天然药化习题

天然药化习题

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时间:2023-07-14

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30D.ᢙrs᪵kᵨE.╋vkᵨB@⚪[11-20][11-15]A.Bᓫ✏B.ᔬᗏ✏C.ᗏ✏D.x✏E.ᐸH✏11.45ᑁy12.z{|y13.x⊡fᾦy14.a}ᑁy15.~ᬀᑁy[16-20]A.xᨴ⏚UVB.Gibb'sᑺUVC.MolishᑺUVD.⛳Ḅ⏣ᡈx⏣E.ᵬG-ᵬ⏚-ᵬ⏚54116.ᑁ?ᓄᔠᱥḄ␺ᵨ17.Bᓫ✏?Ḅ⁐␺ᑺ]ᵨ18.ᵞᡈ?Ḅᓄ␺]ᵨ19.ấↈ⁐␺Bᓫ✏?ᡂᑖ]ᵨḄᑺA20.ᵨ✏C6ᨵ¡3¢ḄUVC@⚪[21-30][21-25]A.9ᕡ;B.7ᩎC.ὅᙳD.ὅᙳL21.¥ᨵ✏ᡂᑖ22.¥ᨵᩈᾦ?ᡂᑖ23.ᡠ¥ᡂᑖ#᪀§᪶AὶGᩈᾦ24.ᡠ¥ᡂᑖ#᪀§᪶ABᓫᩈᾦ25.ᡠ¥ᡂᑖᐹᨵ©ª«¬⏦Ḅkᵨ[26-30]A.BᓫᩈᾦB.ᩈᾦᑁC.ὅᙳᨵD.ὅᙳ¡26.x®⏚UVᕈ`⁐

3127.¯ឋᩩ±)²³sUV28.<´;ᵞy29.µ¶✌y30.45᧖yX@⚪[31-42]31.)ᑡ¥✏?ᡂᑖḄ%dA.¸PB.ᵞ₝C.⊡fᾦD.9ᕡ;E.{º32.Bᓫ✏Ḅ3¢»¼A.7ᜧ¾ᨵ¥¿&ᙠB.5ஹ6ஹ8ᨵ¥¿&ᙠC.]ÁḄ3¢¿ᨵஹᵬஹxRÂD.xR]µᙠ6ஹ8E.xR]µᙠ5ஹ733.Äᑖ;✏ᐹᨵḄឋÅᒹNA.ᨵ✏ᕡB.ᨵᢵ³ឋC.ÇᓣÉD.ÇÊE.ÇË34.23✏ḄÌ1ᨵA.⏚¯Í1B.¯⏚Í1C.Î231D.231E.⏣23135.ᵨ⁐Ì1ᑖ✏Ïᔠᱥ]⌱ᵨḄᔾ▬ᑺᨵA.ấB.⏚ឋᓄÓC.¯ឋᓄÓD.%ឋᓄÓE.ឋÔ36.✏?ᡂᑖḄ₯ᐝÖ#᪀ḄᐵØA.✏§K¡₯ᐝB.✏Ù^⁐₯ᐝC.ᙠ¯%₯ᐝÚÛD.73¢₯ᐝÜÝE.ᔬᗏ✏₯ᐝÞÛ37.EmersonUVᕈ□ឋḄᓄᔠᱥA.GB.ß᪺P⏚C.ß᪺P⏣D.8-✏E.6,7-✏38.à6,7-ᔬᗏ✏7,8-ᔬᗏ✏[áHâᑖ²¯n®ãᵨA.x®⏚UVB.Gibb'sUVC.EmersonUV

32D.åæᓄUVE.çè-éê⏚UV39.¥ᩈᾦ?ᡂᑖḄ%dᨵA.9ᕡ;B.<;C.µ¶D.7ᩎE.⊡fᾦ40.IᡂᩈᾦḄᓫKᨵA.᪺PÎB.᪺P⏚C.᪺P⏣D.SRGE.RSG41.%d¸PëᶭíîḄᨵᦔᡂᑖA.45᧖B.45ᑁC.{∑D.{∑᪛ᵞE.7-✏42.EmersonUVA▢ឋḄᓄᔠᱥᨵA.7,8-✏B.8-ᵬ-6,7-ᔬᗏ✏C.5,6,7-å✏D.6-ᵬ✏E.45᧖(-)ôõnö[1-3]1.✏2.ᩈᾦ3.¯⏚Í1(å)÷ø⚪[1-10]1.✏ù?ᐹᨵ§᪶Ḅᓄᔠᱥ஺HâḄûfüo2.✏û#᪀%ý]ᨵஹஹஹÂ3¢,᪷Ḅ✏ᑖஹஹஹஹ஺3.ᩈᾦᵫ204ᓫᐗᡂḄᜩᯠ$ᱥ஺᪷ᐸ()*+,ᔠᑖஹஹஹஹ./஺4.ᜩᯠ01✏ᜧ3ᨵ5ᕡ7ᑖ801✏ᐹᨵឋឋ;<=>஺01✏ᓄᔠᱥ@,ᵬ⏣ஹC⏣ஹDEஹCFஹGᨵHIᑺKL஺5.✏ᵞ✏ᕡᢵPឋQᓣS஺Lஹᵬ⏣ஹC⏣DEஹCFஹG᩽UឋV7ḄᨵHIᑺ஺6.ᩈᾦᑖ8W᪀YZ[ᨵஹஹஹஹ

