浙江省慈溪市六校2022年高三第三次模拟考试化学试卷含解析

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17প&஺2æTᑣm(H2)=2g,m(Ch)=26g-2g=24g,n(H2)n(Oz)=~;---—;-------;=43P2g/mol32g/molফ&H2æT᪷µᓄöBC÷ÒÜ2H2+02=2H2O,¼½BCḄj?2g,úὑü?16g,ᡠÍXᔠ?eO210g16g.1AḄ
16g,H2Ḅ
10g,n(H)n(O)=——~~~;=101222g/mol32g/molᦑᫀD஺ூ௃ᢕ!"#$
H2+NaO2=2NaOH,()Ḅ
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18ஹ×⌱Ø⚪(ᐳ84ᑖ)023ஹÕÖ;ᓄ?@ᡂ?@ᓄᑺஹf1120H+2CHjOHCH0H2CH,CH3CH=CH2OH0IKHj♦ூ᪆௃AḄᑖAC2H4,@CH2=CH2,89;ᓄ?@9ᡂ;5Û;5Û;ᓄ?@9ᡂ⏚5Ü⏚5Üᵬ⏣89ÞßiḄ?@9ᡂ⏚ᵬÜHOCH2CH2OH,ᐸFM£9ᡂN,àljEHOCH2CH2OH,F⏚ᵬÜ°᪀áAG?@9ᡂJ,ᵫJᑖA¤G9ᡂJḄ?@ᡂ?@GCH2=CHCH3,J89;ᓄ?@ᯠã⏚ᓄ9ᡂLäLäᙠ⏚ឋᩩæÊ?@9ᡂM,ᵫM°᪀áADᑖA¤DçC^OH,FM89èé?@9ᡂḄPC7,00111(7)ᵫÞßii£¤êᑴìí£îìïðᓄ;ᓄÆᑮòᐭÕÖ£î⏣ᡈᓴöḄÂ÷Æᑮ;ூ௃(DAḄᑖAC2H4,@CH2=CH2,ùᨵḄúûüýbÕÖ;(2)?@জb5ïðᓄ;ᓄ9ᡂ;5Û?@ÿ
ᓄঝCO2ᡂᡂ0ᡂCH—CH+;oII(3)ঞ/cஹCH30Hᡂ⏣⏚ᵬḄᓄ!"\/CH,—CH,ßᓄᑺàCHOH+2CH30H2CHOH2(4)টG$ᡂᡂḄJ
C9Hফᵫ&'(ឤ*+DḄᑖ'"
C3H6,-ᔠGḄ᪶0ᐳ234ᨵ678GḄ-᪀:"CH3cH=Chh+

