-üèᙳᑖ}1000M஺Mo⁚ᑖ}âþÿপᐰᜧᑖḄᳮফᐰ᪀ḄবGaussḄᙳ!"#ভ%ᵫ'(Ḅᙳ!"#ম*ᑁ'(,-.,-/ᦪ1☢=0.4389Ḅᙳ!"#য;<=>?ᑖᙠ%ᯠB᝱DEFᔁHḄIJᢣLMNOᔠᱥḄRឋ▲஺VWM?ᑖ-CH-^X]1=1.54A,]c0=109.52

3প%=Nl=2(1000%)xi54==^3080A3Qnm%(2)L=Nlsin-=2000x1.54xsin=251.5"஻ha22oব//=NL=4735(A)2=47.35(஻஻Z)2--------1__mq0ভ=M2=9486(A)2=94.86(஻m2r1+cos஺মn=NF1—COS஺l+(^£=24272(A)2=242.72(஻rs1+cos஺1-cos஺ᡈ(/i2)-=I5.6mnযwL>L>>
%2yIᡠ{ᜧᑖᜐ}%ᯠB᝱DFᔁHḄI~ḄᳮRឋ▲FmaxL/
«257?ᑖḄᑁ'('(cḄᐵ᝞Dᡠ:060120180240300360ᑁ'(:.x9-x{.e9ḄUe=12kJ/mol,.c9ḄUc=25kJ/mol,.gg'9ḄUg=UgI=2kJ/mol,£ᵫBoltzmann¨©ᳮ©ª.19«140࠷ᩩ®DḄ'(,-/ᦪcos஺.29¯?ᑖ°I]c112°,©ª²ឋ³´K¶ᜧhV.19/=0,±60,±120,±180
9Ui=0,012,0002,0025
*1-mol-'WN.°9='(¸ᦪIW413K,R=8.31J/.K«mol9ᵫBoltzmann¨©ᳮ=exp(-t//RT)/

4N(0)=exp(.)=lᑖ»©ª¼-12x1000N(±60)=exp()=0.03038.31x413N(±l20)=exp(_2xl00°)=0.55848.31x413N(±180)=exp(-25X1000)=6.862x1O-48.31x413____\N(e)cos½᜛J,exp(cos(pd(pcos஺=-^ߟ--------=.......--------fN((p)d(pÀexp(ÁÂ))d*ZN’COS/=--------(z=1~4)=0.4521ᧅ(2){]c8=112°,cos6=-0.3746_N/2(1—C0SI1+cos஺h2_1+cos01-cos(p1ÁNl211(137461104521^1-0.37461-0.45218ᎷÅOÆÇ}30࠷ḄᵬÉÊË°I̼Í᡾ÏÐÑ/MJ=835X10-4஻,஻,1²ឋwcr=Ó/⌆Õ=1.76,£×(1)MOÆÇḄÂᦔ%ᵫÙᔣḄÛ(2)*Oᔠ1000ḄÛᦪ஺Vߟ(-CH2_CH^jyCH~3Ḅᐰ᪀᝞Dᡠ:%)=42,Z=L54A,஺=109.5°.VÝÁ=1835x1CT'L=nlsin—=2-^—/sin—=5.99x103(wn)A/

5Þ_[835xl()T஻âÀâ(1)=1.17஻஻?L-5.99xl0-3(nm)AfL2_15.99X1(T35MFM2=216(ë)(M=1000x42)è[835é10-4஻஻êVÝì2/J2=I.762X2X1000X0.1542-3-=293.9(wn2)=<71-13ð=஻/sing=2x1000xO.154sin=251.5(஻஻?)/ip_293.9(1)4L7-251.5=1.17nm(2)N஺ë9òìó?ᑖḄOô᝱õ᪀1D⊤ᑡLøÁùOᔠᱥḄùõ᪀úᦪI£õᔠḄᓄüõ᪀Iᑖ᪆³þ~ÿḄ
ឋ,ᢣᙠᔜ〉ᩞᧇᛛᧇஹஹᵨ஺!ᔠᱥPDMSPIPPIBPSPANEC______11.4-1.61.4-1.72.132.2-2.42.6-3.24.2b=($/""L(nm)1.401.831.832.003.2620o'᪀ᓫᐗᦪ/,-4.987.381320./012ᑖ4,
ឋḄ567/EC

6Ck᦮Ḅᨔg᪷i01ᦪiZ⚜Kkᐰ'ᨔḄM᦮!OPḄmnopq஺Z4sVabcsinB./mnv=s=------------M(3X4)M°/NA6.666x20.87x6.488xsin98.12=1.067(^^-')(3x4)x42/(6.02xl023)iin3pqX?=—=-----=0.94x1O'(&gm—3)v1.067ᦻ.=0.95x103(.஻/3)3ᵫᦻL᪛ᾦḄpqg.=1.50x13-3o=1.335x13.-3Zᑁ!Pa¡E=66.67H஻?OLᓫᐗ஺¢ᨵsᙽḄg᪵1.42x2.96x0.51x10-6m3,¥¦T2.92ஹ10s3Zgᵫ01ᦪi§¨/1᪛ᾦg᪵Ḅpqo'ᨔq;2᪛ᾦḄᑁ!pq஺W70-3./(1)pq᜛=—=-----------------------=1.362x103(A/g-m~3)V(1.42x2.96x0.51x10-6)6p-p_1.362-1.335'ᨔq/=a=16.36%p-p~1.50-1.335cuᡈ¬=.%=18%PPc-PaAE66.67xlQ3(2)ᑁ!pqCEO=------=473(7-cm-3)(1/1.362x1()3)x192ᦻCED=476(J-C஻L)

