山东省泰安市2022-2023学年高三上学期开学考试化学试题及答案

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6tḄឋ᝞Jᡠ஺ÍÎyÇᓄᑺjজÇᓄᦔÐᨬwḄÑÒ᝱ÓᡂÕḄᵯᦪঝÇᓄᦔÐᨬÖḄÑÒ᝱Ḅ×Øᵯ᣸@#ÎஹÙÚÛf⚪17.:ÜᙠᵯஹÝᐝஹ᪶ÙÚஹàáâãäuåᢈ⚞èᨵéêḄbᵨ•ì(Sc)Qxy:ÜÑÒ,ᑭᵨîïðᦈÑÒìò₝⏚ḄÙõÛf᝞Jᡠ஺)ᑡ⚪jScîïðö÷jজxNH4cl»ScF3-zH2OQ“øì”efScF3]ùᓄᱥᡂḄúûøü*ᙠý⏚þᑖ5Æ஺ঝ“ῃ◀┤”Ḅᑖ஺ঞ25࠷ᑖᱥḄᐵ᝞⊤ᡠKp(PbSO)Ks(PbCO)♦(H2c2஺4)Ka2(H2c2O4)S4P242.0x1O-85.0x10-'06.0x10-26.25x10-5(1)“ᯏ#''%ᡂSC2O3Ḅᓄ()*+

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9ᑡ⚪:(1)AḄ8,D—EḄ¡8(2)D5¢£¤Ḅ8(3)B-CḄ¦§M8o(4)FḄª᪀¬M8஺(5)Cᨵ®¯°ᑖ²᪀°³´µᑡᩩ·Ḅ°ᑖ²᪀ᨵ¯;জᑖ¹5ºᨵ»¼஺ঝᑖ¹5ºᨵ2½-CH2OH஺ᑏ¿ᐸ5.¯᪶ÁᐳÃÄÅ5Æ☢ÇÈÉ84Ê3Ê2Ê2Ê1Ḅª᪀¬M(6)Ì᯿ÎÏᔠᡂÐÑÒ»ᵬ⏣Õ8Öᧇ(rvØᑺÙ⌱)ᑴᜓ/CH20HCHZCH'EOHḄÝஹÖᳮßᔠ⚪20.à᯼câᣚäᵨᜧæçᑴH?,Öᳮ᝞ÊCO(g)+HO(g)^=iCO(g)+H,(g)AH—41.2kJ/mol஺22(1)îï5ðñòlcoḄ6ᓄ᳛õòlö᳛ä÷øḄ.⚗úû$ü(2)ýþÿᐸᩩᙠᢗᐭCaOᜧH?Ḅᑖᦪᓄ!⊝Ḅ#$%&'())(3)ᙠᐸᩩ-./01234.56ḄCaO(89:;<9:)ᢗᐭᵯᑖᦪ>/?ᓄ᝞AᡠCᐸ⊤C89:CaOEH?ᑖᦪFGHIḄJKL(M“a”ᡈ"b”),ᑨUᳮᵫL஺H的2体积分数(4)[᯼]ᣚ_`ḄaᳮbcdẆfᐸᨵ2hᵬ⏚kaᳮlm᝞n:জHq*rOH*+H*OsurE=49kJ-mor1al