19CH3(5)ড=$>?@AᡂᡂH0—C—OH,A*CDEᡂCH3(6)ঢ⏚ᵬG©4^1)DEᡂPCᛛᧇḄᓄ!"
(7)ᵫJKii*+LᑴNO*PQNRSᓄᓄTᑮVᐭXY*PQ⏣ᡈᓴ\Ḅ]^Tᑮ-ᔠL
$>*+ᔠᡂ_`
$>H2ᡂᡂN⏣N⏣]^ᡂNRᨬbcSᓄᓄᓽTNO,OHᵫe*+=fgᱥ1
N⏣-᪀:"ு஺ூlm௃o⚪⚪qrstuvḄJK◤⌕y⚪zrJK{ᨵ+|}~ᔠᵨo⚪ḄᐵY◤⌕ᐹᜓஹJKḄஹᔾᦈஹ᦮ᔠᓄJKḄᵨ⌮-ᔠḄ⌲ᑖ᪆ᨵᔠᡂ_`*sᔜᨵᱥḄ-᪀:"ᯠbᑖ᪆£¤¥ᔜ¦஺o⚪◤⌕᪷¨gᱥḄ-᪀ᱯlᑖ᪆ᔠᡂḄ&ᧇc-ᔠ⌮-ᔠ}~¥ᐙᑖᑭᵨQ!C&'ᦪzḄ®¯ᳮᨵu±Ḅ⌕²஺³l´ᑖµ᪀¶ᑨ¥¸¹⚪rᩩ»-ᔠ£¤Ḅឋ½ᑖ᪆஺24ஹ¾ᡈNaN6N2SCN+11HO=2SO^+2COT+N?+10HO+2H+SCN¿'ÀᓄH2஺Á22222ᙠ{Ã⁐ḄÅÆ=ᐭÇÈḄKSCN,ÉÊ⊈Ì⁐ᑣÎÏூ᪆௃yᦻÑJK᪗Ó᪾Õ-ᔠÖ×ØÙ}~ᳮ஺ூ௃(1)ÅÆᯚ⁐ᕈÜ⁐ᑣÅÆ=ᨵNa+,ÝÞA=ßàáᐗã¾(Na)஺(2)ä¶ᓫ½CḄ᥅ç½ÈM(C)=22.4L/molxl.25g/L=28g/mol,ᦑ
éä(N),ᐸ-᪀"N=N,ëìA=ßNᐗ2ã஺(3)Õ=ÅÆNaHCChᡂä¶B
CO2,ÅÆᕈ⏚ឋ஺í⁐îïÅÓÞ⏚ᡂä¶B(CO),ᑣí⁐î2ï
BaC(h,ä¶=ßCO2,ᓽA=ßCᐗã஺ÅÆBaCLᡂḄí⁐îïDðÅÓñÞ⏚ᑣD
BaSO“ÅÆ=ᨵSO42,A=ßSᐗã஺*òA
NaSCN஺ÝÞAH?஺ÁḄ¿'!"2SCN+11HO=2SO+2COT+NT+10HO+2H\22222

20(4)ᙠßFe2+¿'ḄÅÆ=ôNaSCNÅÆðÊÌcôH?஺ÁᐜÊÌbÃ⁐ᓽᐜᓄFe?+ஹbᓄSCNöᡈcᓄFe3+஺ÉSCN¿'ÀH2O2ᓄᑣᙠ{Ã⁐ḄÅÆ=ᐭÇÈḄKSCN,ÉÊ⁐ᑣÎÏÉ6÷øÀᓄᡂù±÷᝱ᑣᙠ{Ã⁐ḄÅÆ=ᐭÇÈḄFeCl,,ÉÊ⊈Ì⁐ᑣÎÏ஺25ஹঞû⁐üýÊÌþÈÝÿ⏚ᐭD⁐⁐ᑣᨵᡂூ᪆௃AᨵᮞNHKL!"#$ᮞ%&'ᐭCCḄ)ᓄ+,-ᡂ.!᪷0123ឤ5-6ᨵᡂ஺89ᔠᱥ<ᵨᩭ?ᓾᡂḄA!ḄᨬC.!ᵨ᣸EᦈGᙠIJE஺ூ௃(1)UK%&JLMNO%&ᑺQ⏚