74°±!OPḄᰚ³7´=176࠷,'᪀ᓫᐗ¶ᓄ¸=8.36/¹஺ᔆZg§»(1)¼ᙳ!ᔠqᑖ¾TOP=6ஹ10ஹ30ஹ1000Ḅ¿ÀZᵫ,-ᦔÂÃÄḄ7´ÅTÆᜧÈ(2)ÉᵨÊËÌᑖoÍᐳ!ZÏÊËÌᑖÐÑᐭᨔÓZgÔ§ÊËÌᑖᓰ10%᥅×ᑖᦪØᐳ!ᱥḄᰚ³TÆÙÈ./পsT"'HJDPmÛÜZÝ=176°C=449K,R=S.3Umor'K-',ᵨÐà¹áᐭâÛ§¨Lᑮ:&=337K=104࠷,Åå176-104=72࠷1,2=403K=130°C,Åå176-130=46°C7´3=432K=159°C,Åå176-159=17࠷æ=448K=175࠷,Åå176-175=1࠷çèZé£)P>1000ØZì,ᦔÂíîç0ïᶍ஺(2)ᵫñ4=0.10,X=0.90B11Rஹஹ,------77=------InX.TmT&òJ__J__8.317´-449-836In0.1:.T=428.8A/=156࠷m5ô'ᨔ!ᔠᱥᰚ³T200°C,'᪀ᓫᐗḄ᥅׶ᓄ¸=8.36஺¹஺õ஺Éᙠ5!ᔠᱥÜᑖ¾¹ᐭ10%ö÷ᑖᦪḄøùᛛᑺZÍûü!ᔠᱥḄýþÿᵨ
ᦪᑖ%=0.2-0.2,ᔠᱥ⁚ᛛᑺḄ᥅ᓃ/ᓃ=0.5,"#$(1)(ᐭᛛᑺ*ᔠᱥᰚ,ᔜ./01(2)23456(789:஺

811RV-=$>1?------7---------*+-.@01T„,T&V,,BCDEF஺=0.10,2Gy=0.2I11Qai—=—+--0.5(0.10-0.2x0.102)T4738.36mi=462.6K=189.5°C2GU=—0.2V᪵34XY$T=462.18ZC=189࠷m2>2?7\„-7\^=200-189.5=10.5࠷|7\„-7\°=200-189=11࠷2X`aὅḄcdefᜧFhiᑺḄcdᜧGfhiᑺḄcd஺6jkᨵ8mḄ5ᨔ0>op70%?,qrstᓄIFvḄwxystxyz{|}F~q/Ḅw>10-50%?s|}IFᐸᓄ,FᜧḄw>70%?s|}Iᑣᓄ,vᓣF᝞F"=஺=$PEtᓄXᓄ⊤$[C1]oCH2-CH2-CH2-CH2------►-CH2cH2---------CH-CHo2Cl(Cl=10%)[Cl]------»—CH2-CH2—CH-CH2—CH—(2—C1C1(Cl«50%)[Cl]------>—CH-CH-CH-CH-CH—CH—2C]ClClClCl(Cl>70%)ᵫGCl=35.5,CHC1=48.5,CH=14,2355qCl=10%IF10%=---------nx=2214x+48.5CICᓽqGqCla50%IFV᪵=Yx=1.6TCH2¡,oᓽqGciqC1N70%IF=Yx=l.l

9—fCH^nCH—2ᓽqGC1¤ᑖyḄ2¥ឋḄ{᦮ឋᩭ8FPEḄ{᦮ឋᨬªF5ᨔ0ᨬm\Ewst|}*FᙠC7W50%Fᑖy2¥ឋẚ¯F°5ᨔ0ᓄ,±\qa270%IFᑖyḄ2¥ឋᨵឮ³F´µ¶ᱥᓄ·0ᨵ¸vᓣF¹fºmGxPEḄᓄ·0஺»¼½mᑖyḄi¾ឋ¿1mᑖyi¾ḄᱯÁÂÃÄ1ÅrÆi¾ᡈÈᑖyÉi¾Ê8F᝞ËÌÍrÂoÎÉi¾஺=$¤⊤Ḅ8⚗ÐEFXÑÒrÓḄfV7Ômᑖyi¾ḄᱯÁ$8⚗Ðmᑖyi¾Æi¾Éi¾ᑖᦣ¿,ḄÖᜧᑖyÆØ10-10-10-8mÈᑖyÚ10o%×᡽ᦣÜÝឋ᡽ᦣ᠒FfßÝàáÝ᡽ᦣ᠒FfßÝàá᡽ᦣãFX7ÝàáÝ¿âÝââä¡åឋ¿æ⊝ஹéêëFì¤fæ⊝ஹféêëæ⊝ஹéêëFì¤ííi¾îᦪឋᨵF¹ïmz{íᨵFðñᐝåóTynda11ᦔ8öTyndal1ᦔÍ÷zTyndal1ᦔi=0ᨵzᨵi¾ø0ùᜧúùúû⌕¤ä¡åឋ¿vFX7ᑨþmᑖyi¾Éi¾஺2293KIG0.1LḄ
ᑴᜩᯠḄᜩᯠly3kg,991kg3,ᑖ2X105஺Ꮇ%&ᔠ()*+ᦔ-஺./0112Ḅ3ckg-L728229Ḅ᥅;ᦪn22>᥅;ᑖᦪX228329>ᑺḄ*+ᑖᦪজI,জ22CDEF1123஺=%/J=10-3/01=K12-2L.N2229᥅;ᦪn=W/M5x10-6(RS222253X1010'V=W/p=10-3/0.991=1.009X10-3(L)222V,=0.1-1.009x10-3=9.899X10-2(L)9.899x10-2x0.874=1.109(/716?/)0.0785x10-64.5x10-6n,+n1.109+5x10-62

