浙江省宁波2021-2022学年高三六校第一次联考化学试卷含解析

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+Mg
^=^COg
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=H2g
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=CO2g
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31C.§ᵨᵯc+ᑴ╅MgCLᰚªᦾMg+CLTD.ᔣNaOHJ¬ᐭ}QḄ®ᓄ]SO2+2NaOH=Na2sO3+H2O17ஹW£°±²³J´ḄtQ/¬;µᢞᨵCuiḄ~·/᪷¹~·"ᔲa⁐ᡈ⁐BaᓄḄ'»ᩭᑨF³J´ḄtQ/ᐸ!°4Cul+Hg=Cu2Hgi4+2Cu஺(ᑡᨵᐵ*+-.Ḅ"A.§!ḄᱥCu2Hgi4J/HgḄᓄᔠÁ°+2B.§!JCuiÂ"ᓄᑺ/Ä"ÅÆᑺC.§!JHgᐗÈÉCuᐗÈᙳËᓄD.§!JBᡂ64gCu'/Ì:ḄᵯÍᦪ°2NA18ஹÏÐᩞᧇ⌕ÓᐹᨵÕḄt᳛/×ØᐸÙឋP/ᙠBᱥÚL§ᨵÛÜ!ᵨ஺ᵫN-ÞßàáâãNVP
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ᨵpHᙳ9,ᙳ10mLḄNaOHCHjCOONaᑡḄA.ḄcNa+


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8HjSO,iAANi,NaCIOiONjSOjKLMᜐᳮAB(1)ᑏ)ᵨde\]ᑴXC1O2Ḅᓄfgho(2)\]A$ᢝjkᐭN2ḄmḄ.\]Bop(q“stu”ஹ“Htu”ᡈ“50CḄxtu”)\]஺TUDz{\]A$CIO2Ḅ|}'~\]᝞_bCIO2Kg᝞bজᙠ┵$pᐭ}ḄỚᓄ'ᵨ100mLtO'p3mL⏚ঝᢥ᯿_\ᘤᙠᴻ$pᐭজ$'ঞᡂḄ஺02ᵫkᐭ┵Ḅ$'ᐙᑖᔾᦈ'¢ᴻ$Ḅt᎔ᐭ┵$'¤¥ᴻ2-3¦'§᎔ᐭ┵'ᔣ┵$pᐭ©ª«¬টᵨcmolLTNa2s2O3᪗¯ª{┵$Ḅ&'ᐳᵨ±VmLNa2s2O3(²³b(3)\]$ᴻḄ´ᵨo(4)ª{µFḄ¶·.(5)z¸kᐭCIChḄ|}m(ClO)=g(ᵨ᦮ᳮKḄ»cஹVḄ¼ᦪh⊤a)஺226ஹ(10ᑖ)¿ÀᓅÂÃᜅ$Å)Æ@☘È┴(@⏀ᐹ)'⊤☢▬ḼᨵÏ⁐Ñ&ᱥ|'ᡭÔÕ⏀✏ᡫØ'ᑁÚᨵ26kg☘Ï⁐&'ÛÜÝ{2000ÞßàḄ“¿áâ⏀”஺ãᡃåὃÃçஹè⏀çḄ@éᜧ
