2015高考真题——化学(江苏卷)含解析

《2015高考真题——化学(江苏卷)含解析》由会员上传分享，免费在线阅读，更多相关内容在教育资源-天天文库。

2015
᪥ᐰὃᔁᓄ⚪ᓫ⚗⌱⚪⚪ᒹ10⚪⚪2ᑖᐳ20ᑖ஺⚪ᨵ⌱⚗ᔠ⚪஺1.“᛻”ᡃḄ"#஺$ᑡ&'()*+᎝Ḅ-.A./012ஹ⁚5Ḅ6789B.ᢥ᯿<=>67?@ᱥBCᑖDEFC.GᐭI᩟KLMNOPQD.RSTᵨVឋXYஹZ[ஹᛛᧇ^_ூaᫀ௃Dூ᪆௃⚪ᑖ᪆IAஹC஺Ḅ᣸$%ᦑA'()*+Bஹ,-./ᱥ12ᑖ3%45,ᱥ6728ᦈ:ᵨ%ᑖ3ᜐᳮ%ᦑB'()*>Cஹ?@ABCD%EEFGH1ᩭ%E3,A᛻ḄẚL%ᦑC'()*>Dஹ:ᵨMឋOPஹQR,᪛ᩈUᜧẚL%ᛛᧇY:ᵨZ[\⁐^_%ᦑD'(┯a.ὃeὃfg⚪஺2.$ᑡᨵᐵiᐗklᐸᓄᔠᱥḄ⊤pqrḄ-.»riA.vYᦪx17ஹyYᦪx20ḄizY*B,i|Y-CI-.Ḅ~᪀p'••••CICIc.iᑖYḄᵯY9D.iᑖYḄ~᪀9H3C-CH2CIூaᫀ௃Cூ᪆௃⚪ᑖ᪆Aஹ)vᦪvᦪ=yYᦪ+vYᦪ=37,)ci,ᦑA'┯.Bi|YvYCl2/8/7ᦪᜧᵯYᦪᐸ~᪀p,ᦑB┯CஹizYᨬ᜜7ᵯYizY

1ᑮ8ᵯY¡=~᪀ᦑCqrDஹi~᪀9CH2=CHCI,¢⚪£yi¤ᦑD'┯஺ὃeὃfᓄ¥ᵨ¦஺3.$ᑡ'qrḄ()A.ᑖY9xC2H6஺Ḅᨵ©ᓄᔠᱥឋvª«B.ª«ᩩ$_vḄ2ᢥaஹb®¯⌶±²ᐰ´ᓄ⌶±aµ⌶±bE¶·¸¹ºHO஺22⌶±aCCO+H2UU2-W2U*»¼½¾02⌶±bCCO2½¾C.ᙠÀᓄÁzÂ)yÁzᑺᜫÅᵯYÆᦪ_ÀᓄᑺÇᑮᵯYḄÆᦪD.ÈÉᓄ¥ÊᓄËÌÍÎÏдÊxÑÒ⚪ᑖ᪆%AஹGH«O45dCHsCHQH,e45dCH30cH3,ᓄឋ6fg%ᦑAha%Bஹ᪷jklmn.opqrst᝱vw᝱ᨵᐵ,sop{|}ᐵ%t~vwf%opqf%ᱥWCᡂg,$qg%ᦑBa%Cஹop,ᜫᵯPᦪឤ%ᦑC)*>DஹᓄᓄḄᐗឤ%ᦑDាa.-ὃeὃf«ᑖÓ᪀ÔஹÂ)¹ஹÀᓄÁzÂ)_PQ஺4.ᙠC02yMg½¾6ᡂMgOKC஺$ᑡ'qrḄ()A.ᐗkCḄᓫvÖᙠ×ØÙKÙÚ®¯«kÓÛÔB.MgஹMgOy╅ᐗkÝÞḄß±r(Mg2+)>r(Mg)C.ᙠ*Â)ᩩ$MgḄÁzឋàCḄÁzឋD.*Â)yᓄ¥ºᐰá´ᓄx¹ºூaᫀ௃Cூ᪆௃⚪ᑖ᪆AஹCÁÖᙠCeoஹC70_«kÓÛÔᦑA┯Bஹ«¯ᐗkḄß±ḄµâãᵯYᦪᵯYᦪä¸ß±äᜧr(Mg2+)vr(Mg)ᦑB┯Cஹ᪷æÀᓄÁzÂ)yÁzᑺḄÁzឋᜧÁzçᱥ

