有机化学(冯骏材编)课后习题答案

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1ஹᐗḄᓄᔠᱥᨵᓄᔠᱥᨵᱥ஺ᐸᡂ◀ᨵ᜜ᨵHஹ஺ஹSஹNஹP஺ᨵᱥ
ᨵᐗᡂᨵᐗḄᱥ!
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0VᨵWXᩖᓄḄp(⍝ᚖZ'30sp2ᩖᓄ(⍝ᡠᙠḄ]☢஺sp2ᩖᓄ^_ḄBCᙠ8
]☢`abḄᜳG>120°,ᑖIᢣᔣKcGRḄ30⚔P஺spᩖᓄ%ᵫ
02s(⍝*
02P(⍝deḄᩖᓄfᑮ206ᐰ8Ḅspᩖᓄ(⍝,>spᩖᓄ஺?0spᩖᓄ(⍝ᐹᨵ1/2Sᡂᑖ*1/2pᡂᑖᒕUḄ20VᨵWXᩖᓄḄp(⍝!hi-ᚖZjᙳᚖZ'20spᩖᓄ(⍝ḄBC஺3ஹ஺l%Q12Ḅᵯ2nᐳC“ᜮrᜮ”tu஺nl%Q12Ḅᵯ2nᐳ☢“vwv”tu஺Enlx
Ey஺lx஺4ஹz{|}᪀%HH——IH-C-c-B——IHHHOH——H——HH-C-C-C———
—HHHHOH

1H—C——C=NHOHIH/HcCNI\HH5ஹᙠᨵᓄᔠᱥᑖ2-8}᪀!8Ḅ>8ᑖ᪀஺ᑖ>᪀⌼᪀N*N᪀N஺6ஹ⌕ᨵQ9%
#ᢥ᯿ᨵᓄᔠᱥᑖ2Ḅᑖ>ᓄᔠᱥ*ᓄᔠᱥ;
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ªᱏᡠ¾¬,/¥¦>ᐳ¤lḄ¦஺¦®e¯Kᵯ₹ḄÀ2*¯Áᵯ₹ḄÀ2஺¢£ᐳ¤lḄ¥¦*Âᐳ¤lḄRᡂ#8§de#Ã8•Ä6ᡂḄ¢£ÅÆÆÇ᝱஺8ஹÉÊᵯ2BḄ#Ë᧕Í⏚ÏÐᵯ2BḄ#Ë᧕ÍÑ஺Ò1ஹy12-ᵬ²ÔÕy22,2,3-cᵬ²ÖÕy32,3-Òᵬ²-3-ײÔÕy42,4-Òᵬ²-3,3-ÒزÔÕy52-ᵬ²-3-زÙÕy61,1,-Òᵬ²-3-زÔÕy7¢-1-ᵬ²-4ײÚÕ8¢-1,4-Òᵬ²ÛÕ2ஹ12

22,2Òᵬ²ᑁÕ2.ᵬ²ÖÕ(4)2,3•Òᵬ²ÖÕKÔÕ(5)(6)2,2-Òᵬ²ÖÕ3ஹফ>প>(3)>(5)>(4)4ஹ

36ஹ(1)

48ஹÖÕ%CH3cH2cH2cH2clCHCHCH(C1)CH323

51-áÖÕ(27%)2-áÖÕ(73%)1-á-2,3-Òᵬ²ÖÕ(54%)2-á-2,3-Òᵬ²ÖÕ(45%)ãᓄ*áᓄ᪀Nä஺1-ãÖÕ(1.8%)2-åÖÕ(98.2%)1-æ-2,3-Òᵬ²ÖÕ(0.4%)2-ç2,3-Òᵬ²ÖÕ(99.6%)10ஹ(1)BRCChèéØÕêU+ëBRCCLèéì⁐ØÕ!+஺(2)BRCCL,èé1,2-Òᵬ²ØÕ+ëBRCC14èéì⁐ÔÕ!+஺c1ஹrCH3CH3CH,2ஹ(I)(2)ctîLtîᓫî(3)ctîLtîᓫî(4)ᓫîctîðtî3ஹ