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hÿᓄᓄḄᐗ1:2,ᑣAḄᓄ()!1"#$%&'()*⏚ឋᩩ./&012ᓄᡠ4&(5ᐜ789Ḅ12᣸;&5᣸◀02Ḅ=᡾஺28ஹ(14ᑖ)BC(As4s4)DEC(As2s3)*FGHḄI⌕KᱥMᧇ&OὅᙠRᯠTᐳ஺᪷W⚪YZᡂ/ᑡ]1^(l)As2s3DSnCLᙠ_⏚`ᓄAs4s4DSnCL.abcH2s2d.fAs2s3DSnCLghZᐰ&As2s3DHCIḄᱥḄ.ᑏcᓄaᵨlm᫑o᪗cᵯr`s________________________________________________________________________________________________________________0(2)tuḄᓄᑺ*,xḄ2d(ᵨᔾᦈ஺(3)As2s3DHNChᨵ᝞/^As2s3+10H++10N03-=2113AsO4+3S+IONO2T+2H2஺fᡂ2molH3ASO4,ᑣ`sᵯrḄᱥḄ.f7~ᡂMᵯ&ᑣNthᙠ(]“g᩽”ᡈ“᩽”)▬⍎c஺29ஹ(10ᑖ)ḼḄ&ᜩᯠ2Ḅᑭᵨᩭᑮ஺CH4/CO2ᓄ᦮ᑴᜓᔠᡂ2(CODH"*¢£2dCO2DCH4ᓄᑭᵨḄ⌕⌶¥&a¦§ᑁ᜜Ẇ«¬ᕒḄ®¯஺°±/ᑡ²⚪^(1)³´^জCH4(g)+H2O(g)^^CO(g)+3H2(g)AHi=+205.9kJ-moF1ঝCO(g)+H2O(g)=^CO2(g)+H2(g)AH2=—41.2kJ-moF1CH4/CO2ᓄ᦮CH(g)+CO2(g)^^2CO(g)+2H2(g)AH4ᓄ᦮ḄAH=kJ-moF10⌕µ¶·ᑮ¸⊝Ḅº»aF®HḄx᳛(½GḄ¾¿»2(2)ᔣ2LÂឋÃÄÅᘤᐙᐭ2moicD2moiCO2ÉÊᓄ᦮&ËÌ¢¯/¸⊝dÍCWDCOḄdÎ

11ᑖᦪ()!"#$ᓄ᝞'⊤ᡠ*஺CH4CO¢¯—__TiaaTcb2+,b>a>c,ᑣTiT2(.ᡈ"1)஺Ti'234Ḅ5⊝7ᦪK=(mol2-L-2)(3)89Ẇ;⊤<=>?ᓄᑺឋBḼ᩽EF⌕ḄHᵨᙠKL0.03MPa,"#750CᩩN'=>OP?ᓄᑺឋḄQRᐵᦪS᝞'⊤ᓄ᳛%ᡂ/%ᓄᑺCllcoClhCO,COH422MgO99.387.70.86.850.342.1NiCaO58.845.817.718.833.729.8CeOÑ62.957.617.219.134.029.7ᵫU⊤ᑨW4⌱Y=E(.ᓄZ[)ᳮᵫ஺(4)]ᨵ"#_ḄIஹIIஹIIIabឤKdefᘤᙳᐙᐭ2moicHKg)k2moicO2(g)lm34abfᘤḄ34KLᑖnEpiatmஹpzatmஹpaatm,ᙠᐸpᩩN_Ḅqr'34ᙳlmᑮtmintC(hḄuᑖᦪ᝞vᡠ*wtIஹIIஹHlbfᘤxyzᜐ|ᓄZ5⊝}᝱Ḅ஺(5)ᑭᵨᔠᡂEᧇᔠᡂᵬ⏣ᐸ34ECO(g)+2Hz(g)=^CH30H(g),ᙠyz"#'234ḄᐵᦪS᝞'⊤ᡠ*:/(molL')᳛/(molLTminT)COH210.240.480.36120.240.960.72030480480.719234᳛Ḅ[EVHkiECmCONcYHzNk"#ᨵᐵḄ᳛7ᦪ)஺ᵫ⊤xᦪSz34᳛Ḅ[xn=—(᦮ᦪ)஺2"#'5⊝t