33\]ᑖ^ᕈᔜa;bᡠᐹᨵḄᓄdឋe஺7.ᩈᾦ3ᦪᕈ01/gᦪᡂh஺ᙠjᱥkᑁZmᜧnᐳp⍗ᡈ᧕t᪀ᓄᡈW᪀u᣸wᙠIᑺᜐᳮz{Y|᧕,~ᑖ1ᩈᾦḄᙠᱯ^஺8.01✏+ᐸ᧖ᑖ8YᐹᨵW᪀ᙠYLᡂ᧕IḄ,ᔠᡂIḄ᪆஺]ᐹᨵឋ஺ᵨ✏+ᐸᑁᓄᔠᱥḄ␺^ᑖ1஺9.Emersonᑺ✏᪵IYᐭ2%Ḅ8%ḄᑺmḄᡂ________⁐________஺]ᵨ¢£✏ᡈC6ᨵ¤஺10.¥I⏚§✏ᡂᑖ¨©ᡠ¥ªḄஹ,«Ḅஹ,¬ẚ¯ᑁ஺°±²³´⚪[1-5]L¶·ᵨ¥I⏚§ᑖ1✏ᡂᑖ¸ᑖ᪆¹ºᑖ1¶·³⚪¸2.᝞¼ᵨᓄd½§␺^6,7-¿✏7--8-ᵬÀ✏¸3.YÁ⊡ÃᾦYᢙÅ᷆ÇḄÈ⌕ᨵᦔᡂᑖ¶·ᑏᐸW᪀Ìᑖ᪆ᨵÍÎឋe¸4.ᑏtᨴÐ⏚ÑḄÌ஺5.YÁÒÓYᢙÔᨵᦔᡂᑖ¶·¸᪷ឋeÕÖᑖ1×{ᑖ᪆×{஺

34ᓄᔠᱥ(-)⌱Û⚪[1-90]A/⚪[1-30]1.ÜÝMg(Ac)2ᕈÞßÞà⁐ḄA.1,8-¿᠄⏨B.1,4-¿ã:ÜC.1,2-¿᠄ÜD.1,4,8-åæ:⏨E.1,5-¿æ:ç2.YÁèéYêᶭìíîḄÜᡂᑖïA.GÜB.ⅉÜC.ñÜD.℗ÜE.¿℗F3.óôᑡö÷:ÜḄCFIªYᵨøḄ5%Na2cChLIª⃓¥LúḄᡂᑖD.E.4.;m¥ªP,ᡂû⁐ᓄᔠᱥḄA.üB.:⏚c.:D.¿÷:üE.:5.ýþÿAA.ᜧ℗⏨ᱥB.₝:ᱥC.ᱥD.:ᱥE.:ᱥ6.ᑡ᠄ᱥ⏚ឋᨬ!Ḅ#

35A.B.C.A.%&'()B.*⁐,ᵬ./0C.1ឋ2ᵬ()D.3⏚╅()E.5,6ᵬ78()8.ᙠ᠄⏨Ḅ:᜜ᐝ=>?ᨵ1ABCḄᓄᔠᱥ#A.ᜧB.ᜧC.ᜧᵬD.₝E.₝9.ᑡ᠄⏚ᵨấHↈJ⁐=ᑖ?ᵨ7-3⏚MN3O1PQR?RfSᜧTUVWA.জঞ>@>ঠB.ঠঞটC.ঠ\>জ?ঝுটD.টঝுঞுজுঠE.ঝ`জ>ঠ>জ>ঞ10.ᙠᜧa℗Ḅbcd>?e⌕ᑖᜧ⏚ஹᜧஹᜧஹhiᜧஹᜧᵬ?jᵨklᑖmnᨬoA.pHpq⃓cnB.sᓄtu⁐=nC.ᑖvwᨔnD.yz⏚{nE.pHpq⃓cn|ấHu⁐=wᔠn11.}℗Ḅ~᜜ᐝ=ᧇWO

36UVAxnm(loge)O225(4.37),279(4.01),432(4.08)111aᓄᔠᱥ#A.1,2-᠄B.1,3-᠄C.1,8-᠄D.2,5-᠄E.5,7-⏋12.1-OH℗⏨Ḅ:᜜ᐝ=>?CḄᱯ#A.1675cm-1ᜐᨵCB.16751647cm16371621cmᨵAᔾᦈC?C2438cm"C.1678~1661cn?16261616cmᨵAᔾᦈC?C4057cm-D.ᙠ1675cm”1625cm”ᜐᨵAᔾᦈC,C60cm”E.ᙠ1580cmᜐWAᔾᦈC13.ᑡᓄᔠᱥᵨᨬḄ#A.ᜧB.ᜧℍ⃔C.¢£AD.ᜧᵞE.ᜧ⏚ℍ⃔ᵞ14.ᑡ℗ᨵᓣ¥ឋḄ#A.ᜧℍ⃔ᵞB.ᜧC.¢᧖AD.ᜧᵞE.hi✌15.¨©ª«HA|ᜧḄmn#A.¬sᓄzdB.®⏚¬zdC.3⏚╅ᵬ⏣dD.°±⏚E.z²³⏚´M816.bcᜧ>aµᡂᑖ·ᵨḄzᑺ#A.¹B.M⏣C.MD.²³⏚E.3⏚MN17.z®⏚¹zdḄ#A.ª«IB.ª«HAC.ª«ª«BD.ª«ºᵬE.◚ª«18.ᜧᡠ½ḄUV¾ᕈÀ.~⁐₯ᐝḄᱥÂ#A.ᜧ⏚ᵞB.hi᧖C.ÃᜧÄD.¢ᵞE.ᜧ19.jᵨu⁐=ᑖ᠄ᡂᑖ?·Å⌱ᵨḄᔾ▬ᑺ#A.ấHB.sᓄtC.È⏒8D.Ê⏚¬┛E.ℍÈÌH20.ᙠ:ÍᱥUVᐝ=>?Î262295nmᔾᦈCḄlog£ᜧ4.1Ï?ÐᡂᑖWA.ᜧB.ᜧC.¢᧖