6H3cCHCH---CH23ᨵLñ4ஹ(1)õὅᨵcî5ὅºᨵQî஺(2)õὅᨵcî5ὅºᨵ
î஺5ஹclùcl6ஹ(1)1680-1620cm1,(2)2260-2100cm1,(3)1750-1690cm1,(4)2600~2200cm-1,(5)3600~3200cm-1ᔾᦈ⚣᳛ᨬḄ-O-Ho(2)(4)᜜ᔾᦈ⚣᳛!"஺7ஹ(1)ᵫ'ᐳ)*+,ᜧ./ὅ1᜜ᔾᦈ233஺(2)4ὅ1᜜ᔾᦈ233஺8ஹ6781ஹ(1)X᜜:;*ᡈᑁ:;*>ᨵᐝABឋ஺(2)X;ᐝDᔣF᪀HR/SLM>ᨵNOᐵ+஺(3)X(4)X(5)X(6)X2ஹ(Q3(:H(UH(33Ri--J--------—ScD1TLJrR11SBlHSBlHU3CC--------S11111RCII311K33S111(UH2Br(2H2Br(M2Br(UH2Br3ஹ(1)2஺(2)4(3)2஺(4)0஺(5)4஺(6)4஺IFHWXឋḄ஺IIIFWXឋḄ.Z[\᧜*஺5ஹ(2)(4)(5)ᨵᐝABឋ஺6,(1)R(2)R(3)S(4)R(5)R(6)S

7CH=CH2COCH3CH(CH)32CH=CHCH3OCH3(6)CH3(7)NO2(3)BrCHCH33H-------------ClHOHHOHCHCOOHCN3(4)(5)CH3ClNHCl2HOOC-----------HBrHCH39ஹQᱥ

8CH2cH31CH(CH)32H3c_ᧇ[RH.Qᱥ[SH஺6g81ஹa2bch2bcbc-A=^a3bch-3-bc2-ᵬefc3-ᵬefc4-ᵬefc2-ᵬe-2-fch-3-ᵬe-2-fca-3-ᵬe-2-fc

9a4-ᵬeT2-fchT4-ᵬe-2-fcH3S,3-iᵬejc2,3-iᵬe-2-jc2,3•iᵬejc2ஹV/S-h4ᵬe-1,3-fics-a4ᵬe1,3,-fics-h-(3E)-2-ᵬe-1,3-fics-h-(3Z)2ᵬe-1,3-fics-h-(3E)-3-ᵬe-1,3-fics-h-(3Z)-3-ᵬe-1,3-ficVs-a-(3E)-2-ᵬe-1,3-fics-a-(3Z)-2-ᵬe-1,3-fic

10S-a-(3E)3ᵬe1,3ficS.a(3Z)3-ᵬe1,3■fic3ஹ(3E,6E)-3,7,11-nᵬe-1,3,6,10-ᓝip7c4ஹ(1)(2)CH3coeH3+CH3CHO(3)(4)(5)CHCHCHBr(6)322OHOH(8)(9)CH3cH2coeH3CH3I-HC——C——C%—CH20H3CH35ஹ(1)/ὅᜧ'4ὅ஺q[/ὅrstuᨵḄᵬeᦪ4ὅw.஺-“ᐳyz{|.}~ឋ|ᜧ஺(24ὅᜧ'/ὅ஺ᳮᵫ᝞(1)»(34ὅᜧ'/ὅ஺/ὅe\Ḅᜧ.}~ឋ஺6ஹ(1)ᐜᑖᵨBr2/CC14.⁐Ḅ;ᵨ⏚.Q⁐Ḅ.T

112ᵨ¡¢£¤¢h¥.¦§¨h¥Ḅ,Tᓽ7ஹ(1)H3CCH3CH3H3cCC-----CHBr2(2)H3cH2c—H3cHe^CH—CH—CHBr22C6H5CHBrCHBrCH^CH2C6H5CH^CHCHBrCH2BrCHCHBrCH=CHCHBr652(2)

120+Ho

13KMnO—C=CH4COOH6«¬1ஹ(1)2,3,3-nᵬe4f(2)h-3-ᵬe-1-eᵬe²b(3)5-ᵬe-4-®¯e-2-°±(4)(3R)3°-3ᣳ-b(5)(3S)-3-°-²bc(6)2,3-i¸f(7)4-ᵬef-2-⏣(8)1,2-iᵬe-2-¯c-1-⏣(9)14ji⏣(10)h-3-ᵬe²b⏣(11)1-ᵬe²fc-3-⏣(12)µc¯c⏚(13)1,4-iᵬ´eµ¶(14)2-°ᵬe²´µH3c——CH——CH——CH3H3C-CH——CH—CH2—CH3(4)cH3——C2H5IHCCH—CHOH32(6)%_/¼CT\H20H