1032*+ᑖᦪ1.009x10-3ᓃ஺20.012ᓃ+ᓃ9.899X10-2+1.009X10-3\=1]%=1-0012=0.9983/0^_`⏚_`bḄcᦪ஺᥅;dᔾfgᦪ1G’G/%•

115ᵨ⏚b\=19.62PVC6,=19.42ḄᛛᑺR¡Ḅ
ឋ£¤Rᐭ]¦§¨ᑺ£=16.3,ᑖ3502஺.©ª¦§¨ᑺRᐭḄᨬ〉CD?F1Rᐭ§¨ᑺḄ*+ᑖᦪ஺τ,®ᵫᑺ&ᔠ°ᑣ1b³=£\+61]\219.4=19.61—\2+16.3\F´\=0.06,µ=1-a=0.94,·⏚b100¸ᐸᑖ=326,஺஺6=.35஺100/326+^,7350%=6.85¸2612-ᵨº»uḄ“¼dᑣ”⌱¾¿ᑡ^ᔠᱥḄ〉Áᑺ1ᜩᯠÂ⏣⏚᪛ᾦᨵÇÈᴻ^Ê`ᨒ822᪷Í“ᑺᓄdᑣ”⌱¾¿ᑡ^ᔠᱥḄ〉Áᑺ1ÏᓄÐÑ^Ò_`ÓÔ6,^Õ⏚b832᪷ÍcᦪÖdᑣ⌱¾¿ᑡ^ᔠᱥḄ〉Áᑺ1×ØÂ^Ê`^_`ÙÚ᪛ᾦ஺F112¼dᑣ14—CH>-C=CH—CHfᑺ:CH3-^CH-C^21CH3-C-CH3CH3C-OC2H5COOCH3oo-4-CH2-CN22ᑺᓄdᑣ:Cell-ONO2ᑺ:

12-eCH2-CH^-O_C^CH3o_cஹCH3Cl-0=0oOHHQ+HClCH3o+*'Cl(3)cᦪÖdᑣ1-(-CHs-CH=CH-CHg^0ᑺ:%,=16.3\=16.7YCH2-QH)CH3ooo=lo.3p=19.43=18.2X■4CH2THÞCH3O2=17.568,=18.2OHᓝOCH2cH2஺-0.C2H2CI4à=21.98p=21.8d=24.38]=9.57ᵫáᑖḄ&ᔠâᵫãAG”2ä´ᐸᑺḄᓄåæçᓄèé2.ðñᙠóôᩩö¿áᑖᑺḄᓄåæçᓄêëᳮíᑺḄᓄåæçᓄ஺F1ᵫAG=RT

1312ᡃ«1‘In"=ln(l—ᮞ)—ᡃ—஺2y=3,ᑖᑺᑖ,x=V/V=1,ᑣᨵ2i*,=RT±=RTA^-=-RTDh=-RTX2xx%+xn2%+஻2"ᳮ$%AG(=RT[nInXj+nlnx]]22a.G(“0“!dn{T.P,n2ce8,%i%=RT—nIn--!—+HIn=-]2dn|_/+n_n+n{212VI=RT

14——=RTln:n+;1=RTln(l-x)«RTX22ᑣ=A/Zj=A//(8HugginsCᦪyḄᱥᳮGH᝞JKᙠMNOPQRSᑺឋU.VᑺஹXVᑺஹYZU0Ḅᐵ]᝞JKᙠMNᑺ^_S`ᔠbcOPḄᐵ]᝞JKdᵫfJZgh2ci=ᩩ.k_&02klRTᙠMNOPQnoτ<0ᓽA2<0nVᑺ](/I=0ᓽ=0nᳮ$%](/]>0ᓽt£|2ு0nxyᦪSḄᜧ{nᐸ^%<0.5dn=0.5_஺ᑺn%>0.5d஺ᵫM"=RTn/N

15<0,h”,“<()nᑣbG<0d(1nτ=0,\H=0,ᑣAG“,<0b%(moτ>0,\H>0,ᑣAG“nx\HḄᦪS"N஺mm9Mᔠᱥ%ᵫᑖM2=l()6ḄU(ᔠPx=l()4)ᑖMIO2Ḅᑺᡂn᪀ᡂ%ḄP_1%(ᑖᦪ)n(1)=ᔠᱥ%Ḅ`ᔠh5n"(ᑖ)((2)᯿ᳮ$%Ḅ`ᔠA5,“(ᳮ$)((3)ᔠᱥᑗᡂ1(/¢ᓫ{ᑖn¤ᎷN={ᑖᑺ᪀ᡂᳮ$%Ḅ`ᔠ¦§{(4)ᵫ¨©ª`ᔠ«Ḅ¬®¯°±¬²K_°±Kdᵫ⚪GnPc=l%´1—=1%——=99%ᔩ+ᔩᔩ+%¶=%_0.1kg,¸ᑖ0.001kg,ᑺ0.099kg,ᑣ᥅ºᦪ=W/M=0.099/0.1=0.99W1il%=%/%=0஺01/1஺3=10-6n_0.99ᑖᦪᵫ}=0.99n+xn-0.99+104-10-6t2»=1—᳤=0.01(1)AS,“(ᑖ)=—R(஻Jn0]+஻21n02)-8.31(0.99In0.99+10-6In0.01)8.27x10-2(1t)0.99(2)᥅ºᑖᦪ:Á஻i+஻20.99+10-6஻|+஻20.99+10-6