37D.ᜧᵬE.hi᧖21.ᜧ᠄Ñ᪶ÓḄᑖÔÕÖ#A.A7×ḄB-ØB.7×ḄB-ØC.ᙠA7×ḄaᡈBØD.•A7×ḄaᡈBØE.ᙠ×Ó22.}ᡂᑖÛÜ⁐()?wÝWOzNa2cChzdÜ:⁐.|3⏚╅()Ü.~⁐.|a-ₐ-°±⏚()Åà~⁐×?ᙠNaHCCh>Åzá஺ãᡂᑖW23.ᑡᐵⅯ⏨᪶æᐳèén>êëḄ#A.*cìḄ᠄íÑ᪶ÓᨵAî¬B.6-î¬>ïᙠ8.07ppmC.a-Ḅ6SðW11012PpmD.a-î¬>ïᙠ6.67ppmE.cì>ñòî¬óóàôõC24.ᑖ:|℗᧖?⌱ᵨᑡmnA.AI2O3u⁐=nB.ö÷ᣚ⁐=nC.¹|ù⃓cD.¹|M⃓cE.ù|M⃓c25.ᑡénÅêëḄ#A.úôᨵ⏚ឋB.᠄ᨵyឋC.᠄⏦ôᦪz5%NaOHD.ú:ýz5%3⏚E.᠄Ä•ýᐹᨵ¹áឋ26.᠄#℗ḄA.ÿᐝ᪀B.ᑖ᪀C.᪀

38D.᪀D.ᱥ27.:᪶Ḅ᪶ᐳᱯA.ᔠ"#$%&B.Ꮤ(ᓫ$*#+&ᜧC.Ꮤ(ᓫ-ᑖ./01D.Ꮤ(ᓫ-ᑖ./21E.ᔠ"#$328.1,8-056᠄Ḅ8᜜ᐝ:ᦪ<.A.4180440nmB.4300450nmC.470~500nmD.4000420nmE.500nm=>29.@AB⏚DEF⁐ḄA.HIHAB.HIHBC.HIID.HIJᵬE.◚HI30.MNOPQR60ᵬ6STDḄA.56U:B.56V:WC.ᜧmJZD.X₝JZE.0:\]BZ⚪[31-60][31-35]A.8₝JB.HI^C.ᜧmJD._`ᵞE.jkᵞ31.bc᠄Ḅ32.bcdeḄ33.bc0fWḄ34.bcghḄ35.bciḄ[36-40]A.lmnl⁐B.lono⁐C.8on8⁐D.FnF8⁐E.pqnr⁐36.1,8-0OH℗e@t⏚╅vᔠ(ᕈ37.1,2-0OH᠄@t⏚╅vᔠ(ᕈ38.1,3-0OH℗@t⏚╅vᔠ(ᕈ39.1,4-0OH℗e@t⏚╅vᔠ(ᕈ

3940.1-0H℗@t⏚╅vᔠ(ᕈ[41-45]A.230nmB.2400260nmC.2620295nmD.3050389nmE.400nm=>41.56fḄUVᐝ:,ᔾᦈz{@56ᦪ|ᨵᐵ#@56ᐵḄ42.56᠄ḄUVᐝ:,ᔾᦈz{@56ᦪ|ᨵᐵ#ᔾᦈ⌕ca-OHᦪ|Ḅ43.56᠄ḄUVᐝ:,ᔾᦈz{ᙳ@B-OHᨵᐵḄ44.56᠄⏘ḄUVᐝ:,ᔾᦈz{ᙳ@a-OHᨵᐵḄ45.56᠄ḄUVᐝ:,ᔾᦈMᵨcᑨB-OHᙠ@ᔲḄ[46-50]A.ᜧmJB.QJC.8₝JD.0fW᧖E.HI⏋I46.@Do⁐Ḅ47.@⁐QᵬFᵨ#⁐:Ḅ⁐h>F⁐ᦿ¡Ḅ48.@AB⏚DEF⁐Ḅ49.@Molish¢ᑺD¤O8⁐¥Ḅ50.@PQR60ᵬ6ST¢ᑺD¤Oq⁐Ḅ[51-55]AஹR1=-CH3R2=HBஹR1=-COOHR2=HCஹR1=-CH2OHR=H2DஹR-CHR=-OH1=32EஹR-CH1=3R2=~OCH351.ᜧm¦Ḅ§᪀52.ᜧmJḄ§᪀53.ᜧm⏚Ḅ§᪀54.jkᜧmJḄ§᪀55.ᜧmJᵬ¨Ḅ§᪀[56-60]A.DB.t⏚╅DC.⁐QᵬF¢©D.a-ⅉ¦-AB⏚¢©E.AB⏚D56.«¬ᜧmJ@ᜧmJℍ⃔¯h°⌱ᵨ

4057.«¬1,8-056f@1,8-056fW°⌱ᵨ58.«¬5,8-056᠄@5,6-056U:°⌱ᵨ59.«¬HIJ@HI⏨°⌱ᵨ60.«¬56᠄⏋@56ⅉ°⌱ᵨCZ⚪[61-80][61-65]A.1,8-0OHjgB.1,2,8-³OH᠄C.0ὅᙳD.0ὅᙳ*61.@Dᕈ□ឋḄ62.@t⏚╅DᕈF8⁐Ḅ63.Mcg⏚·Ḅ64.@t⏚╅Dᕈlno⁐Ḅ65.Mcg⏚·Ḅ[66-70]A.IRᐝ:>2/¸6B.IRᐝ:>1/¹6C.0ὅᙳMD.0ὅᙳ*M66.1-0Hf67.1,8-0OH68.1,4-00H69.1,4,5-³0H70.1,4,5,8-º0H[71-75]A.ᜧm⏚B._`ᵞAC.0ὅᙳᨵD.0ὅᙳ71.cg⏚·72.@Do⁐73.MNOMolishD74.»ᜧm75.ᐹᨵ`½ᵨ[76-80]A.1,3-56᠄B.1,3-56᠄WC.0ὅᙳᨵD.0ὅᙳ