2ḄÁzឋMgÁzᑺCÁzçᱥᦑCqrDஹáᑖ´ᡂ¹ºáᑖ´ᡂᐝº,ᦑD┯஺ὃeὃf«kÓÛÔஹß±ᜧஹº´ᓄஹÁzឋàéµâ_PQ஺5.êᕜìíîᐗkXஹïஹZஹWzYðᦪñVòᜧXzYᨬ᜜ᨵ6ᵯYïóôõöḄ÷×øឋᨬàḄᐗkZᙠᕜì⊤yᜐᕜìðᦪ_îðᦪḄúFWḄᓫvûüᵨýßþÔᩞᧇ஺ᑡḄA.ᨬ᜜ᵯᦪᵫᑮḄYஹXஹWஹZB.ᵫᜧᑮḄWஹZ,ஹXC.ᐗ"#$%ឋᵫ'ᑮ(ḄZஹWஹXD.)ᓫ+᝱-ᓄᱥḄ01ឋᵫ'ᑮ(ḄXஹஹWூ3ᫀ௃Aூ᪆௃⚪ᑖ᪆%ᢓᐗdᕜᐗ%P¡ᦪ¢Mᵨᜧ%x£Pᨬ᜜¦ᨵ6§ᵯP%¨Xaஹ.d©ª«¬Ḅ®¯ឋᨬ°Ḅᐗ%¨Y|F.Zᙠᕜ⊤ᜐ³ᕜ¡ᦪ³´¡ᦪḄ■.¨ZA1.WḄᓫ6·¸ᵨ¹º»¼ᩞᧇ,¨WiSi.Aஹ᪀ᐗḄ£P᜜¦ᵯPᦪᑖ¿d%6ஹ?ஹ3ஹ4,ᨬ᜜¦ᵯPᦪᵫÁᑮḄád%FஹHO>SiH4.ᦑDÙa.2ὃ7ὃ8ᐗ"ᕜ:;<ᐗ"ឋ=஺6.>?@ᑡᔜBCD1Eᙠᢣ1HIJᜧKᐳMḄ+3+2-A.NOᏲQR⁐ḄHIJNa''S°4'ClB."=1x10'3moiJ+ஹCaN032+ḄHIJNHஹCl42++2-C.XAlYZE[\H2ḄHIJFeஹKNO3SO4D.]ᵯCḄcH+
=1x10-ஹCO32_3moi.L7ḄHIJK-ஹNa,ஹAIO2ூ3ᫀ௃Bூ`᪆௃

3b⚪ᑖ᪆AஹO⏚QR⁐ḄHI@fHIghឋ@AI3+ஹ0HiᡂklᡈAIO->nEᜧK2ᐳM@ᦑA┯4)>c(OH),HIg⏚ឋ@stCnYZ@EᜧKᐳM@ᦑuvBஹ᪷xyz@fHIJc(HvCஹX2+0HnᐳM@⏚ឋ,AlE[\-+Ḅ@{|}Eg⏚ឋ~}Eghឋ@hឋ,ᑣFeNOᙠ⏚ឋ3+)=1xIOḄHI,-13-1ᩩᐹᨵ'ᓄឋ@niH,ᦑC┯uvDஹ]ᵯCḄc(H2molLfᱥ=]ᵯ-ஹCO2+nEᜧKᐳM@ᦑD┯u஺3AIO2-HA.ᵨᴻ↾CH3coOHHI7ᙠ]ḄpHb@1HIḄpHB.J1@1ᵨᡠḄYZI23C.ᵨᵬᑖI@[\]¡¢£ᑖI¤ᧅ¦[\ᨵ§ூᕚ©ª«¬ᑖ`NaHC03®ÚÛ%AஹfÝᙠÞßpHQà%,áâ%ᡠäIpHfå%ᦑAa%æçm⌕ᵨ■)opèßé23M%êfë᪵,,opèᨵÌí¹ᵨ%ᡠîïðᨵñò,ᦑ)ó>Cஹᑖôõ.à¦è¼Æàö᎔%ᨵøpÆàö᎔%ᦑC┯a+DஹUqù¼úöᶍᔣü⚗þ%ᦑD┯a.ὃ7ὃ8¯°±²³´஺8.µ1ᩩ@ᑡ⌱⚗Jᡠ¸Ḅᱥ=¹ºᓄᙳED¼¯½Ḅ()ClH22A,¿ấSgÁSiÂÃÄ?B.Mg(OH)M/⏚2(aq)Mgᵯ`2