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£¤¥¦§34«ᐭḄ¬©CO2gHsO-34§ᜧ©ᐳªᦑD§⌱;ᦑ⌱B஺2,Bூ᪆௃²³´kµ¶·ᓄᱥxFeOyFe2O3´¸¹ᡂ³ºᑺᑖᡂ»¼½y½ᙠ¾"'ាÀÁᐰ34Ãᡂ¶·ᓄ³FeÄ⏚34ÃᡂFeCLH2,Æy½ÇÈÉᐭ¬©ḄNaOHÊËᑖ34Ãᡂ̳⏚ÍÎÏ»Ðqr'ÃᡂḄ©Ñ5:7,ÒÎᱥḄ©ᑖnE5molஹ7mol,214᪷Sᵯ¤ÕÖ×ឤ,n(Fe)=n(H2)=5mol,n(Al)=7molx—=—mob33ᎷÒxmolFeOஹymolFezfh,14»ᵫFeᐗ×ឤ,x+2y=5,ᵫᵯ¤ÕÖ×ឤ,:2x+2yx3=}-x3Ûx=l,y=2,ᦑx:y=l:2,ᦑ⌱B.3ஹAூ᪆௃AஹÜ⏚Ý⏚ÍÊË34ÃÞ·ᓄÝÜ⏚ÜߧᡠàᵨNa2c03ÊËÉàán⌱⚗AâB.ãäåḄyæçᱥᨵ(CH3)2CHCH2CI,(CH)2CCICH3ᐳ2Ð⌱⚗B┯éâ3C.êÜëEæÜëḄÉêᱥ§ìÝÝíîïᑖ¤xð§ìᨵÝÝíî⌱⚗C┯éâD.ᵬïæᙠᐝ᯿'34ó⌕ôÃḄõöUḄΤ÷ç§ᑮïøUΤ÷çḄᱥ2,4-Þæᵬï⌱⚗D┯éâᫀ⌱A஺4ஹC

13ூÛ᪆௃A.ax§ìïøᑣ§ü|ý✏ÿᓄᔠᱥᨵb✏ᓄᔠᱥᨵOᐗ✏A┯B.aஹcᵬஹᵬஹᵬᙳ☢᪀ᑣa"cᑖ$ᡠᨵ&'$()ᜐ+,-☢.B┯C.a&&/0ஹb12ஹc-CHO,ᙳ(345678ᡂ:;C<=D.b>?)3@ᑴCu(OH)2BCD:;7ᡂẈF⁐HIcᑖ$ᨵ?(J3@ᑴCu(OH)2BCDᐳL:;7ᡂẈF⁐HID┯ᦑᔠᳮ⌱⚗QCo5ஹBூS᪆௃A.V5WXᨵYᑖV53X:;7ᡂVᓄ4"V⏚ᡠJ>[\]^_Ḅᵯ$ᦪᦑA┯B.᪗defg22.4L65ImoL,hNe'$ᨵ10hᵯ$ᓽImolj5ᨵIONAhᵯ$ᦑB<=C.k⏚WDḄlmnᑣ>[\]H+ᦪoᦑC┯D.IZOgNaHSChImoLImolNaHSChᑖ$ᨵImolNaf"lmolHSO,ᑣ120gNaHSChᑖ$□q$"▢q$4Ḅsᦪ2NA,ᦑD┯ᦑ⌱B஺6ஹDூS᪆௃A.FeCbWDu8HIWDvὅ67xᓄy':;<=Ḅq$z{|}2Fe3++2~=2Fe2++l2,ᦑA┯B.