4176.ᨵ⏚ឋḄ77.@³¾ᓄÀ¢ᑺᨵÁDḄ78.ÂÃÄᱥᨵ#ÅÆ(Ç*Ḅ79.ឋ½M@ÈឋÉᵬ6¢ᑺNODEFq⁐ᡈF8⁐Ḅ80.*@PQR60ᵬ6STDḄXZ⚪81-9081.ᐹᨵP§᪀ḄᓄᔠᱥA.8₝JB.8₝JC.HIIIAD.ᜧm⏚E.jk᧖82.ᙠ½ᑡÌÍÄᱥÎV:]ᓄᔠᱥÏ2ḄÐᨵA.ÑÐB.X₝ÐC.ÒÓÐD.ÔÐE.ᖃ$Ð83.½ᑡᓄᔠᱥ⍗Em⁐#×Øᓄ(ÙEo⁐ḄA.56U]B.᠄¦C.ⅯWD.0V:WE.56℗¨᧖84.56Û:⏨UVᐝ:ᨵSᵬ⏒6§᪀ÝÞḄᔾᦈ:ß.A.230nmB.240~260nmC.2620295nmD.305~389nmE.400nm=>85.àá℗᪶â:ᱯA,ᑖãáã2.6B.ᨵM-CO+C.ᨵM-2coåD.æᵯ₹áãE.éêᑖãáã86.½ᑡbcᜧmJ-8-B-D-ℍ⃔¯ᵞឋâḄᨵA.@t⏚╅Dᕈ8o⁐B.@Molish¢ᑺᨵ□ឋDC.UVᐝ:ᨵ295nm(loge>4.1)D.IRᨵ2/-C=O#⚣᳛íîᙠ24028cm"ðE.Mc5%ḄNa2cCh87.ᑖá56℗ñḄòᵨᔾ▬ᑺ.A.ấõB.ö⏒TC.Øᓄ÷D.ÈឋgE.ℍö¯øõ88.«¬ᜧm¦@ᜧmJḄùúA.t⏚╅DB.IRᐝ:C.UVᐝ:D.'HNMR:E.iûüD

4289.½ᑡýᔠHIHAḄþúᨵA.ᨵÿḄᵨB.C.D.⏚╅⁐E.ᨵḄ᡽ᾭᵨ90.ᙠ#⏚$%&'(ḄᡂᑖᨵA.+,AB.ᜧ.⏚C.ᜧ./D.ᜧ.0E.ᜧ./ᵬ234567(89-5]1.;<ᓄᔠᱥ2.᠄A<ᓄᔠᱥ3.a-BCD;4.pHEF⃓HI5.4DJ<3K5LM⚪[1-12]1.A<ᓄᔠᱥO⌕ᒹRஹஹஹTU

4312.]᠚;᪀&BCḄᦪ¨n¿Àij]⏚╅ḄÁÂij]xÃᐹᨵ᪀]ÅÆÇÆ^⁐µᐹᨵ᪀]ÅÇ^⁐µḄ᪀]ÅÈÇ⁐஺3T5ÉÊ⚪9-8]1.A<ᓄᔠᱥᑖËÌU

44ABCDEᓄᔠᱥ(-)⌱I⚪[1-149]AK⚪[1-45]1.DEᓄᔠᱥḄMNOPA.QRSTUVWXYZḄEᓄᔠᱥB.Y-[ᗏDC.2-S]⁐^DD.2-S]S_a-[ᗏDE.2-S]S_YT`ᗏD2.⁐^DTC2ஹC3aᓫbBTZcᙠC2eḄDEᓄᔠᱥfA.D⏣B.hDC.iὡDD.kDE.l⏣3.mhDḄnfA.ᖃpnB.qnC.rnD.spnE.t✏n4.vwxymᨵḄᱯ5ᡂᑖEKA.D⏣B.kDC.hDD.iὡDE.9D5.DEᓄᔠᱥᜧ:ᕈ⁐Ḅᨬ/⌕^~fA.ᐹ)]B.ᐹᐳC.ᐹ]D.ᐹSTE.K6.kD⏣EᓄᔠᱥḄ⁐:fA.⁐B.⁐C.⁐D.⁐E.⁐7.kDஹkD⏣Eᵞᐗᙠyᜧf~A.]:B.ᨵ]C.KD.CT☢KE.CT☢K8.ᙠyᜧḄfA.B.ᵞ₝

45C.ᩈᱰ₝D.ᜧrE.9.ḄfA.᭒B.ᩰ᫥C.¤¥D.ᩈᱰ₝E.10.Dᵞ¦D§ᐗ¨ᙳḄᑺA.«¬B.C.«⏣D.E.⏚11.ᑡDE⏚ឋᨬ°ḄfA.7-OHDB.4'-OHDC.34'-kOHDD.7,4'-kOHDE.6,8-kOHD12.ᑡDEᓄᔠᱥ⏚ឋᨬ±ḄfA.᭒B.C.ᩰ᫥D.ᩈᱰ₝E.²13.␺´DEᓄᔠᱥᨬµᵨḄ·⁐%&fA.¸¹%&B.Wᓄº%&C.Wᓄ»%&D.¼⏚-╅½%&E.k┯%&14."¼⏚-╅½<ᑺᕈ¿%&ḄfA.ᵞ₝B.C.ᜧrD.ᩈᱰ₝E.᭒15."Àk)]%&Ḅ<ᑺfA.WᓄºB.k┯C.yឋ#⏚ÁD.Â#⏚ÁE.Ãឋᓄ╃16.k┯-ÅÆ⏚%&yᐜ·⁐ÈᐭÅÊ⏚Ë⁐·℉Í⌨ḄfA.5-OHDB.D⏣C.7-OHDD.4'-OHD⏣E.7,4Z-kOHD17.¸¹%&ᵨ␺´A.DஹD⏣B.hD