16AS,”(ᳮ$)=-R(஻]InÂ]+஻2Ex?)=-8.31(0.991nl+10-6lnl0-6)=1.15X10-4Q.K)(3)ᑗᡂ10'¢{ᑖ,᥅ºᦪ஽=0.99,“2=1/M0=É/ᵨ=1஺4/1஺6=0.010.99᥅ºᑖᦪ=0.99,x=0.0120.99+0.01TS,"=M/?(஻]EM+”21nx2)=-8.31(0.99In0.99+0.01In0.01)=0.465(JKT)(4)ᵫ¬ËAS,"(ᳮ$)

17RTx'%=16.7—(8.31x308x0.5='108=13.3("•*%)ᦻ,-.17.5(J%•cm%)஺11ᵨ4⊝6789:;ᓄᜩᯠ?ḄAὶCDᑮ᝞FḄGHᦪJKL?M᪵O.Wp=2.034xly3kg,ᙠ298Kឤ[\]^_`abc7—10d,eᑮ674⊝fgOW+W=10.023xl0-3kg,ᑮps298K`ḄjC0=0.868x103᱐-3,᥅mno1=89.3x10-6p3,*஺qᜩᯠL?jCp=0.997IxlO^gm-3,ᜩᯠL?u`Ḅvwxᵨyᦪz=0.437,ᵫ{ᦪJ|Aὶᑖ~pḈ஺ᓃ+ᓃ//+%/________________2.034x10-3/997.1______________-2.034x10-3/997.1+(10.023-2.034)x10"3/868=0.1815ᙠln(l_@)+a++=0Mc^ᵫ_஺2ᶍIn஺%^Ḅ⚗,'997.1x8.93x10-5&.Mc(0.1815ஹ%i100.437)=24,18012ᑏᑨ¡6ᑺ£¤Ḅyᦪ¥¦§¨©ᑖ¡ª«-¬6ᑺᑖ¡.®ᔠᱥḄ±6ᑺஹ²±6ᑺஹe6ᑺᑖ~ᙠ´µ6¶^Ḅ·¸ᱯº{»¼᝱¾᝞«¿ÀKA2ு0,%<,aு1.±6ᑺĬÅ஻,“<0,AG„,<0,6ÀÊËÌÍÎᑖ~Ïᙠ6¶^᡽ÑÒ

1842<°/i>஺<1.²±6ᑺĬԔ,“>06¶ÌÖvᑖ×ᑖ~ᙠ6¶^ØÙÚÛ=0,%=g,a=l.e6ᑺĬuᳮÝ6¶ḄÞßàᜫᑖ~ϲ7²Ùᜐ_µËᯠã᝱஺äåஹæç®ᱥḄᑖ~»ᑖ~ᑖè1éêë®ᔠᱥḄᱯឋíCuᑖ~îᔠ஻=0.03M°S¥ᨵ஻|=1()4஻2=1஺5ñᓫᑖᦣôᑖ஺õöñµôᑖ÷ᔠøᑖ¡ùDÄ=55,000=55,000»=55,000ḄµM᪵஺M|úµM᪵^ñôᑖḄOᑖᦪûªüý¿ÀKþ◤10
ᑖḄᑖᦪᑣ10.
ᑖḄᑖᦪ1-ஹ᪵:M“=1ᓽ55000=~~1—%---------104105•••%"=009%==091᪵[=!ឋ”]ᓽ55000=ᔤTO'+a—“IOஹ.•.%,=0.5,ᓽ10,&10'ᔜ()஺/,᪵K=Zᓡ"ஹi>ᓽ55000=[ᓺx104x0-5+(1-4J105x0-5]2•••ᔩ1஺°35ᔛ1e=஺.652ᨵ34Ḅ567893ᨵ20%:;ᡂᓫ>Ḅ?⊝>ABC>AḄᦪᙳᑖE80000

19FG8Ḅᓫ>ᑖE(஻0)H?⊝>AḄᙳᑖE(M“)ᔜIJ?:P—Pr12P(4>)(ᓫ>M஺)Mn=80,000ᵫ"oH2MoOᡂ,0.2/0.8»-M+-2MM0n2Mnᵫ“——ᓽ80,000=°coᨌU.ZU.o-------1---------M஺2M0M=48,000o0.220.82M+-(2M)20M2MᵫM=o0w—.A/+--2MOO;2M00.2x48,000+0.8x2x48,000=86,4000.2+0.83VᑖEᑖW1()5H1(/ḄX4ᔠᱥḄ[3
ᑖ\ᔠFG(1)10gᑖE1஺4Ḅ
ᑖ&1gᑖE1()5Ḅ
ᑖ]\ᔠF^_“ஹ”.ஹZ*(2)10gᑖE1஺5Ḅ
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ᑖ]\ᔠF^_“ஹ”,ஹ~M.Z(3)`abc[^_defghijdkl—11:প1/11=10,89°TMj104105___1()1=—xl04+—xl05=18,180THH_Zno10xl08+lxl010M&.=^-------=55,000ZnM10xl04+lxl05

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ᐗ⏚஺7-298K!"#$%&'Ḅ)*+ᦪ-᝞':10-2C(kgm-3)20.420.015.010.210.07.65.1n(Pa)10601037561.5251.9237.2141.167.6পBᵨ(D/஺)-஺(F/஺DG஺HIJKLᑖNOPQRSIKTḄUឋWXYZফBᵫ]UḄUឋ^ᑖ_᳛OP4a4஺b:cd(F/c)(ᐔ/C)2ḄZ:(n/c)(m)~~5.305?29^82~~2~52~~2?42~~L-89~~1.35