21H2O+CO2T+(4)⏚ឋ|═⏚©ªR«⁐¬ᱥᨵSth,ᵨÒᨵÓ)ᓄÔªRḄÕÖ×ᣚÒ⏚ឋ|═⏚©ªRḄÕÖÉᡭÅKḄÙḄ<Ë2ÆSChÚᔾᦈ¤᛻^(5)Üᔠ⚪Þ,-ᒕ³NO´ᨵCu20(Ẉa⁐)eCU2OU,-Cu2O+4NHyH2O=2[Cu(NH3)2F(V⁐)+2OH+3H2O,4[Cu(NH3)2]++O2+8NHrH2O=4[Cu(NH3)4]2+(⁐)+4OHT+6H20஺}·ᨵa_⁐NO¸ª¹⊤ᨵCu,A,-¼½¾2CUO+S=2CU+SO2,ᐸCuOUSḄ12{51஺»ᡂCuOḄ,-¼½¾4CuO+2AAS=2CUO+SO2,ᐸCuOUSḄ12{101,eÀS#2ᑣM+,-2Cu+S=CmS,_⁐NOC112S஺227ஹᳫK?yJ12HNCh+C6Hl2O6”fc3H2c2O4+9NCM+3NOT+9H2஺áᐰã■᎔ᔾNaOHªRªRpHæ4.0~5.0çèQéஹ?ᓾÜᨔªRa⁐Sëᑖíᑁ¯«⁐,-ᡂḄMM+<6,-Ḅïᓄᑺ74.8ூ᪆௃(1)জ᪷0ñòᑖ᪆ᑨõöᘤaḄøù^ঝ55%60࠷Aú⏚Uℍ⃔ý+)ᓄ5þ,-ᡂH2c2஺4,ÿ
ᡂN(hNOᱥḄ31,᪷ᵯᜫឤஹឤᑖ᪆ᑏঞ!
ᡂḄNChNO,ᙳᜧ$%&$'(◤⌕+$ᔾᦈ(NthNO.ᔾᦈ/01᎔ᔾ(2)₝⏚5╆[(NH4)3Fe(C2O4)3]᧕89:(;<=ᐸ:8?ḄpH@94.0%5.0A₝⏚5BCBD(

22NO+NO+2NaOH=2NaNO2+HOs2N0+2Na0H=NaN0+NaN0+H0+222322(2)₝⏚5B(NH4)3Fe(C2O4)3᧕89:(;<=ᐸ:8?ḄpH@94.0%5.0A(ᑣ¦Fe2(hᙠᤅ©ᩩ«=89RḄ₝⏚8?(UQ¬:pH@94.0%5.0A₝⏚5╆CBD(

23ḄNᑖ᪆☢Ḅ1⚔12☢ᐳᵨᡠ$Nᨬ&'()$ḄNᨵ12+ᳮ$-ᨬ&'()$Ḅ-ᨵ12.ঝ01234ᙳ6ᨵ7N87B9Ḅ:;<825,=>>?)$h,123cu25253l25g3r------7=-@-Wa2hcm3,123;<ᜧ7B73a2hdg,ᡠh=cm=3D/X10inpmo232dNA-dNAF——2ூ௃(1)G᪶᜜ᨵ7ᵯK᝱GḄ᪶᜜ᵯ᣸NOOPQ;S31TᐗVᵯ᣸NWIs22s22P63s23P63dzsᨵ8X+ḄY>ᡠK᝱Z(Ga)Ḅ᪶᜜ᐹᨵ8\X+Y<Ḅᵯ஺;8ᦑ_ᫀ+HIFTHTi(2)জH2N-CH2-CH2-NH2aGḄb>ᵯ:ᦪ:(5+3)=4,ᡠd⍝ᩖᓄhisp3ঝᔠ$Cu(en)2p+a+lmnd⍝oBpᑖaNlmq:ᵯrslmqᵯ:ḄtN,H,ᔠ$u᪀wWঞoBp8yzt᩽ឋᑖ}~oBpᑖyᑖ?ᡂᡠoBp᧕~y஺æ-/N-H.Cஹ/CH.ᦑ_ᫀsp3NICuI.oBpyᡂᑖ?oBpᑖyᑖᙳ᩽ឋᑖ;H£/ஹNN(3)জᨔu᪀Nᕜ)$ᨬ&ḄBᦪ4,ᓽᦪ4ᵫᨔ☢ᚮ⚔ḄNᑖ᪆☢Ḅ1⚔12☢ᐳᵨᡠ$Nᨬ&'()$ḄNᨵ12+ᳮ$-ᨬ&'()$Ḅ-ᨵ12;ঝ⌱ᨔ@u᪀aᨬḄ123ᓫ,᪷ᙳ01234ᙳ6ᨵ7N87B,9Ḅ:;<825஺1Gᓄ-+>aBN?Ḅ)$acm,ᑣ1Ḅacm,=>Q25v2>?)$h,123@MJ5a2hcm3,ᐸdgcnf3,ᑣ123;<¡J5a2hdg,ᡠ22252525h="36a2⚚=,3ᢚ2X1010pm,ᑣ>>?)$Ḅ⊤§W¨3ὊX1010pm»dN----dN-------dN&----A2A2A2