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11¼ὃ¾ᫀ)1.cூÃ%௃A.ᵫÆ☘È⌕ᡂᑖCU3ÌCO3Í2ÌOHÍ2ஹÆÏÈ⌕ᡂᑖCU2ÌCC>3ÍÌOHÍ2Ñ"CU0H2”ÒÓ.ᑣÆ☘ஹÆÏḄÕ⁐.A×ØB.ᩋṺÈ⌕ᡂᑖLHgS,ÞSᐗàáâGᡂSO2,ãFGäåឋ]ᕡḄ]B×ØC.ᐹᨵéឋḄLFesCU,ìÆÈ⌕ᡂᑖLFezCh,ÞᨵéឋC┯ðD.¢òᐗàLᐗàᕜô⊤II1BöᑮVIIIöḄᓄᐗàøùÕᧇḄûüᐗàCuஹFeஹHgᙳüþ¢òᐗàD×Øᦑ⌱
Co2.Aூ௃A.⏚CaSCU◀ḄCaSCh,ᐜᐭ"⏚#$CaSCU%ᓄ'CaCXh,)*+ᐭHC1◀A⚗┯01B.“84”789Ḅᨵᦔᡂᑖ>NaClO,NaClOᐹᨵCDᓄឋFGHIJឋKᵨMᩔO78B⚗PQ1C.FezCh>U⁐WXKᵨYZ[ஹ]ᧇஹZ_ḄU⁐`ᧇC⚗PQ1D.bDᓄ#ஹcDᓄ"dᡂDefᵨYgᔾ☢ᐹḄjDᑺD⚗PQ1lᫀ⌱A஺3.Aூᑖ᪆௃Bqrᨬ᜜uᵯrᦪ>ᵯruᦪḄ2x+yᔠqr{|qr}ᦪḄᐵKB>Cᐗ10.1mol/LḄDḄᨬDᓄᱥḄᓄᱥ9pHSᐗ1EDqr}ᦪᜧ{|ᦑE>C1ᐗ1ABqr}ᦪ{|ᦑA>Hᐗ1CBqr}ᦪᜧ'ᐗᔜᐗᜐ஺MᦑC>MgᡈA1஺ூ௃A.ᕜ¡qr}ᦪ¢ᜧqr{|¢qr{|
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14"¥H+O='HO»A┯\2222B.Pdᐗᙠ[PdCL]\[PdCbOTḄᓄᔠ}ᙳ"+2}Pdᓫ§Pdᐗ"0}B┯;C.ᵫbcᳮজஹঝᙳ"$ᓄ«¬bcঞ®ᨵᐗᓄᔠ}E¯ᓄ"°$ᓄ«¬bcC┯\D.ᵫbcᳮHC1:crᙳ±²ᑭᵨD\´ᫀ⌱D஺11.Bூra௃A.gIJ¶·᧕ᑖaNaOH¹%º?DgIJ»IJḄᑖa¼EII"½ឋ%¿Àᵨ⏚ឋÁÂᑺA⚗┯\B.Ä⏚┛:7Æ⏚bc"ÇÈÉᑴᜓ#$ᓄÄ%ᵫDÆ⏚ᐹᨵᢵឋᑴᜓGᩭḄ%=ᨵÎHḄdᓄ<%ᵨ⛳:NaHCCh?@◀ÑB⚗\C.gÆ⏚:#$ᓄ═ᙠ5·ᩩlm"ÇÈÉᑴᜓCL,ÓmgÆ⏚º#$ᓄ═¿bc,C⚗┯\D.gÔ⏚:+¼ENO2%ÕḼbc×gÔ⏚⌲Ù¯ᡂ7Ô⏚ᑣEᡂḄ%"NO,ÛNaOH?@ºNOEᓄbcD⚗┯\2´ᫀ⌱B஺12.Cூᑖ᪆௃ᵫ⚪᧕ÜÝÞº<$ᓄß?@à·bcEᡂáÞ⏚ß:<ஹ╅¿º<$ᓄß?@bc;U)ᑮVᨵஹ╅ḄU[:áÞ⏚ß?@\ᔣáÞ⏚ß?@5ᐭÄ⏚<᪶?@?@ÞPQºÄ⏚<᪷bcEᡂ<$ᓄÞST:Ä⏚᪷PQ;U)ᑮ<$ᓄÞST\<$ᓄÞST?D78⏚å5ᐭ8⏚æçghஹèᓾiᨔஹ;UஹêëஹÁÂ)ᑮìẆ஺ூra௃A.ÞÀº<$ᓄß?@:<$ᓄæ?@bc¿Àºî½IJbcᑣ?a᧕ÜÝ¿ÀᵨIJ~ï<$ᓄß?@ᦑA┯\B.ᵫᑖ᪆ST"<$ᓄÞᦑB┯\C.#$ᓄÄðÀºáÞ⏚ß?@bcEᡂ<$ᓄÞSTᑣᵨ;HḄ#$ᓄÄ~ïÄ⏚<-)ᑮ<$ᓄÞSTᦑC\D.ᵫᑖ᪆U[Ḅñ⌕ᡂᑖóஹ╅ᦑD┯\ᦑ⌱C஺13.BCூra௃A.ôõöÀᵯøᵨᑮᦋ⌼Ḅûü%ýþmÿ
ឋᵯᦔ᳛ᓣA┯B.!"ᐹᨵ%&Ḅ(ᵯឋ)*+,᪀ᡂ/01᪀234ᜧ,6☢849a᩽;Ḅ(ᵯ2<B=>C.ᵫ@ABCb᩽DEFGHIJᔠᵯ᩽ᑣb᩽DM᩽ᜫᵯOa᩽D=᩽ᵫP@BC