22(n/c)1/2(m1/2)2.302.3001.951.581.551.371.16047563ᑖNJP(7r/c)~C(4/c)-CK᝞'ᡠg:(UOO'M)0510152010'2c(kq.me°)ᙠm/c)-c]Unop(4/c)o==Lr0.3஻2Mn_᳛HL42=0.2(”4/gT)8.31x298M„=814,7000.3x9.8x10-3({/c)/c02x9.832A=1.9xl0-\cm-mol-g-)2RT8.31x298ᙠ(;r/c>-c]Unop({/c)=«0.7/??_᳛(RT)W£.a0.08(஻J/2,kg-')RT_8.31x298&.M„=515,700O.72x9.8x10-3,2x_᳛2xO.O8xlO6......3,-2ஹ1f4A=----
—-=--------------------------------------=4.43x10(cm•mol•g)2(RTM(8.31x-x298x515700x10-36xl09.8-r^-A^M0,43A?u=4^—M,MnMn4-=1(4.43x104)2x515700=2.53x10-2(cm6molg~3)8ᵬᡂ%&4.98X10G%ᨚ11Ḅ298K!"ᐸP&9.7XlO^Pas,ᙠ$ᩩ'ᵬḄP&5.6X10-4Pa-s,

23(1)ᵨGLcdᱯឋ&¢£;(2)¤¥¦§஻£=1.7¨10-4“஺.69a஺=2.1()2%஺©BcdPSḄªᙳᑖ¬(MQaªᙳᔠ&(X“)஺(3)OPSᙠ®ᩩ'Ḅᙳ¯°±p²஺9.7x10”b(1)r)=—1.73r5.6x10-4%³´3[2(0.73-In1.73)]^4.98x101=L21(d/gT)=(L21)%69=3.83X1()5(2)M1.7X1Q-4X„=^-==83'1஺5=3682M)104m2»বᵫ[஻1=F.½*´¿=(ÀÁÂ¥(p2.1xl(J-6.O2xlO-lo(nm)9333.0KᑺÅ(6ᩩ)!"ᐸᱯឋ&§nh=0.40dlgᙠᵬÅ$᪵Ç&'!ÈḄᱯឋ&n=0.84dkg‘Q¦ᙠ®ᩩ',K=l.15X104,a=0.72,BO(1)®Ḅªᙳᑖ¬M”(2)ᙠᵬÅḄGÊË̬J®ḄÍ᡾ÏÐ(K)”bপM”

24(2)஺%=ÑÒÓ128(3)Ô"2=ÕÖ%=0.40x2.32x1()5()G(°)G(2,1X10*2,=3.54x10-”)=35.4஺஻”)10¥¦B᪵ᙠØ¿ÅḄᑖ¬ÏФá᪗æÑÓçèᐝᦣê!È஺ᦪ-᝞'10%
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ôõ(4)2=----------4ql.37C__(0230X10-3)2`N,,°d(436X10-9)46.02X1023e=1.818x10y(஻/.³o/,ó-2)ö஺=-Rq“÷=ø4.85x10-3=3.23x10-4/ù/90()13cdᔜû%&aḄRbcKc/2%ü.10sR,»((n-,)7.7611.9514.8616.810'Kc/(2R90)(mol*kg-1)8.210.613.615.7JKc/Ñ2R90Ó-cᐵ
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ᵫḄᱏ=5.6x10-3(molkg),A/w——ߟ~=1.78xl055.6x10-3r—in3&.M=----------=1.78xl05W5.6x10-3rᵫḄ᳛=3.5x103,A=3.5x10—3=L75x10-3a(c“3a.mo/.g-29)2/.A=250=1.75x1O-3(cm3-mol-g-2)211⊈ᙠḄᦪ᡽ᦣᦪ,᪥$ᑮ293K&Ḅ'ᑖ)*4.41X10%+6.36107m2»s1,ᙠ293K,Ḅ-.*0.749X10"m3kg”,Ḅ/0*0.998XlOV-kg1«123⊈Ḅᑖ4567⊈817kg9:103kg;<ᑣ8>⊈ᑖ4:?@>;A4BCD“RTSM=-------=-----Dl-vep8.31X293X4.41X10~13X103-6.3x10-7
1-0.749x10-3x0.988x103=6.56Fe=?56஺—=3.86x104EA4Fe/ᑖ4F12GHIJᱥLᑖ4ᙠ293KḄMNOᑺEQ0஻o=3.22x10'ParF*ᳫTᑖ4஺ᵨVWᔠᱥY51g,.Z*106m3,[\ᐸ᡽ᦣᦪ*8.00X10"m2s"F஺23WᔠᱥḄᑖ45஺CD^Lᑖ4Ḅ-.=`<ᳫTᑖ4Ḅab=cᑣ

264M=7uR-N.IV3din-6V=Ar=10-3(m3-kg-')KT?&ᵫEinsteinNu:w*Boltzmann}ᦪ6Dஹ/ᑖ)*᡽ᦣᦪ+᥅ᦪ஺ᵫStockNuDf=6dR஻஺*OᑺQ0஺ckT1.38x10-23x293•R=--------=-----------------------------------6dD6^X3.22X10-4X8.00X10-'9=8.3X1()TO(M3&.M=—Ẅ'N/v4A3=1(8.3xlO-,o)3x6.02xl023/lxl0-3=1456(Zg•஺)ஹLWᱥḄᑖ45ᑖ45ᑖ1GHIWᔠᱥḄᱯឋQ0ᑖ45ᔠ77=0.03஻°$d<¡ᨵ=1()4+2=1()5£ᓫᑖᦣ¥ᑖ஺¦§£¨¥ᑖ©ᔠ<ªᑖ)«\¬D=55,000+=55,000=55,000Ḅ®¨1᪵஺128¨1᪵£>¥ᑖḄY5ᑖᦪ°±?@BCD^◤100¥ᑖḄY5ᑖᦪ*³.<ᑣ10,¥ᑖḄY5ᑖᦪ*1-4<´1´¨1᪵DM=——nMj