4Æ⏚DÇÈ@C.Fez஺?Êeci3(aq@Ë]FebbNH3H2૙Í.D.AgNO3(aq)[Ag(NH3)2]0H(aq)AgÏூ3ᫀ௃Aூ`᪆௃Ä?Ä?Si+4HCI,ᦑvBஹÐ|ᑴb⚪ᑖ᪆AஹSi+2CI=======SiChj,SiCl4+2H=======22ᜓMg,ᵯ`ᰚÔÕ᝱ḄÖᓄ╅@ᦑB┯uvCஹFeCb'⏚(hÆ@ØÙ«¬ÇÈᨬÚÛᑮḄᓄÜ@ᦑC┯uvDஹⅅÍ#ÞឋÍ@nEXßàHIYZ@ᦑD┯u஺ὃ7ὃ8ᐗ"<ᐸᓄᔠᱥḄឋ=஺9.ᑡᢣ1YZḄCãäåḄ()A.Ö+Hæ]CI+HO=2HF+CI-+CIO222-2-B.Na2cO3HIJC0+HO=HCO323Ḅ]`C0+0H3-+I+6H=I+3HO+22C.⏚ឋHIJKI03XKIYZiᡂl1032-+Ba-=BaC031+H2O2+ூ`᪆XaHCChHIJ«çKBa(0H)2HIHCO3+OHÿᵯAஹ⏚⏚ᑏHQOḄᙠᦑBஹᓫ⌮ᐗẚ᪷ᑖ"8?-+ᚈ஺=±HCQT+OH-,ᦑ┯)Cஹ*+ᡠ-ᵯ₹ᦪ0ᦑ┯Dஹ123ᦪ“1”NaHCOj4-Ba(OH)-BaCOjI+NaOH+Haᐹ567822HCO3-+Ba2_4-C«--BaCO31+H2O.ᦑ9:ὃ7:ὃ8CéᶭäåuᑨìíBCO*H,—♦^ᵯ,10.Dïðᵯñò{ó¦ôõᑡᨵᐵᵯñḄ÷øḄ()cotNa,\@஺«&/û

57üýᵯᵯ`þᓄᑺA.
CH+HO3H2+C஺,ὑ1molCH412molᵯ42B.ᵯ᩽AḄᵯ᩽
H+2OH-=2H2O2--2e2-ᔣᵯ᩽BC.ᵯCO3D.ᵯ᩽BḄᵯ᩽
0+2CO+4e=2CO2223ூᫀ௃Dூ"᪆௃$⚪ᑖ᪆Aஹ1molCH4fCO,ᓄᔠ)ᵫ*4)—+2ᓣ6)ImolCH4-
ᐳ6molᵯᦑ┯122--4eBஹ4᛻678ឋᔲᑣ6<=C5,ᐸᵯ᩽
?CO+H+2CO=3CO+HO,2322ᦑB┯12Cஹ᪷ABᵯBᳮᵯ᩽A7D᩽ᵯ᩽B7E᩽▢GᔣD᩽ᦑC┯12Dஹ᪷Aᵯ2-Bᳮ6ஹCO2ᐳI-
ᐸᵯ᩽
?O+2CO+4e,ᦑDEJ஺22=283ὃLὃMBᵯḄBᳮNᵯ᩽
?Oᑏ஺6Q⚗⌱T⚪U⚪ᒹW5X⚪X⚪4ᑖᐳY20ᑖ஺X⚪Zᨵ\]ᡈ_]⌱⚗`ᔠ⚪a஺bEJᫀZᒹW\]⌱⚗c⌱dX⚪e0ᑖ2bEJᫀᒹW_]⌱⚗Z⌱\]fEJḄe2ᑖ⌱_]fgEJḄehᑖiZ⌕⌱┯\]dX⚪ke0ᑖ஺11.lᑡnoEJḄ7()23A.bH2O2ᑖ"=1molC>2,ᳮrḄᵯᦪt4x6.02x10B.uvlpH=3ḄCH3coOHwxpH=11ḄNaOHwxyz{|ᔠwxpH>7C.}~ᵨᱨ□᩽ᡈ᜜-ᵯḄ▢᩽o■ᐸῖ⇨VzOsv,⏚180CᐙᵯD•\Qᩩl
N+3H2NH3ᑮ⊝3VE(Hz)=2v⌮(NH3)22ᓄᑺᵯᓄᑺூᫀ௃C