14HCOH3O——CH=CH2HCO3OCH33ஹ(1)(2)CHOHCONO92(3)(4)C=CHCN(5)(6)OCHIC2H524ஹ1জ¾ீঞ(2)ঝVঞvজ5ஹÄᑖÅÆ>ᨵ¦Ç´_ÅÈÉḄBÊË.ᡠÍ⏚ᑖÅLMΦÏÐËsZÈÉÑÒ⏣LMÓÍÔᡂËs஺6ஹ(1)(2)CH3(3)

15BfBr(4)(5)CN(7)CHCH3IIC2H5——C——C2H5(10)CHCHI327ஹ1ᵨAgNOJC2H5OH.>ᨵÖ×Ḅ3-2fc.ᐜßÖ⁐Ḅ4-¸-2-fc.Tᓽ5-¸2fc஺2ᵨᓲᓱ£ÚᑺÜÝ.ÞᓽßÖàáḄ2-ᵬe-2-j⏣,ᦪᑖâ4ßÖàáḄ3-ᵬe-2-j⏣.Tᓽ3-ᵬe-1-j⏣஺8ஹAUBUCUCHCH3CH3CH3H3C9ஹAUBU

16cH3——cH——3H3coHH3cc=CH——CH3cUH3CHNa二c1H3C————CH—CH+2H223oNacH.3çH2sO4H3c-----CH------CHa+H9OKMnO4HC-----CH------CHa3H3C-C-----CH-----CH3+HIO4---------►CH3coe%+CH3CHOH+HIO3+H20OHOHcHCH——33èH2so4HC-C------CH------CH33H20~10ஹAUH3CH3c——CH—CH—CH2OHcUDUBrBlOHH3C——CH-CH—CH2BrH3C——CH—CH=CH2

17EUFUOHHC——CH=CH—CHOHH3c——CH——CH—CH3223GUHC——CH,—CH,—CHOH32Br——OHïðKMnOtILriLS2--------------------*—CH—CHOH2BrBrBl————H3c——CH—CH=CH2——CH——CHBr2BrNaOHH3c—CH=CH—CHOH2H2OOHOHHIHC——CH—CH=CH----2-->H3c-----CH—CH—CH3223òᓄᑺH3c——CH=CH—CHOH-òᓄH3c——CHTCHTCHOH2222OHIH+.HCTCH—CH—CHḄᓄôH3c—CH=CH—CH+H3c—CH—CH=CH323322Hc-CH—CH—CHOH-^-^HC-CH—CH=CH3222322IIஹHC——CH—CHBr32CH312ஹõ3CH—O—CH/\HcCH33

186ö81ஹ(1)1-ᵬe-4-®¯e÷(2)3-°e÷(3)4-ᵬe-2-÷ø(4)1-ᵬe-3■•ᵬ´e÷(5)1-²b÷(6)6-°-2”ὶ÷(7)a-1,2-i÷eµc2ஹপ(3)

19HOCH(CH)323ஹ1,24nᵬ÷CH2cH2cH34ஹ(1)(3)(4)(5)ᐹᨵü✏ឋ஺5ஹ(c)Ḅ⏚ឋᨬþ஺q[(b)(c)ᨵᔾᵯḄ⏚ឋᡠ(b)(c)Ḅ⏚ឋ(a)஺(c)Ḅᙠ!"Ḅ!ᵯ₹$%&ᐳᵐ)*ᑖᦣᑮ./01Ḅ⏚ឋ஺6,(1)(2)

20OH7ஹ6᳛89ᑮᜧ;bᔜᱥA᪗Ca,b,c,d(1)cvbvavdDEFGᏝIJKḄLb,do(2)avc

21COOHOHBrBrBr(6)

22CHCH33(9)NO2(12)