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283§ᑖ45ᑖ)*1()5+1()4ḄϨWᔠᱥḄ£>¥ᑖ©ᔠ,<12:(1)10gᑖ45*IO,Ḅ¥ᑖ1gᑖ45*1()5Ḅ¥ᑖÑ©ᔠ,<ÒÓᵨ"ஹ”Õஹ.Mz(2)10gᑖ45*1஺5Ḅ¥ᑖ1gᑖ45*1஺4Ḅ¥ᑖÑ©ᔠ,<ÒÓË“ஹËWஹMzi(3)-ÙcÚ£¨ÒÓÛÜ<\ÝÞßÛàB—11MD(l)M„_.=10,890wrn7TT>—-----+---->Mio4io5æ='è¼=é1()4+gxio5=18,180f_£¼10x108+1x1()1°0´-10xl04+lxl05-’—Mn1Ë17ᓃ777=55,000ফ=77Ty▢------«~----------T105104Ëw=ZíMxio5+—X104=91,8201111Mzy—(3)´¨©ᔠᱥ1᪵ḄᑖᦣឋD^^=1.67,ᡈ=^=3.03M“Mw·¨©ᔠᱥ1᪵ḄᑖᦣឋDM"1miMz=-=1.67,=11.n0Q8MHMÕïᑖ45éḄ¥ᑖðM஻ñòᜧ6ᑖ45ᜧḄ¥ᑖðM“.+Mñòᜧ஺z

294ôᨵ&ᑡ¨Wᔠᱥ1᪵DE1Fᑖ45*2X103Ḅ÷ø᪛ᾦ6E2Fᑖ45*2X104ḄWûüᨴ☘6E3Fᑖ45*2X1EF5ḄWÿ
4ᑖ2X106Ḅᜩᯠᐸᙳᑖᑖᢣ᪵"#ᵨḄᨬ〉'Ḅ()*+,-ᡠ/ḄᙳᑖḄ0123஺56189ᑖ᪆)Mn.VP0)M,,;2?@)M஻1,ᐝᦣC)M";3?@)M,,,ᐝᦣC)M;w4HIJ)M,,,?@)M.n5᝞MNOᔠᱥRSᙠឤVḄWXY᳛-ឤVḄ[\]Y᳛^_`abOᔠcde[fg஺hOᔠiᱥḄ”klᜧn56ᵫV3_N(M)MdMpN(஻)M2dM-M£N(M)MdMᵫ⚪2aᎷVNvᦪᑣyz{|ᑖ}~2/2MM3/32Mn=M=M~2wM2/2~3M4w=1.33M„~36ᨵAஹB,᪵ᵨ89V)ᐸᑖ஺,᪵Ḅᙳ0.311g,0.0259moldnf3KoH᪗VὑᵨḄ|ᙳ0.38ml஺1A᪵᪀6HfNH(CH2)6-NH—C—(CH2)4-C4^OHOOᐸᦪᙳᑖl+n2᪵BḄᦪᙳᑖ6.38X104,ᑣB᪵Ḅᑖ᪀ᱯ£᝞¤n3¥,᪵Ḅᔠᡂᩩ¨ᨵ¤©ªn

30ZW_lxO.3111xlQ356পM„(A)=31,610N-0.0259x0.38a(2)ᵫ⚪2M,,¬=2M"(4),"Z=2,ᑣB᪀HO-^C-(CH)C-NH(CH)NH-C-(CH)4-C^pH24262OOOO(3)ᔠᡂAzᐗ⏚°zᐗ±²'RSBzᐗ⏚c஺7O³´
-¶·¸¹º298K/©ª»@^ḄIJ¼ᦪ½᝞^:10-2-C(kg-m-3)20.420.015.010.210.07.65.1¿(Pa)10601037561.5251.9237.2141.167.6পᵨ(À/c)-஺°(1/c>-c,ÁÂ)ᑖhakÃÂÄḄÅឋÇÈÉ?(2)ᵫËÅḄÅឋÌᑖÍ᳛h&-4o561Ï(À/c)°ḄÐ:(n/c)(m)5.305.293.822.522.421.891.35(n/c)1/2(m,/2)2.302.3001.951.581.551.371.16047563ᑖÁ(/r/c)-c°-cÂ᝞^ᡠÑ:0510152010'2c(kq.m'a)ᙠ(4/c)-cËÅyÒÓ(;r/c)0P0.3mM஻Í᳛RLA2=0.2(஻J.AgT)8.31x298&.M=814,7000.3x9.8x10^(7r/c)/C02x9.832A2=J.9x\Q-\cmmolg-)RT8.31x298