6ூ᪆௃>⚪ᑖ᪆τAஹ2H16-2H2O+஺@ᡂImoK%BCᵯ6ᱥᔊḄ2F2'6.0"1G3ᦑ┯Bஹfig⏚⏚HᓄJKL,0NOPᔠR⏚S2TUV⏚ឋpH<7,ᦑXiYCZᱨ□᩽Ḅ▢᩽_`a᪷bcᵯdcᳮ.ghijkḄlmno᩽piᦊ9᩽▢᩽_`a᪷bᵯd,piᦗ▢᩽■tpiḄJB⇨ᦑ9:IX⌕w7ᔣy9y⌮z{᳛}h0~3ᦪ}h2V9-3i?NHj
.ᦑ┯.ὃLὃMᓄ
Bᳮy¡஺12.¢£¤¥Ḅ\¦ᔠᡂ¨©᝞lL\&CjHCH,O_C_f^HClH2H**1,0CHCHXYῊlᑡ«¬EJḄ7®A.ᙠNaOHwx°-±ᓄᔠᱥX³
B.ᙠ\Qᩩᓄᔠᱥ´HCHOµ¶
C.ᵨFeCbwx␺¸ᓄᔠᱥXNYD.ᓄᔠᱥ´°6¹ᨵºឋ»Bூᫀ௃BCூ᪆௃>⚪ᑖ᪆AஹXᙠHᓄJḄTU@Ḅ@HᓄJḄTUᦑ┯Bஹᵫ~YḄḄjkYᨵḄYY@¡ᦑ9:;CஹX£¤YY£ᨵYᵨFeCh¦ᑖᦑ9:)Dஹ§ឋ¨c6ᢣ¨c6ªᨵ«¬Ḅ®6ᡈc6°Y£“CHªᨵ4¬Ḅc6ᡈc6°±¨c6§ឋ¨c6ᦑD┯.ὃLὃMᨵ¼ᱥ½¾¿ḄឋÀஹºឋ»By¡஺13.lᑡÁYḄÂÃÄᫀ¾ᑮÂÃÅḄḄ7®A.ᑴᜓAl0H®3ÈÉxᔣ1moLL%Cl3wx°-ÊËḄ6mol.L'NaOHwxB.Ì͹ᨵÎËÏ⏚ḄÏ⏚ÏÐᔣ¹ᨵÎËÏ⏚ḄÏ⏚Ïа-ᐭÊË⛳N»⏚ÓwxÔ₩Ö☟ØᑖxÙ◀³ᨵ¼ÛḄcÝ/ß6àÖá3+:âÎËãäÃwxᔣᐸ°-ᐭÎËåᑴæçè-C.äÃwx°7ᔲ¹ᨵFe

7KSCNwxéêÂÃëìD.íîᓄᑺïH2O2ᑖ"ð᳛ḄòóᙠÛIᩩlᔣ\ô$õ°-ᐭ2ml5%H2O2N1mlH2஺ᔣö\ô$õ°-ᐭ2mL5%H2஺2NImLFeCLwxéêÙ÷øÂÃëìூᫀ௃BDூ"᪆௃$⚪ᑖ᪆AஹAIOH
37_ឋùúᓄᱥûNÊËùúᓄÓ
üý⏚Óᦑ6¾ᑴᜓùúᓄýÈÉx┯12BஹÏ⏚Ḅ⏚ឋþÿ⏚⛳⏚◀⏚⏚Ḅ᪆ᯠ2+3+ᑖᓽᦑCஹ"#ᐹᨵ&'ᓄឋ*+Fe'ᓄᡂFe,./01203ᦑ┯5Dஹ6789:;<=᝞?@AB78ᑈDEFG@HBIJFeCbKLᓄᑺNOPQR᳛ᦑ஺ὃVὃW<=XᫀḄZ[஺14.\]^ᔣ^ᑡabᐭdQḄDefpH=7gbᐭDe:ehḄijkᶍmanᑖopḄᱥrḄstᐵvḄKgm-12-))=c(HCO)+c(CO+33A.ᔣO.IOmolLNH4HCO3abᐭCO2wC(NH4B,ᔣ0j0maJNaHSdabᐭNHwc(Na+)>c(SO323)>c(NH4-)+)=2[c(S03-)+C(HSO3)]C.O.WmolL+2—2Na2SO3bᐭSO2wc(Na)+C(HSO3-1))>c(CHCOOH)=C(CI)+3D.O.IOmolLCH3coONaabᐭHCIwc(Naூyᫀ௃D