ᔣ(NH5SO4WDu8Ba(OH”WD}2NH+SO-+Ba2++2OH-=2NH.HO+BaSOI,ᦑB┯324c.ca(OH)2WD3NaHCChWDᔠ}Ca2++OH-+HCO3=CaCO>k+HO(ᦑC┯32D.3mol/LNa2cO3WD"Imol/LAL(SO4)3WDlᔠᑣCCV-3Al"ᢥ᯿3:267/XS:;q$z{|:2A13++3CO^+3HO=2A1(OH)+3COT,ᦑD<=஺2?2ᦑ⌱D஺7ஹCூS᪆௃A.kḄ⌕ᡂᑖ⏚,⏚,ᵨk◀X,q$z{|:2CH3COOH+CaCO3=COT+Ca2++H2O+2CHCOO,23ᦑA┯B.⏚ឋᩩg⏚⏚xᓄ7ᡂ⏚q$:;z{|}3SO32+2H++2NOy=3SO42+2NOt+HO,ᦑB2┯C.Cr(VI)ᐹᨵxᓄឋ(Jᵨᙠ⏚ឋᩩgᵨ⏚ᜐᳮXCr(VI),:;Ḅq$z{|}

14CrO72+3SO2+8H+=3SO42+2Cr3++4H2O,ᦑCgÓÑ23D.⏚ឋ®Ô⏚Õ(ᓄ₝⏚"#&₝⏚*×⏚&Ë)Ø&gÓḄḄÙr2MnO4+5HC2O4+6H+=2Mn2++10CO2t+8HO,ᦑD┯ÛÑ22ᦑ⌱C஺ூÞß௃á⚪Ḅ᧕┯ÞB,⌕ãYä⏚ᐹᨵæᓄឋ&)ç7èé⏚᪷Ùrᓄ஺8ஹCூê᪆௃YMrᙠ¶ᕜíIîᐗMrï¥ᨬᜧ&ᑣYNaXDY)ᡂòó▢□ÙröᦪøÌḄÙrᓄᔠᱥ&ᑣXO,òóᓄᔠᱥùᓄúDᓄúÑû¢/,0.1molL“WḄüᓄᱥý"#ḄpH1,ᑣHWᐗæ⏚&¶ᕜíIîᐗüᓄᱥᐗæ⏚ḄᐗþᨵHCLWClZChÿᐭNaOH
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;ᙳ=>:=?@:ḄᵯB⊝ᦑCDE1D.OFᨵD3ᦑD┯01ᦑHᫀCoூJK௃ᵯᦪ!"ᜧᵯᦪ$%᪶ᵯ₹ᦪ(!"ᜧ,LMᐗOPᨵᨬRD3ᨬRD3STMUᦪPᨵᨬVW3ᨬVW3STMUᦪ-8஺9ஹDூ᪆௃A.YZ[\]^TᔠᡂRᑖᩞᧇ^TᨵcRᑖᓄᔠᱥᦑADE1B.ấefḄ!ghᩞᧇiᑴ⌼l□iᵯnoᡠ)“᳝ᐢs”ᨴᳫwḄl□iᵯnḄᩞᧇxấᦑBDE1C.yl□iz{|ᓄᵯiᨵᑭT⁚iᦑCDE1D.ᘤ〉ᵨTḄ=〉ᵨTᵯᘤᦑD┯01ᦑ⌱D஺10ஹAூ᪆௃

15N?(g)+0(g)f2MXg)2QmolIDCQC0().ᓄ(mol/DQc஺-c)(c-Cj)2(c-q)00B⊝QmolIDcc2(஺-cPx[ᦑK=4"q),ᦑADE17B.ᱥ8ᡂᱥᙳxhᦑhḄm=ᘤឤᘤᦑV=ᑣp=£=ᦑB┯01C.ᵫbḄB⊝¡¢(ᦑxB⊝>£¤¥ᓄᑺ§iᦋ©᳛=iᦋB⊝ᦑb=ixᵫT¥ᓄᑺ?@ḄᦑC┯01D.ᵫbᓄ«©᳛¬(ᓄ®ᜧ)ḄB⊝¡¢(ᓣR±B⊝Dᔣ£¤ᑣDᔾ´ᓽAH>0,ᦑD┯01ᦑHᫀAo11ஹBூ᪆௃iµ¶·Ḅ¸⁐¹º»¼½Ḅh¾¿h