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4/c>-cËÅyÒÓÔ//=⁐^«0.7/wnJÍ᳛(RTk°»0.08(W7/25)—RT8.31x2985M------=--------------------=515,700n0.720.72x9.8x10-32xÍ᳛2x0.08x106A?------~-=----------------------------------------------------=4.43x10(cm-mol-g)(RTMj(8.3lx-x298x515700xl0"3)"xlO69.811299pzp2zA”“r3_4_4-1)---A______—-'_____........-------------="&Mn2MnMnMn=1(4.43x104)2x515700=2.53xlO-2(cm6mol-g'3)48ÙOÚ
ºᵬÚÜᡂ»@4.98X10Ýkg-m-3Ḅº298K/ᐸß?@9.7XlO^Pa-s,ᙠäªᩩ¨^ᵬÚḄß?@5.6X10-4Pa-s,1ᵨåæ)1Ïᱯឋ?@ç];2é[஻]=1.7X10TM069-஺=2]xl2%0/T,1ÏPSḄᙳᑖ=/T=073[2(%-ln%)i[2(0.73-In1.73)]^[7J=---------------------=-------------------------c4.98xl()T=1.21
òóz(2)M=(ᓽ)%=(1-21õ)/69=353x1()5nK1.7x10M3.83xlQ5n=3682%104

32(ö÷বj!3ø÷=(ᔳ)J2x3%û(p2.1xl()~6.O2X1O-,O(WM)9OÚ
º333.OK¶é¸ᑺý(6ᩩ¨)/ᐸᱯឋ?@[n]“=0.40dlgþᙠᵬÚýª᪵ÿ
Ḅᱯឋ[n]=0.84dlgT,ᙠᩩ
,K=1.
Xa=0.72,(1)Ḅᙳᑖ“(2)ᙠᵬḄ!"#$஺&(3)Ḅ'᡾)*+প(084)%=2.32x1051.15X10-4(2)a=(/0=1.280.40(3)1ᡝ24")604)x2.32x105==02.1X1021=3.54xl()T°(%)=35.4(஻஻?)109᪵ᙠ;<"=Ḅᑖ)*>?@A᪗C()DEᐝᦣH஺ᦪJ᝞
103c(kg*m'3)0.71.42.22.9I”LM᪗)24374652?9;<Ḅᢚᐝᢣᦪn=1.3761"=ḄᢚᐝᢣᦪP(1,^=0.230X103(m^kg1),ᵯᐝRḄST02=436"1஺ᵫ@VᦪJWXM“>YA?஺K1——=4-2A2c+ᵫ2RMw

334"412x1.3762(0.230X10-3)2K=஻:]94234%(436X10^)6.02X10=1.818X10-42.a஺/.j-2)4k“2)2=4/x1.3762(0.230x10-3)2AX஺")(436X10-9)46.02X1023=L818xl()Y(p2.m஺/./-2)%஺=4rst=24.85x10-3=3.23x10-40,90()WXᔜwx
Ḅᡃ90YKC/2R90Z:lORoGif')7.7611.9514.8616.81O3KC/(2R,)(mobkg')8.210.613.615.7OKc/(2RQ-cᐵ஺103>M=1.78xl05w5.6x10-3103..Mw=1.78x1055.6x10-3ᵫḄ᳛=3.5x10",-=1.75x10-33,i•g-2)moA-—=1.75xlO3(cm3-mol-g~2)211⊈ᙠḄᦪ᡽ᦣᦪ,᪥ᑮ293K
ḄᑖA4.41X10%Y6.3X107%',ᙠ293K¡Ḅ¢£A0.749X10'm%kgLḄ¤A0.998X10:tm3«kg'»⊈Ḅᑖ&

34?⊈¨17kg©ªlO^kg¬>ᑣ¨w⊈ᑖª®¯w¬°±+“RTSM---------=-----D(\-v-e)P8.31X293X4.41X10-I3X1Q3-6.3X10-7(1-0.749X10-3X0.988X103)=6.56Fe=᜛.56:*10-3.86x10"(°³e/ᑖ)129µ¶ᱥ¸ᑖᙠ293KḄ¹"ᑺ(஻஺=3.22XKT"&.S)Aᳫ¿ᑖ஺ᵨÁᔠᱥÃ1g,£ÄA10%3,Åᐸ᡽ᦣᦪA8.00X10ᔠᱥḄᑖ஺+ǸᑖḄ¢£È>ᳫ¿ᑖḄÉÊ=Vᑣ—4,M=-7iR3N./V3AËin-6V=^—=lQ-3(m3-kg-')KT?&ᵫEinsteinГABoltzmannÓᦪ&Dஹ/ᑖA᡽ᦣᦪY᥅Õᦪ஺ᵫStockÐf=6M)R%A"ᑺ஺ckT1.38x10-23x293•R=--------=-----------------------------------"6Ö஺6^X3.22X10-4X8.00X10-19=8.3x10-”)3&.MM—TTR'NJV4A3=-^-(8.3xlO-,o)3x6.02xl023/lxl0-3=1456(Zg•p஺³)

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41]X1()63.4log-----=0.32958xl0?5//%=2.14(ª)5ᓽqrqr]Ḅ2.14ª஺14¬lᔠᱥ(Tg=320K,p=lxlO3kgm3)ᙠ400K4I±ᐸ]105Pas,´ᵨ¶·Ḅo¸d⏣(Tg=160K,=lxl03kgm-3)ᐙᑖ»¼5½ᔠᱥḄ¾ᑖᦪᓰ»¼Ḅ0.70஺ᑣÀᛛAᔠᱥᙠÂkÃ](400K)&Ḅ]ᜧ¬ᔠᱥÀᛛᑺḄÅᵫ¾ᨵÆÇqÈឋ஺¬mᑖ¾ᑖᦪV-------=07%=0.3zᓃ,+%%ᵫÅᵫ¾ᳮ+/=/+«(T-T)ᑣᑖLZXᑏÐgzgÑᔠᱥÒ=0.025+aq(ÓkÓÔ)¸d⏣Ò=0.025+a஻(T—4J&᪗pÈdᑖLÙ⊤ᔠᱥÈÀᛛᑺ஺஺q=4.8x10k'/]5aÜ=10k7]5p«P,=1x10!kgm᪷ßÅᵫ¾ÆÇqÈឋᨵ0à=/ᢌ+Òâ=[0.025+a(T-&)]%+[0.025+a(T-T)ᦈfpfdgd=0.025%,(T-T)%+(T—&)(1—%X"gp¬q¸d⏣Ḅ]ᑖLçÈ7,᪷ß]Åᵫ¾ᑖᦪḄDoolittleëì)In="஺-11ïÒkÒfff.fpTpr={(1k%)[a஻(T—T“)kaq(T—஻)]}/{[0.025+%(T-%)][0.025+aq(T-4)-%+%"-&)(>%)]}=7.05In7=In105-7.05=4.463