8ூ᪆௃>⚪ᑖ᪆τAஹ¿ὅ᪷bTUᕈÂᵯ£ឋcCNHO+dHXOHD+ZHCQO+ZqOQ?)ÃFpH-7,c(H-)-c(OH").ᓽ“NHTKHCQjD+ZaOCV-),ᦑXBஹHSO\=±H+SO52-,NH3;H-@ᡂÅÆ⏚JÅẚ⏚Ç.Ḅ8ÈÉḄÊNa-XSOj2-)WNH(-),ᦑXËUN^SQj+SQj+HjO-ZNaHSOj.pH-7,+TUḄTᾦN&SQjஹNaHSOj᪷bᱥᧇÎឤ12c(Na*)-3(c0>H<0LᓄᑺᵯALᓄᑺB.evḄ¬&P¬wP¬(᝱U)>2P¬(᝱I)C.evac(CO)wc(CO,᝱¥)<2c(C0,᝱HI)D.⌮PQR᳛V⌮wV⌮(᝱I)>V⌮(᝱ᵪ)ூyᫀ௃BCூ᪆௃7⚪ᑖ᪆wAஹCC02PQKᔾ³PQH>0,ᦑA┯5BஹI´ᩩ¨©Kbᐭ0.1molCC>2,n´ᩩ¨©KbᐭOZmolCOz,᝱11¶·ᐜb0.1CO2,¹Ḅ&dºbᐭO.lmolCOz

9Nᐭ⊝»¼¹Ḅ&º§2½P¬g᝱I
,¾⌕ÀCO?ḄtdºQ:¹N³PQᔣPQXᔣ»¼DeᱥrḄsÁN¹P¬g᝱¥m>2P¬g᝱1
ᦑcஹ᝱n¶·ᐜb0.1CO2,¹6ὅCOḄtdºᙠbᐭ0.1molCCm2,Nᐭ⊝»¼II᝱COḄtº§2½HI,¾ᐙᐭCO2,dÄÁᜧ&⊝Å»ÆὑCO,¹cCO,᝱¥
<2cCO,᝱mm,ᦑDஹ]ÈPQR᳛ÈOv⌮g᝱Im11CaSQ,åᓄḄ{|Xæç*èᐸåᓄR᳛Ḅêëᨵ.gíîïm--J・oE/(o一srA.ᤅøäᧇB.N³äᧇf100࠷C.Áᜧú#tD.û~C02bᐭR᳛g2
ÄâpHüý6.5þÿ
஺ᱥḄᨬᜧḄ▢

10(ᓄ);!
"ᔲ$ᐰḄ&'"஺(3)ᙠ)*+ᘤ-ᵨNH4cl/0123ᰀ5Ḅ-6Ḽ0138ᓣ-/2+):ᜧḄ;<஺c(Ca+ᡈCaSO+CO2=CaCO+SO42-,AC?433ூAᫀ௃(1)CaSO4+2NHH2O+CO2=CaCO+2NH4332-ஹ(2)S04,1FᨬGHIḄ
JKLM-ᔣᐸPQR⏚⏚ᓄḄBaCb/-TUVHC03WX⁐Z[-ᑣ⊤^_
$ᐰ`(3)0138ᓣ-/c(H+):ᜧ-abca?+0c஺ூd᪆௃>⚪ᑖ᪆τ(1)Ùᧇ£ᨵḄᔾᦈC6,Bᡂ8»2-,ᑭᵨ¨⏚┛ḄáÈâ~ẚ⏚᜜ḄäåæçḄBᓄᦑ567878tCaSO+2NHHO+CQ}-CaCOj+2NH-3cCaSO,+CO---CaC0+4i24i1W.AஹèéÙᧇ┠0ëì☢Oî{{᳛9ïRîðÙᧇñKᑖòóᑭ~ᔾᦈ,┯CஹᗔᜧKöÈᨵᑭ~ᔾᦈ8iW8»2-ḄöÈî÷{᳛9BBhDஹøJஹC6.ùâᱥḄöÈ{᳛úûX(2)ëü6.5ýþó,TU£ᨵCaSO«,±ÿᨵ⊡ᑖ8»2-ᡂHCOj-,ᦑ▢♦ᜧḄW.HCOj-,ᔲ.■ᔲᨵSO?'ᦑ!"#$%ᨬḄ'()*+,-ᔣᐸ-012⏚⏚ᓄḄBad
5.6789:⁐<ᑣ⊤?@ᤎBᐰ,(3)Eᓄ╆G⏚HI,ᐸJKLMᔾOLMPᓣR«H-SᜧTUVW-3XY.ὃᓲߟὃijkloj/OCH.-TVCH^17(15ᑖ)ᓄnᵨM"Hᢙrst⊈lᱥḄᵯw-xyzJ{ᖐ'ᔠ~.ᐺ⎇*C^H,OY^-CHICNIlNaOHCHJO-^^-CHJCOOH2)HCIDOFQCHKHQHF(1)ᓄᔠᱥAḄ(Ḅ).(2)ᓄᔠᱥBḄ᪀`ᵫC-DḄ"?஺(3)ᑏcᑡᩩḄEḄHᑖ᪀Ḅ᪀