15a᩽DFePO,RᵯOSᐗUᓄᔠW1ᔠM+XᡂMFePO,,ᵯ᩽YZ[D:FePO+M*+e=MFePO,C=>44D.ᵯO2]ᵯ^_`abcD┯dᫀ⌱BCo14.BCூh^௃A.᪷kᙳmnᑣFeMḄᨔpqFenOᦪs8xt+6xJ=4ஹNnOᦪs1,86FexNyḄᓄv[DFe&N,ᦑA┯B.NnOxyᨔpqz{N|}~ᨬḄND6ᦑB=>C.axFeḄᨬ}D☢Ḅ☢D&apm,ᡠaxFeḄᨬ}Dapm,ᦑC=>D.2CuᐰᨔqbxFeXᡂḄᱥ
2ឋ9ᨔpqnOᦪ8x)=1ஹSnOᦪs6x4=3ஹNnOᦪs1,ᓄv[DFesCuN,ᦑD┯⌱BCo15.ADூh^௃A.NH4HCCh=NH+HCOt,NHtHCOᑖ^HC0+H,0fHCO,+OH,2NHt+HquNH/H,O+H+,D>1,ᡠc(OH-)>c(H+),ᑣ¡HCO^¢ᜧ£c(H)ᵯ¤ᑮ¦`ᦑA=>B.§ᐭ©NaOHªHCC>3«¬!NHt«®¯°ᡠ0Hᐜ{NH²⌕YZᦑB┯;¶H+-c
COc¶NHc
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NH3H2O=£wc¶HCO-*C
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NHH,O,@q3233K“XC
NHc
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16Is2s2pযপ½¾¿EHHite(2)H>BB>N>HH(4)33d64s2ூ^᪆௃(1)Ns7ᐗUWᵯO᣸Â[D2s22P3,ᵯOᓰkᨬ2ÃḄᵯOÌÍÎ@D½¾X¬᝱NnOIs2s2pḄÏ⍝⊤A[Dτ]]]111τ||τ—τ—(2)BAlḄ¬᝱nOᵯO᣸Â[ᑖDIs22s22PlIs22s22P63s23p௃BÔ°Õᵯ2ÖAlᜧIi(Al)<800kJmor',D3P2ÃḄ2y2P2ÃḄ2ᜐy3P2ÃḄᵯOÅÆ᧕ᜫÈh(Al)<"B)(3)জ{NnO*ØḄHᕈ=ᵯឋ(H$+),ᵯMឋN>H,{BnO*ØḄHᕈMᵯឋ(H,ᵯMឋH>B,ᵯMឋᵫᜧᑮ°ḄÚÛsN>H>BঝÝᕜßᐗUàPᑮáÔâ㯰nOÔᵫᜧᑮ°ḄÚÛsB>N>HঞHD{s;BஹNxyp;ᙠᐗUᕜß⊤qḄᑖ;{ᐸçèÝḄss(4)জà@éBêëC஺íᓄᵨªᨬïðñ8òᨬᜧᦑíᓄᦔóᨬ&C஺ḄWᵯO᣸Â[D3d74s2,nOqôᡂḄᵯOᦪD3ঝà@éBêëFeíᓄᵨªᨬõðñ8òᨬ°ᦑíᓄᦔóᨬöFenOḄW÷ᵯO᣸Â[D3d64s2øù17.(1)2SC2(CO4)3+3O=—=2ScO+12CO22223(2)1t2AA(3)ScF3+H2O^=ScOF+2HF(ᡈScF-6HOScOF+2HF+5HO)◀ý”ªNHC1ᑖ^ᡂ3224HC1,ᢓᑴSc3+Ḅ(4)1.5x104PbSO4