46C.iὡDD.kDஹkD⏣E.Ð⁐18.DᵞEᓄᔠᱥÑᵨḄÒÓÔÕfA.⏚ÒÂÖB.ÂÒ⏚ÖC.×ÒÓD.«ᘊÒÓE.ᵬ⏣ÒÓ19.ᵨÂ⏚ÖÕÚÐஹÛÜEÝᩞyÒÓDEᓄᔠᱥÂß⌱ᵨA.5%NaHCOB.5%NaCO323C.5%NaOHD.10%NaOHE.⛳¦áᮞ20.ᐹÀe)]DᵨÂÒÓãäåÀe)]ḄÔÕfA.ȸ¹æ^B.È#⏚ÁÖçC.ȹ⏚èᔠD.È«⏚⃓ÓE.Èᓄºᔾ▬21.Ú²yÒÓ²ᵞ:ÑᵨḄÒÓÔÕfA.ìí⏚ÖçB.îï⏚ÖçC.ᵬ⏣ÒÓ⏚ÖçD.«⏣ÒÓ⏚ÖçE.ðDÒÓ⏚Öç22.pHñ⃓ÓÕᑖᑡDᵞᐗᵨ5%NaHCC>3ஹ5%Na2cO3ஹ1%NaOHòó⃓ÓᐜË⃓ÓôᓄᔠᱥḄõöA.ঝfজঞB.ঞজfঝC.জঞঝD.জfঝfঞE.ঞfঝfজ23.pHñ⃓ÓÕᑖDᵞᐗEÈÂ⃓ÓḄõö&fA.NaHCO-NaOH-NaCO32B.NaHCO^NaCO-NaOH323C.NaOH-NaHCC^fNa2co3

47D.NaOHfNa2cCh—NaHCChE.Na2cO3-NaHCC^fNaOH24.û⁐2ᑖᐹ3-OHᡈ5-OHᡈÀk)]ḄDEᓄᔠᱥßᵨḄýᐙᑺfA.ÿឋB.ấC.⏒D.ᓄE.25.ấ⁐ᑖᑡᓄᔠᱥᨬᐜ⁐Ḅ!A."᜼B.$%C.&'D.ᩰ᫥E.*+26.⏒⁐ᑖᑡᓄᔠᱥ,⏣.ᵫ0ᑮ23456ῃᨬᐜ⁐Ḅ!A."᜼B.᭒%C.&'D.ᩰ᫥E.*+27.⏒⁐ᑖᑡᓄᔠᱥ,⏣.ᵫ0ᑮ23456ῃᨬ9⁐Ḅ!A.ill᜼B.᭒%C.&'D.ᩰ᫥E.*+28.ấᔾ▬TLC,,<-ᵬ⏚ᵬ@-ᵬ⏚5A4A1BCDᑺᑡᓄᔠᱥ&GᨬᜧḄ!A."᜼B.$%C."᜼-3-0-ℍ⃔KLD."᜼-3-0-M✏KᵞE."᜼-3-0-PQKR29.⏒ↈTTLC,,ᵬ⏣-U1A1BCDᑺᑡᓄᔠᱥVGᨬᜧḄ!A."᜼B."᜼-3-0-PQKᵞC."᜼-3-0-ℍ⃔KLD."᜼-3-0-M✏KᵞE.$%30.ᑡᓄᔠᱥXYZ⁐,BAW[\Ḅ]TBCDᑺRfGᨬᜧḄ!A."᜼B."᜼-3-0-PQKC."᜼-3-0-ℍ⃔K᧖D."᜼-3-0-M✏KᵞE.$%31.ᑡᓄᔠᱥḄZ⁐,2%_5%`⏚UBCDᑺaGᜧbcdB

48A.জঞB.ঞজC.জঞுঝD.ঞ>©>ঝE.ঝXAঞ32.ijkᓄᔠᱥḄl᜜ᐝ,ᐸqIrs325nm,tᓄᔠᱥuv!A.᭒%B.*+C."᜼D.ᩰ᫥E.5,7-wxy⏣33.ijᑡᓄᔠᱥḄl᜜ᐝᐸqIBz{Ḅuv!A.ᵞ₝B.$%C.*+D.ᩈᱰ₝E."᜼34.l᜜ᐝᐭrᑺ⌕!ᓄᔠᱥ᪀ḄA.ᵬyB.yC.xyD.yE.Ky35.l᜜ᐝ⌕ᵨsஹ⏣ᓄᔠᱥ7-OHḄᑺ!A.ᵬ⏣B.`⏚C.`⏚-⏚D.A1C1E.AlCh+HCl336.l᜜ᐝuᵨsஹᓄᔠᱥ4,-0HḄᑺ!A.ᵬ⏣B.`⏚C.`⏚-⏚D.A1C1E.AlCh+HCl337.iஹ⏣ᓄᔠᱥḄᵬ⏣l᜜ᐝᔾᦈq{

