云南省玉溪市红塔区2021-2022学年高三（最后冲刺）化学试卷含解析

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Pb=——~~-=0.5mobPb=+2SḄTU+,ḄPbḄᱥḄ=°.5moLᑣ+,ᵯḄᱥḄ=207g/mol0.5molx2=lmol,᪷XὶᵯᵯYឤᑣᵯḄ▢᩽?+,5MḄᱥḄ=0.5nwl,D┯$%ᦑᔠᳮ⌱⚗=B஺ூab௃d⚪ὃgCᵯEᵯh)CᳮᵯḄᵯ᩽+,FGᑨjCᵯFk᩽ஹᵯ▢□᩽mn'ᵯ᩽?534=od⚪ᐵqra=ᵯ᩽+,sḄtᑏ஺vஹw⌱x⚪yd⚪ᒹ{5|⚪}NHCHO:HOfOHHOjOH17ஹ⏚q~+,ᡈᡈH(CHONH:CH>CH,COOHCOOHCOOHJFKhHs(h11xO-C|ClClKtCCh1i*C♦()..()yNH,ooHJ|,I1COOH1C(X)H1..NHNO,tOHூ᪆௃COOHCH»CH,B@⏚ឋ'⏚3ᓄᡂC,ᔠAḄ᪀sB-?(v|ᙠ᪷P.,*11,IHXX-CI,,V(&E>%“ஹ,5Ci+,⏚ᓄ⏚ᓄ+,yU+,}ᡂCHJSOJNHCOClᡂᑖs-Cl5H7CIF3NO4ḄF,F+,ᡂ᪀ὅḄ᪀s?F-CI,ᑖ᪆஺

14ூê§௃COOH᪷Éív,Cr+,ïðÁ`Bñ⏚ឋòó⏚zôᓄ1ᡂC,õᔠAḄõ᪀÷ðÁBᙠùøI—.CH»IKKX'ú⏚ûᓄùü⏚ý1üᓄ)^+þÿ
ᡂ»7';HrCFLSOxXHCOᡂᑖG5H7CIF3NO4ḄF,F“7Mᡂ,᪀ὅḄ᪀H,!IIOX*Cl
IEτஹ#,“$L,&'()*+,⏨./01CH,CH»2A-B2ᙠ45⏚7ᓄ94:⏚:ᓄ;<
ᡂ=ஹ”1?@
1NH,COOH
3D,ABᩩDজF)GH)FeCbIJK⁐HᑣF&ᨵO.PQ0H&ᨵROHS01ঝᑖUᨵ4VFWᓄXY᛻Ḅ[Hᑣ\]^,H_`Yabᨵc
0ᑣ^deᨵfc2RS0HᑣgiQ—cu\5_`Yaᨵhc
0HᑣcRS0e^,ஹfci0fcj0HkᔠᩩDḄᨵCH,fHCOOHCOOHCH,
5m,1ng
oᧇᑴᜓ7=\/=<,,mHᙠsᓄtḄ7ᓄ9s஺/H࠷YAYAN
2UOH

15COOHCOOH⏚ஹ£3>n¤¥⏚)ᵨᡂூab௃d⚪ὃgᨵ§ᔠᡂn¨j⚪Ḅᐵq=ᑖ᪆+,©ªஹ¨Mᔜᨵ§ᱥn+,Cᳮd⚪Ḅra=ᔠ⚪ᔠᡂ«¬ᔠᳮḄᔠᡂ®ᫀ°±⚪²³Ḅ´஺------->CT?'+3NaCl+2H2OCoONa(1)᪷AḄ᪀sᑨjᐸ¶·=¸¹,Dº»¼-½ஹ¸C%¾¿DஹEஹGḄ᪀+,ঝ-"ᡂ+,,ᦑᫀ-.¸¹%½ஹ¸C%"ᡂ+,;(2)G93ᓄÂÃ+,>+,ÄῃÆ1ᑖ>ᡂÇᡂÈ~E93ᓄE+,ᑣ+,®OHQHPs-...JX.jOH----------►\-3\aCKH()>COONaOH_,pHᦑᫀ-.SHJNaOH--------\COONa(3)É.HO-CH—Ë-¨+,ঝÍ5ᱥ-ÎÏGÐ’᪀s-:

16(4)GḄÓᑖÔ᪀LL⍗FeCbÂÃÖ⁐67ØᨵÙÐÚÛ>+,ÜÝÞ⁐ßà567ÙÐáâஹ¾âãᨵHCäLNaOHḄå⏣ÂÃᐳè»+,ᑣLØᨵ-CH2cH2aᡈ-CHCICH3,LÎÏ?BØᨵ2-Cl,LNaOHḄå⏣ÂÃᐳèéÐ+,BᓴëḄìÆ+,ᡂᱥḄ᪀s-.19ஹឤíîÃïᧅ!ᜧ>ᩰ½Ḅᓄ᳛néᑖ;Må⏚E>ôõ+,ᱥḄᓄ᳛öèᙳᒴùúûᑴýþbÿ
ᑁᑖᘤ2cH3coOH+CO32-=2CH3CO(r+H2O+CO2ta80%ூ
᪆௃(1)᪷ᘤḄ᪀⌼(2)᪷⊝ᓄ᳛Ḅ!ᦔ#(3)ᑖᘤ$ᑖ%&ᱥ(4)(⚠*+◤⌕.ᑴ0123ᑖ᪆(5)5ᔠ⊤89ᐵᱥ;<=Ḅᦪ2◤⌕?@⏚BC2@⏚0Dᶇ;(6)GHIJᑖᘤKᓄḄLM(7)NO⏚ᑴᜓQ⏚ḄRᳮ(8)TUBVḄWXYZ[GBVᡠᵨWXY9^᪷_`Ḅ;a'cCᓄdᡂḄ✏ghᳮi&a’᪷&᳛=||m*o஺஺q஺(9)ூ
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17(3)rsᑖᘤ$
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ᑖ%@⏚2
ᑁIJᑮᑖᘤ2ᑣ$¢ᑨ¤_`¥¦§ᐰ(7)©⏚ª«@⏚_`dᡂ@⏚ªஹ®ᓄ©2ᐸ%°±²³´2cH3COOH+CO32-=2CH3CO(T+H2O+CO2T(8)TUBV
2⌱¶·¸WXYᓽ$2ᦑa⚗95%x38.5g73g(9)ᩰḄᱥ;Ḅa=,1=0.2998nwl,@⏚{Ḅᱥ;Ḅa-=0.7157mol,ᑣ$@⏚ºHa2ᳮ122g/mol102g/moli»$dᡂ✏ghḄᱥ;Ḅa=0.2998mol,ᐸᳮi&a=0.2998molxl46g/mol=43.77g,ᑣ&aw▭yz35axlOO%=-~~—xl00%®80%»ᳮ|yz43.77g20ஹ(1)¼½⏚᪷%°¾%°஺(2)জ2Ag++SO33=Ag2SO31஺ঝ¼½⏚᪷ᨵÁRឋ2îᓄ½⏚᪷%°2ᓽ$Z¾%°5ᔠdᡂ½⏚¾ÄÅ஺(3)Ha¼½⏚ª஺(4)জᑨ¤Xvᔲv®ᓄ¾஺ঝᨵÁRឋ2Èᨵ¾ᐗh2Ƚᐗh஺@Ag+2HNO()=AgNOj+NOt+H2O»(5)জ®ᓄ½஺ঝA22SO3+H2O”+2Ag+H2sCh32ூÍ᪆௃(1)জÏÐaÑ⁐ÄÅA&SCh,Ag+ZSO3?_`dᡂAg2s03,Ag2s03ÓHaḄNa2s(hÓ,dᡂÄÅḄ%°±²³´2Ag++SO3”=Ag2so31ᫀ´2Ag++SO2-=Ag2SO3h3ঝÏÐaÑ⁐ÄÅAg2sCh,ᐸ᪷SO3?ᨵÁRឋ,$ÕîᓄSO42",ZAg+_`dᡂAg2sO4Ñ⁐ÄÅᫀ´SO3?ᨵÁRឋ2îᓄSO4*,ᓽ$ZAg+5ᔠdᡂAg2s04ÄÅ஺(2)Ag2s03Ñ⁐2ÖÓ2ÓHaNa2s03Ó2×BஹCÑ⁐ÄÅ2sNa2s஺3Ó2ÄÅÓÍ2ØÙBஹCÑ⁐ÄÅAg2s03Ú×Ag2sChÛ2^᪵ᩩÞsßaNa2s03Ó,~᯿áâ,ãLÄÅÓÍᫀ´HaNa2s03஺(3)জ®ᓄ¾Õä⏚dᡂÑ⁐åᓄ¾ÄÅ2ÓḄpH=2,&dᜧaÑ⁐ÄÅ2
æ2&dçèéêë⁐ᱥ;X,ᔣXxíä⏚2îÙïKᓄ2ØÙXvAg2Oᫀ:ñâXvᔲAg2O஺ঝᔣXᐭHaHNO3,&dóê⁐ôNO2,XZõ⏚ãd®ᓄÁR_`2XᐹᨵÁRឋ2X÷Õøùᓫ;2÷Õ¾û3XÈᨵAgᐗh2ÈSᐗhᫀ:ᨵÁRឋÈᨵAgᐗh2ÈSᐗh஺ঞᔣXᐭHaHNQK)2&dóê⁐ôNO2,¾õ⏚_`2ýᐗh+5K+4þ2^
dᡂõ⏚¾2_`±²³´Ag+2HNOK)=AgNO3+NO2T+H2஺ᫀ´Ag+2HNOKᱏAgNCh+NChT+IhO஺(4)জ⁐ᱥXAgḼ⏚ឋḄ+4Ḅឋ+1ᓄ+4Ḅᓄᱥᓄ!"#$%&ᐭᓄ()*+⁐,-Ag2s03.ᓄ⁐Ag/%0ᫀ23SO2஺