23NO2——CH3CH3CH3

24Br2MNKM11O4晨剂K^Cr?஺?KaCr2஺?CH—2H2SO4Cl2HOOCCOOHFe13ஹ

25——CH3'HNMR2.4WXḄLᵬ.ḄAḄᓄ[\7.1WXḄL^.ḄAḄᓄ[\஺IR700cm"WXḄcde;Ar-H☢᜜Ḅklmn1500cn?WXḄLq^rsC=Cvwmn3000cm-1WX;Ar-Hvwmn஺yz{1ஹ(1)2,2-|ᵬ}~(2)5--7--1-(3)2,2-|ᵬ-3-~(4)3-ᵬ-5-(5)4-ᵬᵬ(6)3-^ᵬ(7)3-m-ᵬ}(8)4-(-ᵬ)ᵬ~(9)3-ᵬ^2~(10)2-ᵬ-1,4-ⅉ(11)(12)H3co4(13)H3c——C——CHO0.ICH3(15)(16)OH3cNOHCHO

26(17)(18)CH3CHO2ஹᑖ=Caஹbஹஹf,ឋ89ᑮᜧ;(1)f

27OHCH—C——C2H52CH3CH=CH-CH=CHCHO(8)(11)CH3COCOONH4+A4+H2O+3NH3OH

28(14)OHOHCH3CH3

29OH,0CH3CH3CH35ஹ(1)✌ᐜᑖ=ᵨᓲᓱᑺᓽLJKḄL¡⏣ᦪᑖ¤¥¦ḄL-2-⏣lh¥©ª«ḄL¬-2-~ᯠ¥ᵨ¯°EFG¯±JKḄLª«ḄL-2-~஺(2)COCH2cH3CH36,A²B²

30CHOHCH,O3I-II-IIHC——CH—CH—CHHC——CH—C------CH3333C²HH3HC——CH—C——CH33CH2cH2cH3oHoIKMnO4IIH3cCH—CH—CH3AH3c—CH—cCHOH-3cHocH33——OH-ncH-eCHCH3CH2CH2MgBrH3c¶cn¶cI------CH33-ICHCH,CH23cH-3HC-CH¶CHO38ஹA²B²HcHoH3O——3IIIHC—CH¶c—CH-CHHC—CH—CH——CH—CH323323c²D²cH——3OIIH3C-----C-----CH-----CH—CHH3c-----C-----CH233E²CH3cH2cHOcHo——3^CHNOH3=一CH—CH-H?NOHAH3c—CH—C——CH—CH2323cH3——OCH3OHII¶CH¶cH3c—CH—CH—CH—CH23CH3OHCH3CH—CH—CH,—CH3""SOஹH3c—C=CH—CH2cH3+H,O

31cH3o——^O3cH3C—C——CH—CH2cH3--------AH3cCH3+CH3cH2cHOZn/HO9OIIH3c----C-----CHb/Na()H»CHjCOONa+CHI33ACH3cH2cHOH+Ag(NH3)2OH---------►CH3CH2COONH4+Ag]+H2O+3NH3y¸{1,(1)2,4,4-¹ᵬ⏚(2)3-ᵬ-2-º»⏚(3)2-ºᵬ⏚(4)3--2-½}⏚(5)3-»¼⏚(6)2,5-|ᵬ|⏚(7)J-2-ᵬ-3-⏚(8)4-⏒ᵬ⏚2ஹ(1)CH3CH3cH2cH2cH2cHeHCOOHCH—CH3ICH3COOHcH——3CH3cH2cHecH2coOHO(5)

32CH3CH3cH2cH2cHeHCOOHBr¿6ÀH3cH2cH2cH2CஹHÀC=CÁHnÀC=CÁ/CH2cH2cH2cH2cH2cH2cH2coOHHÀC=C¿3ஹ¿1Àᵬ⏚ு^ᵬ⏚¿2Àᵬ⏚Å1ᵬ⏚ு1Æᵬ⏚,Æᵬ⏚¿3À}Ç⏚Å}⏚ு}⏚¿4À|⏚ு}|⏚Å»|⏚ு|⏚¿5Àᵬ⏚ுᵬ⏚Åᵬᵬ⏚4ஹ¿1ÀH3c——CH=CH—COONa(2)CH=CH—COOH+HO2

33(5)OMHHCCHHO(6)ClCNCOOHIIH3CCH—COOHAH3C——CH—COOHAHC—CH—COOH35ஹ(1)on(2)OOIIIIHC——C——CH—C——C2H53CH—COOCH225OIIHC——C——CH—CH—COOC2H5322(3)