2425ᦑ_ᫀ4123©/io1%dN——A•229ஹ-203.5BDAஹC6.75xl04CH3OCH3+16OH-12e=2CO2+11HO«᩽C32ூ᪆௃(1)᪷¬®¯জx2+ঝx2-ঞ°±²LᡠéH=(-41.0kJmori)x2+G49.0kJmol-i)x2-(+23.5kJmori)=-203.5kJmori(2)A.ᔣ4⊝@µa¶ᐙᐭ7®<ḄCH30cH3¹@4⊝⌮ᔣ»¼½¾4⊝c(CH30cH3)¿ᜧᦑAX⌱.B.±²À᳛ᐜ¿ᜧÃÄÅƱ²À᳛ᜧ⌮±²À᳛4⊝ᔣ»¼ᦑB⌱.C.»Ç±²ᱥɱ²ᱥḄ@©ᑖ6<Ľ4⊝Ê⌮ᔣ»¼ᦑCX⌱.D.˱²ᯏÍα²Ïб²KÑ¿ᜧÅÆÒÓÔÓÔÒÊÉ4⊝ᔣ»¼ᦑD⌱.ÕÖᡠ×⌱BD(3)ØÒÖᓣBÚᓄÛḄÜᓄ᳛ᐜÖᓣÃÝÓÅÆᙠÒßÔà+à?ᑁ±²âã§ᑮ4⊝4⊝ÃØÒÖᓣBÚᓄÛÜᓄ᳛ØÒÖᓣåÝÓ.জA.ᵫaæçèÒé800KàCO2Üᓄ᳛a(CO2)ر²ÒᓣéåÄÅÆ˱²Ïб²éH>0,+à˱²¹@@Äê$<(),ᦑA┯ð.B.ᵫbCO2Üᓄ᳛a(COz)ᜧaᡠñᡂᱥòbᜧaᦑy(b)⌮ுv(a)ôᵫbã4⊝'ᔣõöv(b)jE>v(b)»,ᡠu(b)>u(a)⌮ᦑB÷.C.ᵫaæçèÒ4()0K~800Kà±²õö+à?Ãø°IrùúᓄᑺḄCO2Üᓄ᳛a(CCh)ßéÅÆIrḄúᓄᦔ᳛ýéᡠᵨIrஹCeùúᓄᑺà±²ḄþᓄYÓÔýÿḄ
Ir,ᦑC┯D.᝱dஹe
⊝᝱dᑮe,ᓣ⊝⌮ᔣa(CO»ᦑD஺ᦑᫀ"ACঝ$%ᢗᧇ4moicO2(7m0IH2,᝱e(900K))a(CO)=50%,ᑣ+ᓄḄCO22mol,ᑡ./0ᨵ"22co(g)+6H?(g)UCH30cH3(g)+3HO(g)22%(mol)4700+ᓄ(mol)2611⊝(mol)21133ᘤḄ5610L,ᑣ⊝7ᦪK==6.75x10%0.22X0.16(4)9ᵬ;<ᧇᵯ>?9ᵬ;@AᓄBᡂ9AᓄDᡠFGᐭ9ᵬ;Ḅᵯ᩽J᩽KᵯLMBNOᵫQᵯRSKOHTUᡠFᨬWXᱥD⏚᪷ᵯ᩽\]0"CHOCH+16OH-12e=2CO32+llH2Oᵯ>^_)O33ᵯ>Oᵯ>?▢aLbᔣJ᩽(5)cdḄᓄefghᡈjᡂ)Ḅklmᓄcd9ᵬ;(n⏣pᯠdᑖs᪀5u᥅wSlxdyᑖL?ᓄefz

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