17ூ᪆௃(1)ᵫSC2(C2()4)3ᯏᡂSC2O3CC)2,ᜫᵯឤឤ!"Ḅᓄ$%&'(2SC2(C2O4)3+3O22SC2O3+12CO2஺(2)“xNH4Cl-yScF3-zH2O”ῃ◀╆-ᢣῃ/0ᨔ2ᓄ╆2ᓄ╆34ᑖᡂ672ᓄ8ᡠ:;<=>ᡠ:380~400࠷@ABCDḄEF'2ᓄ╆ḄEF200~300࠷@CDḄEF'ḄEFᑣ2ᓄ╆ḄᱥEḄF'(5I?,01g=006mol,ḄᱥEḄF'(Lᑏ⁠=0.12mol,53.5g/mol18g/molx:z=0.06:0.12=l:2o(3)SCF36H2OOPQRῃSCF3,STUVᨵScOFᩖEY-QRῃ@ScF3;Z[!AA"ᡂScOF,0ᔠឤ!"Ḅᓄ$%&'(SCF3+H2O=SCOF+2HFᡈSCF3-6H2O=ScOF+2HF+5H2O^_“Oa”“ῃ◀╆''ᑴdefQḄScFᐸY-“◀h”@NH4cl3,ᑖᡂHC1,ᢓᑴSc3+Ḅ஺(4)6jk*“C2(H+)-C(SO;)c2(H+)-c(CO^).c(Pb2+)-c(SO^-)2C(HCO)c(HCO)c(CO;-)c(Pb2+)2242242Ka,(H2C2OJ-Kil2(H2C2O4)-Ksp(PbSO4)6.0X10-2X6.25X10-5X2.0X10S<----------------------------------------=1.3x1I0N4ᙠn⌕ᡂᑖ-Ksp(PbC2O4)5.0x10'°H2c2஺4Ḅp_qᐭPbSO,0ᔠ!"PbSO4(s)+H2c2O4(aq)UiPbCzOMsHZH+gqHSO((aq)4ᨵDFPbS04sᓄ'tPbC2O4,ᡠuvᵨxy⏚ᜐᳮ@}ᜧtᡂᱥḄxe⊝⌮ᔣᡠ:ᡠ“OP”-PbS04஺A18.(1)MnCh+4H++2cl-=Mn2++Clt+2HO22(2)⛳ᢵ[Ḅ2ᓄ8;C_ḄNaOH!"NaOHḄᑭᵨ᳛(3)!"ᡂḄNaOHᡂ2⏚QᧇḄᑭᵨ᳛(4)■ReQᡂNaCICh142V(5)ᐭᨬNa2s2O3@Ḅ⁐¢/£ᑖ¤ᑁ¦⁐§ឮ©--%¬WQூᑖ᪆௃ᙠA_ᵨMnO2x⏚ᑴ27ᵨ⛳◀/27_ḄHC1,27TᐭNaOH

18_ᡂḄNaClO®¯°⏚!"ᡂ±2®²°⏚ᨬᵨNaOHᔾᦈµ¶Ḅ27஺(1)AA_ᵨMnChx⏚!"ᑴ27!"Ḅ·%&'(MnO2+4H++2Cl=Mn2++C12?+2HOo2(2)ᵫ¸⏚ᐹᨵᢵ[ឋᡂḄ27_»ᨵHC1,¼§◀/HC1,ᑣHC1½ᐭC_;¾ὑNaOH,NaOHḄᑭᵨ᳛ᡠ:⌕ᵨ⛳◀/27_ḄHCL(3)NaClO®²⏚!"ᡂNaOH,!"_§ÀTᐭ2727:ᡂḄNaOHÁÂ!"ᑮ®Ä⏚!"ḄNaClO,QᧇḄᑭᵨ᳛஺(4)ᙠq4ᩩÆÇ27NaOH!";ᡂNaCICh,ᡠ:C_ᵨÈÉ஺(5)জ±2®²°⏚ᙠ⏚_sᓄ'HC1O,HC1OËKIÄᓄ'L,qᐭPÌÍᢣÎᑺL⍗PÌÑqᐭḄNa2s2஺312!"ᡂÒᡠ:ÓᐭᨬÔNa2s2஺3@Ḅ⁐¢/£ᑖ¤¦⁐§ឮ©ÕᑮÖ×Ø஺ঝ᪷!"%&(HC10~2Na2s2O3,25.00mL¾ὑḄNa2s2O3ḄᱥEḄF'0.1000mol/LxVx10-3L=Vx1O^mol,n(HC10)=5Vx10-5mol,100mL_”(HClOAZVxlO/mol,᪷ÛḄn5TÛM=2Vxl0'4molx35.5g/molx21.42Vᨵᦔ2Ḅ⊤Õ&ᨵᦔ2=---------------2-----------xl00%=--------%஺wgwঞ¼ÖâÖãäᘂᨵ7æÖ7æ¾ᜫᑣ¾ὑḄ᪗èBé¬ᜧᨵᦔ2ḄêÖëˬQ஺19.(1)ᵬíî!"(2)ïðஹò