18ঝXAg,+⁐,-.ᓄAg,ᙠ⏚ឋᩩ78,:⏚*+4Ḅ,+1ᓄ;ᡂ=⏚,>?3Ag2s03+HO@2Ag+H2so—/%0ᫀ3Ag2SO+H2O@2Ag+H2so4஺2321ஹ-71.4kJ-mol-'0.225mol-L-1-h-140%C2H4CD(ᡈGHᑖJKLMN)48ூQ᪆௃পᑭᵨWXYᑏKYᓄ[\]^_᪷abcdefghᑮᡠ◤Yᓄ[\]^;ফজ>?n᳛pqfghᑮὑzঝ>?ᱥ.ᓄ᳛=xlOO%1বuv^ᑡ^fgx⊝zN{ᱥḄ|D}~N{ᱥḄ|}~fghᑮᔜN{ḄᑖDᔠx⊝ᦪᭆfg(4)জᵫᓣNᱥḄ|ᜧx⊝⌮ᔣᑣ/>?2Y>?ঝᓣx⊝⌮ᔣaḼᓣᱥḄ|ᜧᓄbஹcḼᓣᐸᱥḄ|;ᡂᱥLஹ¡LḄ¢ᓄ|ᜧঞ¤H2Ḅx⊝.ᓄ᳛◀ᦋ¢᜜¨©Ḅª«2ᜧD஺ூ¬Q௃(1)ᙠlOlkPa8CH>COஹH2ḄWXY(”)ᑖ¯-890.3kJ/molஹ-283kJ/moR-285.8kJ/mol,°±ḄYᓄ[>?4\]^ᑖ¯3জCH4(g)+2O2(g)=CC)2(g)+2H2O(l)Z\”=-890.3kJ/molঝCO(g)+0(g)=C02(g)AH=-283kJ/mol2ঞH2(g)+O(g)=H2O(l)AW=-285.8kJ/mol2᪷abcdeᵫজx2-ঝx2-ঞx4h2CH(g)+0(g)=2CO(g)+4H2(g)AH=|(-890.3kJ/molx2)-(-283kJ/mol)x2]-(-285.8kJ/molx4)=-71.4kJ/mol42(2)জ²>?ḄᓄᱥḄ|x,N{D}~N{ᱥḄ|}~co(g)+3H2(g)=CHQH(g)+HO(g)22(mol)1300(mol)X3xXX2g(mol)1-x3-3xXXP(3P³=(4-2x)(1+3)=0.85,Qh3x=0.3mol,ᑣᵨN⊤µ³2¶z>?xᙳn᳛

193x0.3molV(H2)=2L=0.225mol/(Lh)2hঝᑮ⊝᝱H'ᓄᱥ¢Ḅzy,co(g)+3H2(g)UCH30H(g)+HO(g)22(mol)1300(mol)y3yyy(mol)i-y3-3yyyP¦§P¨=(4-2y)(1+3)=0.8,G©§y=0.4molª«]9Ḅ⊝¬ᓄ᳛=®¯xl00%=40%Imol(3)_ᩩD±²8MPa,300CḄ«]9'ᓄ[³ᢥ1:3Ḅµ¶·ᐭH¹©'ᓄḄ⊝¬ᓄ᳛50%,ᔠº»ᑡ½¾,82(g)+3H2(g)UCH30H(g)+HO(g)2(mol)1300(mol)0.51.50.50.5(mol)0.51.50.50.5ÀML.Kg“ÂᵨÄ-”ªᱥ¢Ḅᱥ¢Ḅz.8x0.548x1.54ᑖ±=űXᱥ¢ḄzᑖᦪHᱥ¢Ḅzᑖᦪ=—⎋Ḅᱥ7Ḅef,ᦑP(CO2)=---=-,P(H)=---=4,244—Ëf8x0.548x0.54331,P(CHOH)=---------=-,P(HO)=----------=-Kp=--=f(MPa)2323333—x433(4)জᵫÍ!Hᓣ\«]H[³ᱥ¢ḄzÏᜧHÑÒ⊝⌮ᔣÕÖHᑣ×2ØÙHᦑÚ”<()1ঝ᪷ÝÍ!Hᓣ\«],[³ᱥ¢ḄzÏᜧHÑÒ⊝⌮ᔣÕÖHᑣ×2ØÙ1஺ÞßàḼ«]ᓣ\Hᱥ¢ḄzÏᜧH'ᓄHâcàḼ«]ᓣ\ᐸᱥ¢ḄzäåHᡂᱥஹæçHèḄᓄzᜧæçHᡠÂcÞß⊤C2H—ঞᵫÞßᓄ!àḼ«]ᓣ\H[³Ḅᱥ¢Ḅz⌲îÏhHÑÒᓣ\«]⊝⌮ᔣÕÖHᑣ×ØÙHª³᝱ᑖᦪïgḄHð\H2Ḅ⊝¬ᓄ᳛H◀ᦋ«]᜜Hôõ
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