49¡⊦⌨¤¥tᓄᔠᱥᨵA.3-OHB.5-0HC.4'-OHD.7-OHE.§¨©ªḄy«38.iஹ⏣ᓄᔠᱥḄ`⏚-⏚l᜜ᐝu᪀!ᔲᨵA.3-OHB.5-OHC.7-OHD.wxyE.4'-OH39.ikᓄᔠᱥḄl᜜ᐝAlCh+HCl®AlCb¯°q1ᔣl30_40nm,¤¥tᓄᔠᱥA.B²]ᨵwxyB.ᨵ5-OHC.ᨵ3-OHD.A²]ᨵwxyE.AஹB²]ᙳᨵwxy40.iH-NMRᓄᔠᱥ´⌕!µ¶A.B²H-3'Ḅᱯ¸B.C²¹ºḄᱯ¸C.A²H-5Ḅᱯ¸D.A²H-7Ḅᱯ¸E.B²H-2'»H-6'Ḅᱯ¸41.¼-NMR,7,4'-wxyw½.⏣5¾᪶¹ºᓄÀrḄᜧbcdÁÂBA.A²¹ºB²¹ºÃH-2H-3B.B²¹ºA²¹ºÃH-2H-3C.B²¹ºA²¹ºÃH-3H-2D.A²¹ºB²¹ºÃH-3H-2E.H-2B²¹ºA²¹ºÃH-342.¾᪶¹ºᓃ-NMRÅÆrsᨬ0ÇḄ!A.H-2'»H-6'B.H-4'C.H-2D.H-5E.H-843.'H-NMR5,7,4'-Èxy-8-ᵬyH-2'»H-6'ḄÅÆBA.87.81,wÉ{B.66.87,wÉ{C.56.68,ᓫ{D.86.20,ᓫ{E.83.82,ᓫ{44.EI-MS⏣RᐗᨬḄÌᱏº{ÎÏ!A.MAB.[M-l]+C.AÐ

50D.BJE.B+245.EI-MSᨵÑ4ḄÌᱏº{A•(m/zl52)ÜBiA(m/zl34),t(4ß^!A.*+B.ᩈᱰ₝C."᜼D.᭒%E.ᩰ᫥B´⚪[46-100][46-50]A.&'B.áâC.ÓₐD.ÕÖE.Ý%✌46.×s⏣ᓄᔠᱥḄ!47.×sw½ᓄᔠᱥḄ!48.×sØὡᓄᔠᱥḄ!49.×sÚᓄᔠᱥḄ!50.×sÛ-3-⏣ᓄᔠᱥḄ![51-55]A.ᓄᔠᱥB.ᓄᔠᱥC.ØὡᓄᔠᱥD.á⁐ᓄᔠᱥE.Ýᓄᔠᱥ51.ã᪷!52.åæç!53.èéç!54.ᜧê!55.*+![56-60]A.ë⁐B.ᮞ⁐C.Ý⁐D.⁐E.í⁐56.ᵞḄì⁐ÎÏB57.w½Ḅì⁐ÎÏB58.Ḅì⁐ÎÏB59.ØὡḄì⁐ÎÏB60.pH>8.5á⁐ì⁐ÎÏB

51[61-65]A.ïB.ïᵞC.᭒%D.$%-7-0-PQK᧖E.ðñ₝61.ᨬ᧕ósUḄ✌ᐗ!62.ôósUuósNaHCChóõḄ!63.ôósNaHCChuósNa2c஺3óõḄᵞᐗ!64.÷ósU᧕ósNaHCChóõḄᵞ!65.÷ósNaHCChuósNa2cO3óõḄᵞ![66-70]A.5-OH,4-øyB.wxyC.Y-ù¯ᗏ²D.ÐrûºE.ÁÂxy66.üý╅ÿᑭᵨᓄᔠᱥᨵ67.⏚-⏚ᑭᵨᨵ68.ឋᓄ┲ᑭᵨᓄᔠᱥᨵ69.⏚ᑭᵨᓄᔠᱥᨵ70.⏚ᡂᑭᵨᓄᔠᱥᨵ[71-75]A.5%NaHCOB.5%NaCO323C.0.2%NaOHD.4%NaOHE.5%HC171.pH⃓5-OH⌱ᵨ72.pH⃓6-OH⌱ᵨ73.pH⃓7-OH⌱ᵨ74.pH⃓4'-OH⌱ᵨ75.pH⃓7,4'-OH⌱ᵨ[76-80]!⏒#$⁐&ᑖ()ᑡᓄᔠᱥ+,--.⏣0ᔠ1ᑺ3ῃA.3,5,7-567B.3,5,7,4'-867C.3,5,7,3',5'-967

52D.3,5-67-7-0-;✏=7✌E.3,5-67-7-0-ℍ⃔=7ᵞ76.✌ᐜC3DḄ77.FC3DḄ78.F5C3DḄ79.F8C3DḄ80.ᨬHC3DḄ[81-85]IJᨵ)ᑡK᪀Ḅஹ⏣ᓄᔠᱥḄN᜜ᐝ&A.3-OHB.5-OHC.7-OHD.4'-OHE.BQᨵRS6781.ᵬ⏣U&ᵬ⏣&VW+XIYZ40[60nm,\]ᡈ_+`ᨵ82.⏚U&ᵬ⏣&VW+XHYZ5[20nm,`ᨵ83.⏚U-⏚&ᵬ⏣&VW+XIYZ12[30nm,`ᨵ84.AlCh+HCl&ᵬ⏣&VW+XIYZ35[55nm,`ᨵ85.AICb+HCl&A1CU&VW,XINZ30[40nm,`ᨵ[86-90]A.ᔣYcZB.ᔣNcZC.ᔣdefᔣcZD.ᔣgefᔣcZE.hᨵiᓄ86.BQj_k67lmᵯo7+pqN᜜ᐝ&XI87.AQj_k67lmᵯo7+pqN᜜ᐝ&XH88.AQj_kS67+pqAQjrsoᐳuvw89.y᪶jS67ᵬ7ᓄᡈᵞᓄH+pq{ḄN᜜ᔾᦈX90.7-OHᡂ~H+pqRcH-6ஹH-8soᐳuvw[91-95])ᑡᓄᔠᱥCQsoḄ'H-NMRvwA.᜼B.C.ᜧD.r᜼E.r91.sovwDᙠᨬde(87.82,s)Ḅ92.ᨵ5+Jᑖ11Hz+5Hz,17Hz+ᓄᔠᱥ93.ᨵ+J11Hz+ᓄᔠᱥ