193CHOH^^CRCHOH222CHOH2(5)10(Cj—2H—CH20Hlóôஹõஹö3ó,᪀6ஹ^\H20H᧼XXᡈ£HOH(fT%H20Hø.2CHHOHCCHOH322CHOHCHBro0/஺22(6)|j^%|úH_û2tNaHஹTHF07AH>/_\__ptrü/þ஺11THFV_/^^OHCH2BrCH3CH2Br!"#$%ᡂூᑖ᪆1AᓄBr<ஹ᪷AḄᑖAJ%,!'#$()'ᡂ*UCHBr2[^1+,-⏣!'#$()'ᡂcOH,+23ᓄ/!'#$()'ᡂDE!'01()'ᡂF,F+,⏚!'5ᓄ()'ᡂG,᪷GḄ6᪀,OH78FḄᑖFீ-(1)CH3A13,:;ᵬ=>?@£B[+I1!'#$஻C2H50-2H5஺࠷2Hs()'ᡂEFHBr,()GH#$()>OC2H5(2)

20OD,JKLḄ:;⏨Nஹ31;(3)()PQFḄ6᪀7(5)CᨵSTUᑖ᪀VUWXYᩩ[ḄUᑖ᪀V:জᑖ^_ᨵ=`,ঝᑖ^_ᨵ2b-CHzOH,CILCH20HCH20HCH-CH2OHIT,cஹdஹe3T,᪀6Tfᐳ10CHOH2T>ᐸ^@T᪶kᐳlmn^o☢qrs4322IḄ6᪀7ᡈt᯿vwᔠᡂyz{=ᵬ⏣F1ᧇ~ᑺ⌱ᑴᜓ|0C2H5CHBrCHBr22HzCnfRH,=ᵬ⏣+HBr()'ᡂஹ+XUOH2

2120.পHzO(g)Ḅ(2)CaO{FᱥCO?()ᱥḄ⊝ᔣ(3)aḄCaO⚩¡¢⊤☢qᜧ+CO஺¥¦ᐙᑖᔾᦈḄCO?S()▲ᜧ«VqᑖᦪᜧভঞOH-(5)P50%10()ூ¯᪆௃(1)²()³VVq´µḄ¶·()'^ᵨ¹ᜧ()ᱥº»³Ḅ⊝ᔣ()Pᔣ¼@½ᓄ/Ḅᓄ᳛¿()À᳛ᦑÂᫀHQ(g)Ḅ>(2)ᐸÄᩩ[´µᙠVÆ^ᢗᐭ@ɽᓄ┛½ᓄ┛+'ᡂᱥ-½ᓄ/()'ᡂ/⏚┛'ᡂᱥË¢⊝ᔣ()Pᔣm³ḄVqᑖᦪ¹ᜧᦑÂᫀCaO{FᱥCO,()ᱥḄ⊝ᔣ>(3)Ḅ½ᓄ┛⚩¡¢,⊤☢qᜧ+-½ᓄ/¥¦ᐙᑖ,ᔾᦈḄ-½ᓄ/S()▲ᜧm³Vqᑖᦪᜧᡠ{Ízaνᓄ┛em³VqᑖᦪḄÏÐᦑÂᫀa>ḄCaO⚩¡¢⊤☢qᜧ+CO?¥¦ᐙᑖᔾᦈḄCO?S()▲ᜧÑVqᑖᦪᜧ;

22(4)()ḄÔÀÕÖ#×Ø()À᳛ᨬ᠒Ḅ()()ḄÛᓄKÜᜧ()À᳛Ü᠒ᵫ⚪ßÛᓄKḄᜧ¢()ঞḄÛᓄKᨬᜧB()ḄÔÀÕÖ>ᵫ1bᦪàឤ()ঝ^âᑏäḄåOH*,ᦑÂᫀঞ>0H*;(5)জᵫ()CaCO(s)UCaO(s)+CC)2(g)Ḅ⊝óᦪKõPoKPa,Aù-½ᓄ/ḄᑖúPoKPa,3ᑣAùḄᙶ᪗(t,Po),ᦑÂᫀPo;_20R,-10Pnঝᵫ⊝Ḅᓄ᳛ᦑᫀ50%ঞᵫ⊝!"ᓄ#ஹஹ%"ᓄ#ஹ&'Ḅ⊝ᑖ)ᑖ*PoKPaஹ10PoKPaஹ10P°KPaஹlORxlORlOPoKPa,ᑣᑖ)⊝3ᦪKp=p1op(=10ᦑᫀ19஺