11I.ᑖᨵ2¢£¤D.ᑖᨵ3Uᓄ¤᛻Ḅ¨RCHCNRCHCHNH2ᓄQ.®222©4«_¬?¯ᑏcyH°;ᧇᑴᜓᓄᔠᱥX©᪀¶·¸«Ḅᔠᡂº»¼½¸©¾¿LᑺxÁ⌱«஺ᔠᡂº»¼½¸ÃÄ᝞?OJCHJCHJOHCH3CHOCH3COOHCH3COOCH2CH320HூAᫀ௃©1«⏨ÈஹÉÊ`©2«—''—/-1Î;ooCHO-(~)-C—^2)-OCHjCH-CH,33HOQb(4)

12ூK᪆௃+⚪ᑖ᪆τ(1)ᓄᔠᱥA-ḄabcdṘfஹhij(2)AḄᑖkCuHuQj.lBḄᑖkmnoYBnAp2qH,r?sLMtuLMhivᡂwᦑBḄx᪀☢kj<^y

130-40<50HO100120nitre(4)çü10.1710gMnSO4-H2஺᪵þÿ┵ᐭ〉FhPdNH4NO3Mn2+ᐰᓄᡂMn3+,ᵨc(Fe21Ḅ᪗(!.)=0.0500molL3+"#$%Mn2),&ὑFez20.00mL஺)*MnSCUH?஺᪵,Ḅ-.(/01)*!)Mnூ4ᫀ௃(1)4.487(2)5.0?ᜫᵯBCឤ7n(Mn3+)x1=n(Fe2,—3-3)x1=20.00x10x0.0500mol=1.OOx10mol,᪷M!Nn(SO)=n(MnO2)=17.4/87mol=0.2molᔠ0.2x22.4L=4.48L82(2)ᑴᜓMnSd,R᪷?ᜫᵯBCឤ7n(Mn3)x1=n(Fe2)x1=20.00x103mol,᪷<++—3x0.0500mol=1.00x10

14MnᐗFCឤ—3m(MnSO4-HO)=1.OOx10x169g=0.169g,-.G70.169/0.171Ox100%=98.8%஺2ὃ7ὃᓄ=>)*ஹ.Ḅ)*ஹ◀ᩖ⚪஺19.(15ᑖ)ᵨoᡠᑴᜓKCIOKCIOFe(NO3)3Ḅ=>ᑴᜓ9ᦔᜐᳮᑺKFeO»KzFeO,ᐹᨵᑡឋজ}ஹKOHᱥ0࠷¡¡5࠷ஹ24¢£ឋ¤¥¦ঞᙠFe3+Fe(°H)3©ᓄªᵨ«¬ᑖH’টᙠ⏚ឋ°£ឋᩩ²’³=>¬ᡂFe(OH)3Oo2(1)AKMnO4´⏚=>¬ᡂMnCIzCL,ᐸ¶BM!N%஺·ᑴᜓḄ஺2B}◀¸(¹ᓄN)஺(2)CI2KOHᙠ¥9{.=>¬ᡂKCIO3.ᙠºᦋYKOHḄ.nḄᩩ²zᑴ=>ᙠ0࠷¼5࠷½¾}¿ÀḄÁÂG஺(3)ᑴᜓKzFeCU\KCIO⛳Fe(NC)3)3⛳ḄkᔠMN%஺(4)Ä-KzFeCUÅ],ÆÇᨵFe(OH),KCIÈᩖÉḄMᫀ%7·¡ḄKFeO324Å],ÊḄ3mol-L1KOH(ËᵨḄJᑺᨵ7⛳KOHÌ⏣8◀ÎᵨÏᘤ᜜ËᵨḄÏᘤᨵ7ṺÓÔᧅÖ×ØÙÚ)஺ூ4ᫀ௃(1)2MnC)4+16H++10CI=2Mn+5CIt+8HO,HCI8(2)Û᠒´⏚ஹ222CÝÞ8(3)ᙠᤅà·Fe(NO3)3⛳Û᠒ᑮKCIO⛳8(4)ᵨṺÓÔᧅá·áÝÞᔣáᐭ⛳KOHᤅàஹ☟RᵨṺÓÔᧅáᨔnᵨ〉Ì⏣ä