34OHOH6ஹ(1)✌ᐜᵨFeCbÈ⁐JKḄLʺᵬ⏚²ËᵨBm/CCLEÌ⁐ḄL3-}⏚ͶζÎᓽ;»⏚஺(2)E¬NaHCO3JKÏGÐÑḄLᵬ⏚E¬FeCLFGÈ⁐JKḄLᵬEFG¯±JKḄLᵬͶÎᓽ;☩⏣஺7ஹA²OHH3c----CH—CH--COOH2B²C²0IIH3c——CH=CH——COOHHC——C-------CH338ஹ—CH=CH——CHOH0\_J9ஹA²/CHL-COOH/■H3c—CH-COOHB²0II¶\H3C—CH/OXCH-2-cIIo

35yᓝ{(1)3-ᵬᵬ⏒Æ(2)⏒ᵬ⏒Ö(3)2-ᵬ-2-»|⏚Õ(4)|ᵬ⏚ᵬ|×(5)o^cH2C=CH—CH2—CHc、zC1=o(7)cH.3HC2COOCH3HC²=CH——CH=C=NCH23(9)CH——3H3C——CH—CN(10)HC^CH—COOCH=CH222ஹ(1)CH3I8OH(2)CH3CH2CHO(3)

36COOC2H5COOC2H5(4)HCCOCHOH32(5)CH3COOCHCH+CH30H2CH33ஹ(1)(4)OIIHN—CH2cH2cH2cH2cH2——C——ONa2(5)

37NMgBrGH50HcH3——HC——CH—COOH3

38yᓝ¶{1ஹ(1)»-2-Ö(2)N-ᵬ}-2--1-Ö(3)N,N-|ᵬ^Ö(4)|^Ö(5)Úᓄ¹ᵬ╄(¹ᵬÚᓄ╆)(6)N-ᵬ-N-Ý}-3-Ö(7)4-ᵬ-4'-|ᵬ°Ꮤß2ஹ(1)(2)(CHCH)NCHCHCHCHNH(CH(CH))3233222324CH3——NHCH33ஹᑖ=àáᢥCabcdef••••æឋᵫèᑮḄé;(1)c

39CH3N(CH3)3+CH3cH2cH=CH——CH—CH+HO32(3)BrNH2NH2

40CH3CH3NH(CH)3=^=CHCH—CHCH23cH—.———c—N(CH)32CH3(3)A²B²

41N஺2NH2rᔆCWCLJITᔆᔆC'cncCH3H3cCH?஺Lx2HC3CH3c²N(CH)6H33N-H一2-LH.C-CH2ccH3CH.NH2+———N(CH)OH33cHTccH31HC—CH——332AH3c—CH-------C---------CH23CH,N(CH)6H33CH3c-------CH3N(CH3)3+H3c-----CH2—C-----CH2+ICH3yᓝ|{OHOH(2)

42HBR2HOCH3cH2cCH»=22cc------------>CH3cH2cH2cHOCH3cH2/HOH-(3)/ícCH3ONa(HC)C——Cl-------►(HC)C—OCH33333CHONaOHCHOCHO(5)(6)oOIIH+IICH3cH2COOC2H5CH3cH2CCCHOOC2H5------►CHCHCCCHOOHHO+323OHHI2CH3cH2cHeHCOOHCH3(7)HC3H3cHC3)——COOH¶î2B12CONH2NaOHNHH3cH2cï2H3cH2cgH3cH2c511(8)

43CH3COOHCONH2NHNO22NO”…2஺2ù,JHBFjFeCljf[H.NH2(9)/OH2NOH>A\H.)—NOH_H__,ஹNHᔆoòó-------(10)\NO02ANO25NH2i„A/FeCl3'þ.NaNO2Br\HBrCuBr|•/H,O,100࠷*HBr

442ஹপ--CHOH2(2)CH2cH20HCBr(CH)H323c——c——CH3(3)c^=c/\(4)Ikc,-¶(kOHCHCH33(5)

45OHCHOH2(6)CH3cH2coeBnACH3cH2coONa+CHBr3OHOH(10)

46OHyᓝ¹{1ஹ(1)1-ᵬ-2⏒(2)4--2-ÿᔬᗏ(3)2,5-ᵬ!ᔵ(4)4-ᵬ(5)4-ᵬ#$%(6)4-ᵬ⏒(7)4-ᵬ'-2-ᗌ(8)4-(9)2-ᵬ-5-*#+ᕡ(10)6-()HCOOH(3)(4)(6)