5394.,ᑮ66.49Ḅᓫ+ᓄᔠᱥ95.CQsoḄᓄᔠᱥ[96-100]EI-MSvwA.m/z270B.m/z269C.m/z242D.m/z168E.m/z10296.ᑖo(o97.Aᱏ(o98.B1ᱏ(o99.[M-CO](o100.[M-H(oC⚪[101-135][101-105]A.¢£B.✌C.ὅᙳD.ὅᙳ\101.ᐹᨵ᡽¨©ᵨ102.ᐹᨵᢙ«©ᵨ103.⏣104.105.AC%¬⁐X₯ᐝ[106-110]A.᜼B.ᵞ₝C.ὅᙳD.ὅᙳ\106.⏚-╅°¬±Y[N²⁐107.8rU¬Y[NY⁐108.³☢ᑖo109.µ³☢ᑖo110.ឋᓄ¢¶ᡂ·[¸⁐¹º[111-115]A.»¼B.᭒¿C.ὅᙳD,ὅᙳ\111.1ÀÁÂ⏚

54112.ᵨÃ-Ä113.Å┯¬⁐+kÇ⏚HÈ⁐\É114.ᵨÊ1⏚¹ËÄ115.Molisch¶ᡂ¸⁐Q[116-120]A.PC,,BAWjÌÍÎᑺB.PC,,3%⏚ÍÎᑺC.ὅᙳD.ὅᙳ\116.᧖%Ñ,᧖ᐗRfᜧ117.᧖%ᜧ,ÓᐗRfÑ118.ᙳÓᐗ+³☢ḄwÑ+µ³☢ḄRfᜧ119.Ôᵞᐗ+S67ᦪÖ_×+&ÙÑ120.\〉À~ᐗḄÍÎ[121-125]A.ᵞᐗB.ᵞC.ὅᙳD.ὅᙳ\121.!⏒#ↈÌ⁐&,ÍÎᑺᵬ⏣--Ü11Ý〉ᵨ122.!⏒#ↈÌ⁐&,ÍÎᑺÞ-¼-ᵬ⏣Ü60:2020〉ᵨ123.!⏒#ↈÌ⁐&+ÍÎᑺᵬ⏣--11,RfWᜧḄ124.!⏒#ↈÌ⁐&+ÍÎᑺß-ᵬ⏣Ü946,&WᜧḄ125.!⏒#ↈÌ⁐&+ᱏḄᜧÑàÀᔾ▬³⊝ãᦪḄ{ᜧÑ[126-130]A.3-OHä5-OHB.RS67C.ὅᙳD.ὅᙳ\126.AlCkåᑺḄᓄᔠᱥ127.ᙠHC1⏚ឋᩩç)AlChåᑺḄᓄᔠᱥ128.AICh+HClN᜜ᐝ&ᵬ⏣&{Ô+`Ü⏣Ýᓄᔠᱥ129.AICb+HClN᜜ᐝ&AlCh&{Ô+`Ü⏣Ýᓄᔠᱥ130.AICb+HClN᜜ᐝ&AlCb&\Ô+`Ü⏣Ýᓄᔠᱥᨵ[131-135]A.EI-MSèéfêIB.EI-MSèéfêIIC.ὅᙳD.ὅᙳ\131.ᵨÀëìᓄᔠᱥy᪶jíîï132.ᓄᔠᱥèéð¶ᑖo(o

55133.ᓄᔠᱥèéð¶A+Bᱏ(or134.ᓄᔠᱥèéð¶B+ᱏ(o2135.⏣~ᐗḄñ⌕èéfêX⚪[136-149]136.óᐗᢥK᪀ᑖ+ñ⌕õöA.5÷øḄÅᓄùB.ᔲûü=øC.BQûücýD.ᩭÿᱥE.ᔲᡂ137.Ḅ⌕ᨵᦔᡂᑖA,᭒B.ᙠ!"#$C.%&'()*+,D.%&)⏚./0ᔠ+,E.2ᵨ4⏚5678138.9:Ḅ⌕ᨵᦔᡂᑖA.9:;B.ᨵᢙ=>ᵨC.9?⏣AᓄᔠᱥD.%&C⏚D/ᡂE⁐5GE.᧕IᓄJᩞ᜜MNO139.P᪷Ḅ⌕ᨵᦔᡂᑖA.ᨵᜧSTB.9?⏣AᓄᔠᱥC.%./U-WX⏚+,D.%./Y⏚-╅[+,E.2ᵨIᓄ\]⁐^6ᑖ_140.2ᵨ`␺bc(9?AᓄᔠᱥḄA.Y⏚-╅[+,B.'()*+,C.┯-WX⏚+,D.C⏚D+,E.C⏚╅+,141.9?&efYAgᑺ0ᔠḄi⌕ᩩkA.ᐹ7-OHB.ᐹmcnopC.ᐹ3-OH