15å2—3æsᙠÖ×ØÙÚØÙ஺ூK᪆௃+ᑖ᪆1(DKMnO,ᐹᨵGEᓄឋ¢2⏚-CT%ᓄᡂG2¤304-+16"+100ஹ~02+50^+8H2d¦~B-§¨⛳ª2Jᵨ◀¬E-ḄᓄEW(2)ChKOHᙠ®RPLM9ᡂKasᑴ#Kaoiftᙠ0C5C,¦C¨ᙠ°J±-.■³(⏚Ḅ´µ.¶1(⏚·M¸᠒¶1τ(3)Rº⏚᫦ᙠFe»-F«OH)3¼ᓄᵨ9ᑖKr?M¢½⏚º01ᑮKCK)-ᣳτᙠᤅÁÂFGKRJ⛳5¸᠒Ã1ᑮKQO⛳5-(4)Rº⏚ÄÅ5*JஹÆ5*KOH5,ÅÇ((ÈḄÉÊ◤ᑮRº⏚ÌᯠᵨÍÎ'$Rº⏚ÏḄÐᜫᦑᵨṺÓÔᧅ(È.Ö×*°J±-ᔣØ-1ᐭ⛳KOH5ᤅÁஹ»■.ÚᵨṺÓÔᧅ()ᨔWᵨ〉%ÍÝÞ2—3,ᙠßàáâ-á.ὃ7ὃᓄ#$=>M!NḄçᑏஹ◀ᩖஹkᔠÈé20.(14ᑖ)êë(ì⌕îïᱥSO2ஹNOx)ð஺3⚜ᜐᳮsᵨCaSO3òóᔾᦈ}töêëSO2ஹNoxḄÇ஺஺3ᓄêëSO2ஹNOxḄì⌕=>ḄᓄM!N%7-1NO(g)+O3(g)=NO2(g)+O2(g)÷H=—200.9kJmol-1NO(g)+1/2O(g)=NO(g)AH=-58.2kJmol22-1SO(g)+O(g)=SO(g)+O(g)AH=-241.6kJmol2332(1)=>3NO(g)+O3(g)=3NO2(g)Ḅ÷H=mol-L\(2){ø½ᐭ=>ᘤḄNOஹSC)2ḄᱥḄᦋYᐭ஺3ḄᱥḄ=>¡ù\úsnûn(NO)ஹn(NO2)n(SO2)ü=>ýn(O)7n(NO)ḄYᓄþÿ஺3জn(O)n(NO)>1NO2ḄᱥḄᐸ.3ঝn(O),O3ᓄSO2Ḅᐸ!"3

162-$NO2(3)ᵨCaSO3&'()ᔾᦈ,஺3⚜ᜐᳮḄ012)(pH458)6SO37ᓄ5NO,ᐸ89:;<5஺22-)=_______=ᵨc(SO24(4)CaSO3&'()6ᐭNazSCh?)@ᑮB⊝?)6c(SO3D)ஹKsp(CaSO3)GKsp(CaSC)4)⊤IJCaSO3&'()6ᐭNa2so4?)"KLN02ḄᔾᦈM᳛ᐸO⌕.ூRᫀ௃(1)—317.3(2)জ஺3$NO2ᓄᡂVLWXᓄᱥYঝSO2Z஺3ḄM᳛᠒Y2-+(3)S032NO+2OH2-+2NO2-2-)/Ksp(CaSO4),CaS037ᓄ52+H0Y(4)Ks(CaS03)>c(S042P=S04=\]?)62-Ḅ^_ᜧaSO2DZN02ḄM᳛஺SCM®ᑖãপåækvçজ+ঝX2J,3NO(g)4-Oj(g)-3NCh(g)AH—200.9-582X2kJ•3-317.3U•mol-i,(2)(DnCO,).n(NO)>l,ëE(ìNQjₐ$ÅbᑭᵨḄïEᓄឋ¢NO
ᓄᡂðRñò,ঝó10(6)6EᓄS6ḄLMõö7÷ø?ÅbsLMù᳛®᠒(3)pH᝝ü8,r?5ýþឋ,ÿ
ᓄᵨ(ᱥ)ஹ(ᱥ)᪷ᦪឤᡠᵯ₹ᦪឤ,ᐸ,S0?-+2NQI+2OH--SO<2-+2N0-+H2O
(4)Ca?SO/!W
K,(CaSO)-c(Ca2_)xI4"SO?),c(CaJ_)-K.,(CaSO4).c(SOJ").#ᳮc(SOJ-)-K.,(CaSO).c(CaJl.c(SOr-)"K^(CaSOj)xlJ}«SO,2)Ksp(CaSODᑭᵨ&'ᔣ)*+,ᔣ-."SO?)Ḅ0112&'3᳛ᦑ67NOiḄᔾᦈ:᳛.ὃcὃdeḄfgஹᓄhஹ?_iḄfgjkl21.(12ᑖ)ூ⌱o⚪௃q⚪ᒹsAஹBtu⚪v⌱wD6Du⚪xᙠzḄR⚪{|ᑁ~R஺oᑣᢥAu⚪ᑖ஺2-+3CH3cH20H+16HA.=ᱥ᪀Zឋᑡᵨᔲ⏀20X)73++3CH3COOH+13HO-»4Cr(HO)226(1)C2+᝱᪶᜜ᵯ9᣸<5YᔠᱥCr(H2஺3+6ZC2+ᡂ¡Ḅ9(¢ᐗ¤¥¦)஺