47NNH9NH23ஹᑖ./0abcde•••7ឋᵫ:ᑮᜧ᣸ᑡ?@1Aa

48(£)HHHOCH3(Z)

49OH°H4ஹ@1ArᓄMHḄ'bTrᓄMHḄ|®஺r¯°±⁐Ḅkℍ⃔MbTr±⁐ḄkµM஺@2Aℍ⃔MkWMbⅅMk[WM஺⌱ᵨtuvᑺஹ}᪍vᑺᡈxyzᱯvᑺrᓄWMbTrᓄ[WM஺@3A¹ºr¯Ớ¼©½bcⅅMTr஺5ஹA¿@2HO(HOIT11OHHUriᡈITnOHHUH(2HOH(H20H2Bc¿H0(rHOUCR______IJ11HUHᡈ1IJ1-------------------OOHilHOHCH20HCHOH26ஹ(1)

50OCH(CH)32aᡈBCH=NNHC6H5C=NNHC6H5H-------OHH-------OHCHOH2ঞCOOHH-------OHH-------OHH-------OHCOOHট

51COOHAঠCHOH2OHOHIIcuHOriCHOH27ஹ(¿H0(H20H(:HOH2riOHHOHHCHOriHUHHOHH2HUH---------------►HOHNIHOHu-HOririOHHOHucHU11(H20H(H20H(H20HD-1À⃔MD-l.⃔M⏣L-ÃÄ.M⏣(¿HO,¿H20H(:H2OH(¿=0uHUHmurllJriscH,H°ti12H------------A+H——OHᵨuUH#UlinOn.THUHOH(¿HOH(2:H20H(:H2OHD-µMD-ℍR⃔M⏣D-ᵞ£⅟M⏣

52CᓝÇF1ஹ@1AÈᙠÊ⏚a-VWGḄ⏚N?a-⏚஺@2AᵫÌ⏚ᑖGᐹᨵ|ÎbÏÐÑÒᡂᑁÔbÕÖN?×ឋØGᡈᏔ᩽ØG஺@3Aᙠ⏚Û¼HbÜ⁚Û¼pH,Ïà¯⏚áØḄ□ØG|▢ØGḄähbÛ¼HḄ☟ᵯ₹?èbᙠᵯéH⏚êTᔣm᩽ëìbíTᔣî᩽ëìbïkÛ¼ḄpHðkñ⏚Ḅᵯò஺@4Aᨵ10⏚Trsóᙠ^ᑁÐÑᔠᡂbᡈὅõrᔠᡂböTr÷ømùḄ◤⌕,cüýþTZḄÿᱥ
᤬᝞⏚ᑣᡠ◤⏚஺5!"a-⏚Ḅ᪀()ᵨ+,᪀(D/L⊤1᪀ᡂ345Ḅ6ឋ345⏚Ḅ᪀(89L᪀(஺6;<9=>⏒@<ᓽ-CONH-,ᐹᨵI☢K᪀ḄᱯM஺7ᙠP;ᑖR
SḄ=TN-USᨵVḄ=UC-U஺8Uᑖ᪆YZ[P;ḄᑖRPᜧ]8ᨵN-U^C-U᝞⌱`=a〉cḄdᑺfghP;ḄN-UᡈC-U⏚jkᯠmn;

53HOCOCH2cH2—CH—COO------------------►HOCOCH2cH2—CH—COOHCrNH3NH21NaOHHOCOCH2cH2—CH—COO-----------------►HOCOCH2cH2—CH——COONa3ஹ(1)O02——CHCHO+co.2(2)C2H51CH3cH2coNHCHCOOH(3)CH3{)—CHOCONHCHCOOH2(4)NHCOCH3CH3CONHCH2CH2CH2CH2CHCOOH(5)CH3ON------(ு-NHCHCOOH2NO24ஹ

54ᵞ⏚Gly----------a|⏚Ala---------►ᵞ⏚Gly௃}|⏚Phe--------------------------------------------~⏚Va1ᵞ⏚Glyv------------|⏚Alay----------ᵞ⏚Gly}|⏚Phe___________________________»~⏚Va15ஹ⏚-⏚-⏚-ᵞ⏚-}|⏚-⏚-⏚-}|⏚-⏚Arg-Pro-Pro-Gly-Phe-Ser-Pro-Phe-Argᓝ1,(1)(3)

55o