56D.ᐹ5-OHE.3-OH5-OHqrs2142.ᓄu6v2w5-OH9?&3-0H9?xbḄgᑺyA.C⏚DB.)⏚-C⏚*C.)⏚-₝⏚D.c{I┯-WX⏚E.|ឋ{ᓄ┞143.789?Aᓄᔠᱥ2ᵨA.ᑺ786B.DY5G6C.4⏚56D.6E.⏒⁐^6144.pH⃓86ᑖ_9?AᓄᔠᱥA.w9?ᙠᾦឋᨵᑺB.4y⃓8ᑺC.〉ᵨ`ᑖ_᧖A᧖ᐗAD.〉ᵨ`ᑖ_⏚ឋsḄTᐗAE.⏚ឋḄ9?ᐜ⃓8ᩭ145.᜜ᐝ^6v9?⏣AḄ{ᓄ\-Y⏚^ᑖb&{ᓄ\^ᵬ⏣^v2¡A.7-OHB.4'-OHC.mcnopD.5-OHE.3-OH146.᜜ᐝ^v2ᵨ`¢¡9?ஹ9?⏣¤᪀ᨵ¦mcnopḄ§¨gᑺᨵA.ᵬ⏣*B.{ᓄ┲C.C⏚*-)⏚D.₝⏚-)⏚E.AlCh+HCl147.9?AᓄᔠᱥḄ᜜ᐝ^A.9?9?⏣ᨵªIªII«¬B.®9?ªூyvªIIᑣC.c(9?ªI±yvªIᑣD.²ὡ?ªnyvªIᑣE.9?9?⏥^µ!¶v·ªI§¸s148.¹ᑡᔜᓄᔠᱥ%ᑭᵨᐸᵬ⏣ᐝ^xbḄA.9?&9?⏣B.9?&²ὡ?C.9?⏣-3-0-ℍ⃔Àᵞ&9?⏣-3-0-ÂÃÀ᧖

57D.c(9?&c(9?⏣E.ÄÅ&Æ149.ᙠÄÅḄᓃ-NMR^A.H-3yr¬È┦ḄᓫËÌB.H-6H-8ÍcÎC.H-6ËÌH-8Ȩ̈`ÏÐÑxD.H-2'ycÎE.H-5'H-6'yÒcÎcÓÔÕ[1-2]1.9?Aᓄᔠᱥ2.Ö×ᐳÙÚÛÜÝ⚪[1-7]1.rß9?A᧖ᐗà`ஹஹ᧕`áᨵᑺvc(9?ஹ®9?áâᑖãväᜧ஺9?ᵞᵫ`¤ᔠçÀvឋv-ß᧕`ஹஹá᩽ឋᜧḄᑺvà`ஹஹá᩽ឋéḄᑺ஺2.9?Aᓄᔠᱥ⏚ឋêëìíyᜧ`ᜧ`ᜧ`,ïឋð2ᵨ`78ᑖ_஺ñ7-ᡈ4'-0Hᜐ`4-§ôpḄ,ᦑ⏚ឋ;÷5-§opñ&øpµᡂ,ᦑ⏚ឋo3.9?Aᓄᔠᱥñùᐹnopv2`vúûü25G᪆஺ᑭᵨþ_9?ÿᔠᱥḄ⏚ឋᵨᑖᐸ7-ᡈ4,-0Hᵨ⃓5-0Hᵨ⃓⃓ᑖ⏚ᓄᑖ஺4.ᵨ⏚!ᓄᔠᱥ"#$%&'()ᜧ+,ẚ./⏚⏚ᓄ"0(1pH)2+,3ᡂ56789:2ᦈ᳛஺5.=ᦪ!ᓄᔠᱥᙠ200@400nmBᑁᨵEFG⌕ᔾᦈJJIᙠnmKLJHᙠnmKLMJINBOPQᵯSTUVWḄᔾᦈJHNAOPQḄXY.!ᓄᔠᱥḄ![ᐸJIᡈJnḄஹஹ]^᪷`!ᓄᔠᱥᙠᵬ⏣Ḅc᜜ᐝfᱯh+ijklḄ஺6.ᙠ!ᓄᔠᱥᵬ⏣/ᐭnopᑺ5!ᓄᔠᱥḄrstᡈ,vwc᜜ᐝfḄᱯhឋᦋy᪷`z{yᓄ+i|rst}~tḄᡈ஺7.ᙠEI-MS!ᓄᔠᱥᨵEt99I

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72¨©ªḂ᧖(ߟ)⌱±⚪[1-68]A⚪[1-18]1.²³ᔠ´µḂ᧖ᐗm᪀ᱯiḄA.AஹBஹCஹDஹEF¹º»B.E»F»¼½¾¿ÀÁÂC.E»ᔬᗏ»F»Åᗏ»D.Ci஺ஹC13ஹC17ÆÇÈᙳ+B-᪀E.ᑖÊ_ËtÌÍ⏚ឋḂÎ2.²³ᔠϼÐÑÒm᪀ᱯiḄA.CioP-CHB.CP-CHC.C14a-CH31333D.Coa-CHE.C25B-CH3233.²³ᔠḂÎÓឋḄA.ᜧ+Ô⁐mᨔB.ᕡÞßàáC.pæçᨵèéឋD.Ö᤯ØÙÚTÛÜE.ᜧᦪᨵã⊈åᵨ4.ѵḂêëãᑖìíᐭ⏚ï:íð⏚<ñï:íòóᓄô<ØÖ᤯m1A.õïÛÜö÷øùB.⏚ïÛÜöúñïûüC.ñïÛÜöú⏚ïûüD.õïᙳýÛÜE.⏚ïᨵÛÜñïýÛÜ5.²〉ᵨúÿḂ᧖ᑖḄA.ᑖB.ᶇ⏣C.D.⏣⃓E.⁐6.ᨵᐵḂ┯ḄA.ᓫ"#᧖$%"᧖B.&ឋḂ᧖C.()*ᵬ⏣ஹ-⏥ஹ/⏚D.12ᔠᡂᶇ567Ḅ8⌕:ᧇE.<%=/⏚>ᑺ@AB⁐$CDEFGᵨ*I⁐@⁐7.ᨵᐵJKḂL┯ḄA.ᐰNᱥPḂ᧖QRSTU᪷ுX᪷B.AYஹBY᧖ᐗ[\]Y^_ᱥC.CY`ab⏚Ḅc"#D.AYஹBYᨵ)⊈eᵨ$CYᨵᢙ)⊈eᵨ73

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