17(2)CHaCOOH6C9§⍝ᩖᓄª«5Y1molCHCOOHᑖ96¬ᨵ3

185¡Ḅᦪ¯5°3
Z±0²5jᵯ9³ḄD´□895°¢ᓄ¶<
YH20ZCH3cH30H!·¸¹º»²?◀5½¾¿᩽ឋᑖ9᜜h5஺ூRᫀ௃°1
1s22s22P63s23P63d3ᡈ[Ar]2d3,0Y2
sp3>sp2,7molᡈ7NA3
HF,H02+2ZCH3cH20HÂ!·ᡂá஺ூ=᪆௃@⚪ᑖ᪆DG■DEFGᕜIVIBJ᪷KᱯᱯMCr3-O᝱᪶᜛STUVW122522P஺39Y஺ᓾᡈ5[Ar]2d3,C/\]^_⍝ab,\]cᵯdeᨵgᐗiᨵcᵯdjk-lᡂnoḄpqO2ᵬOsᨵ46◖ucᵯdvwᵯdᦪW4,ᑣᩖᓄz{qᵬ!|Osᨵ36},ucᵯdvwᵯdᦪ3,ᑣᩖᓄz{q~ᡂpelᡂ16᪷⏚Ḅ᪀Vᨵ7moiᡈ7N*3
ᵯpᦪvᵯᦪᦑjH2஺ᵯḄqHF-,=◀᜜lᡂᑖஹ&'ᨵᐵlᡂᑖḄᦑ.2ὃcὃdᱥ᪀ஹᵯ9᣸<ஹᩖᓄª«ஹᐳW¡ª«ஹjᵯ9³ஹ?Å_jkl஺B.[ÇÈᓄ¶]ÇÈÊ·ËᵬÍ5ᧇᑴᜓÑËᵬÍ°ÇÈÒÓÔzᐵᱥḄÖcÔ▬⊤ØOᐸÇÈÙÚ5ÙÚ1$Û⚠Ý6ḄDwºḄÞ&AICI3ஹ1,2DßàáâGËᵬÍᐙᑖäᔠᓣæç60࠷.é᠒ê,^ë⏚íîïḄ)ÑðæDñòᓾ஺ÙÚ2$äᔠᱥé᠒ᐭDwḄôõ⏚6ᤅ÷ஹ☟Óஹᑖ)•ᨵzᵨ10%NaHCO3?)úû஺

19ÙÚ3,úûḄᨵzᐭ〉Þ&MgSdý³þÓDñïÿ஺
4ᨵᦈᑖ஺(1)Ḅ⌕ᵨ┵!"Ḅ#$%஺(2)
1ᡠ'ᐭḄᱥ*ᨵ+,ᱥ*-ᓄᑺᐸᓄ12%஺(3)
2ᵨ10%NaHCO3#$34ᨵ%5◀7#8ᨵḄ(:ᓄ12)஺(4)
3'ᐭ<=MgSCU>?Ḅᵨ.(5)
4AᵨᢈC%5■E஺▬⊤ᐵᱥ*ḄIJ(101kPa)ᱥ*IJ/Lᱥ*IJ/࠷N58.81.2-PQRS83.5TᵬV179WXTᵬV229ூZᫀ௃(1)]^NaOH_(2)AICI(3)Br?ஹHCI_(4)◀7ᨵḄ=_(5)Wa3;TᵬVbcᓄ஺ூ=᪆௃@⚪ᑖ᪆(1)Ḅᵨᐸ¡¢ᑮ¤¥¦ₐ¨Ḅ©ᜫ“¡¢”ᨵᢵ®ᩭd°᛻ᨵ²³´µ◀¶៎l¦¸¹ºNaOH
(2)᪷»¼ᨵ½ᱥ¾ᓄᑺbÀqu½ᱥ,ᦑqA1C1"(3)ᵨᨵÁzÂ⏚Âℍ¸⛳Å⏚ÆḄᵨ◀¶=ᙠI⃫ᵬɸÊ⏚(4)uËMgSO,ºᙠÌÍ3ᯠÏqÐÑÒᯠuËMgSdḄᵨq◀¶ᨵ½ËÓ(5)ÔOÕ᧕ἑgᓄ■ÙÚÛᵬÉÜÝᓄ.ὃJὃefᘤஹ◀ᩖijk஺