42r/=86.74Pas15PEÈPMMAᓄ\EᑖL41.8kJmol_1È192.3kJmol1,PEᙠ473K4Ḅ]n஻(473)=91PasóPMMAᙠ513K4Ḅ]%I3)=200PQS஺ôõ:(1)PEᙠ483KÈ463K4Ḅ],PMMAᙠ523KÈ503K4Ḅ];(2)øÔ
f᪀ùᔠᱥ]Ḅúû(3)øÔÃ]ùüÂf᪀ᔠᱥ]Ḅúû஺(1)ᵫᦻþÿT)=193K,Tg»w=378K,Ḅᙳᙠ(R+373)KᦑᵨArrhenius'()஻=4,☢ᡈ2.303log%=5(L—)8RAT?2.3031og^41-8xl0-(J---L)PE)=918.31483473஻(483)=71P—s2.303log=>"Xi"(J----L)918.31463473,஽483)=U4PesPMMA)2.303bgDJ92.3X103F_H_L)2008.31523513
"(523)=84J஻•S2.Q31og^1923X103(J---L)3=2008.315035137503)=490Pa•s((2)OឋQ(PMMA)RSឋQ(PE)ḄᜧU(3)OឋQḄRSឋQḄVWḄXYᜧ஺16[\]ᛛPVCḄTga338K,Tfa418K,cdeᓄg=8.31஺h஺J433KiḄa

435Pasoj]ᛛPVCᙠ338Kk473KiḄᔜamᜧno)ᙠ7Uߟ4+100"஺qᑁᵨWLFs◅uvwxᓽ^7433_-17-44(433-338)°851.6+(433-338)=-11.3015log%,=log5+l1.3015=12.004r)=10"PensT*sz{a473KT|ᦑᵨArrhenius'(wxᓽAEJRT7=%e8.31xl0\zexp(-------------)
7(473)8.31x473ᡈ=0.82267(433),8.31x103exp(------------)8.31x433஽473)=5x0.8226=4APas}~ᱥḄឋ1298KiḄᑗa1.25X109Nn)2,Ra0.35,ᐸ(E)k(B)m?RḄᦪᜧ.o)E=2G(1+v)=2xl.25x109(1+0.35)=3.38x109N-m-2E3.38x109=3.75x109%.2B=3(1-2v)3(1-2x0.35)•••(B)(E)ᑗ(G)2H¡ḄᑗalOVm2,¢ᵨN-m=kkgcm2⊤¤i¥Ḅᦪamᜧ?o)G=107x0.1=106JV-m_2(Idyn-cm-2=0.1JV-m2)106=10.2Ag-cm~29.81X1043¢¦§¨©ª«ᔜᔣឋḄᩞᧇ,ᙠ©ª°±²³´µªiIᐸRu=1/2,ᢣ·ᔜḄ᩽▲.o)ᵫ⚪¼AV=0,ᡈ8=P%/AV=oo

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53-17.44(423-358)log"(423)=-9.722151.6+(423-358).•.a=1.89xl0-'°(423)ᵫaTo7(423)1.89xl0"10r(r)ஹ~-=-----------.~=2.12x10-3ᓽRrs500tr(393)8.94X10%(T)7(423)1.89x102(7u)=1.43x10-5,ᓽRrsio$tr(378)1.33xIO-ஹr(4)20?vwBḄFGxyz{-ᙠ25࠷}~{lhH3Xl()5N.m-2.%ᵨZᦔᣚ(1)ᙠ-80࠷}~{lhḄFGxyz{STuফᙠZ[H,~10%,-8(rc~{lh,ᡠᑮḄz{QD<\ᵫPIBḄ-Zᦔᣚ(᝞ᡠ)(1)ᵫ-ᙠ-80࠷}~{IhT,logE(t)=9,PpE(t)=109N-m-2ফUVPIBḄ1\=-75࠷,FᵨWLF`a}⚪¢-,1-17.44(193-198)log------=-----------------------t(T)51.6+(193-198)g.1.^,)=0.01345(/1)=48(5)ᵫ⚪¢-ᙠ1(Th~D᪵ḄE(t)ḄZ[T,£¤¥¦HᨵDḄ§¨©ªlog%,.«_-17.44(7-198)"°80.01345-51.6+(7-198)T=214K=—59(22¬?@AB%᪵®10.16X1.27X0.3201?,¯°277.8NḄ±₹³IJ≯´µ-ᑮ´µᦪ·᝞H⊤.%¹ºᐸ≯.᝞¼Boltzmann¿¯$ᳮᨵᦔ-ᙠlOOmin±₹¯t-ᑣᙠ10,000min%᪵≯Ã'ST<t(min)0.1110100100010,000'[l(m)0.10240.10280.10350.10440.10510.1063\᪷·£=°4=Å

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