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À⏚ឋµ¹º»À¸⁐ÈÄ=iµ¶·Ḅ¸⁐¹º»¼½D┯01Hᫀ⌱B஺12ஹBூ᪆௃᪷ÃÔÕÖᵯ᩽H2,Òᵯ᩽F2,ᯠ᪷ÃᵯÙᳮÛÜᑖ᪆8ᑨÞ1ூ௃Aஹ᪷ÃÔÕKHF2;HᐗOÀ+13Öᵯ᩽᪆àH2,⊤¿Öᵯ᩽>âᵯḄãÙᓽÖᵯ᩽xᵯnḄ▢᩽Öᵯ᩽åᵯæḄW᩽$çᦑA¾èDE1Bஹ᪷ÃÔÕ⍎àḄhH28F2,¾¿ᵯê:
;¢ëḄxì8íᐗOÈÄᵯîï◤⌕=Þ⊡ᐙḄXxHF,ᦑB¾è┯01Cஹ□᩽ôᡂí▢᩽ôH2,õὅ{÷>ᒓùúûᰦýÈÄþÿ◞
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16Dஹᵫ¢4ᓄ£Ḅ¢ᓄ4>XWD(J¤ᵯ(¥n¢4ᓄ£ᙠ¢ᓄ467ᵯqᦑD¦[<=஺13ஹDூS᪆௃Aஹ⏣᧕ᢵ6ᔣLḄ⏣ªᐭ¬5(Jᔣ®¯°±²⏣³5"x5⌱⚗A<=Bஹᙠ´µ¶ᓄg⏣67¶ᓄxᓄ7ᡂ?⌱⚗B<=Cஹ?᧕ᢵ6;ᵨ·X¸ᦈº?»ᱥ⌱⚗C<=Dஹ»ᱥᨵ⏣⏣¼)y'⏚ឋ½═⏚£WD¿ᐸÁ⁐⌱⚗D┯஺Âᫀ⌱D஺14ஹBூS᪆௃A.ᙠ25'C}জC(s)+C)2(g)?^^CO(g)AH4=-lllkJ/mol®H(g)+10(g)=H(g)222AH=-242kJ/mol(3)C(s)+O2(g)=CO2(g)AH=-394kJ/mol,ÄᔠÅÆÇÈ(nঞ-জ-ঝÌᑮ22CO(g)+HO(g)=CO(g)+H(g)AH=-41kJ/mobᦑA<=222B.ÎᜧÐ:;জḄ-⊝ᔣ⌮:;zᔣ_ÓÔÕÖᑣ-⊝×ᦪKÖᦑB┯C.-⊝+ᱥØḄᱥØḄḄÖᓄÙÚᓄÛ\ᦪÙÚᑣজÜᑮ-⊝Ý7ᡂImolCOḄ+7ᡂ0.5molO,ᦑC<=2D.:;ঝÞL:;ᯏÖàáᓄÛ0ᔾᦈḄ)ãäᡂ0åÞḄ)æᱥØḄ3Lᡂ<Úᑣ:;ঝàç2moiH-H"lmolO=OḄᓄÛ0ᡠᔾᦈḄ)Úèᡂ4moiO-H0ᡠÞéḄ)484kJ,ᦑD<=Âᫀ⌱B஺ூêë௃:;L=:;ᱥ0)s"-7ᡂᱥ0)s"஺15ஹCூS᪆௃A.⏚ឋᩩg⏚᪷q$)í⏚îxᓄ7ᡂ⏚îᦑA┯B.;ᐜ8Vᓄ⚞ñ8&⏚ᯠóôñ8î⏚(◀äõîᨵḄ⏚┛ᩖØᦑB┯C.øq$⍗KSCNWDÖ⁐u8VXøq$xᓄ7ᡂøq$⍗KSCNWDÖF⁐(úûWDᨵFe2+,ᦑC<=D.⏚ᐹᨵxᓄឋ(xᓄỚq$)¦ûH2O2ḄxᓄឋÚLᦑD┯Âᫀ⌱C஺ூêë௃ý⚪ὃᱥḄ␺ᫀḄḄḄᐵ᣸◀᡾"#

17ᑺḄ&ᐭ()஺16ஹCூ᪆௃A.⏚ឋ12⏚ு45ுHCO3,ᡠ7C6H5O+CO2+H2O-C6H5OH+HCO3,A┯9:B.;<Ḅ=<ᔠ;?@ABᦋᑏᡂOH\B┯91C.FGHᵯᰚKḄMgCLᑴMN╅CPQ:D.ᔣNaOHSTUᐭVWḄXYᓄ[\]ᡂNaHSCh,D┯9:ᦑ⌱C஺17^Aூ᪆௃A.Cu2Hgi4CuᐗaḄᓄᔠb+1bHg+2bI-1bᦑAPQ:B.Cuᐗaᓄᔠbcᑖᵫ+1bfgᑮ0bijkCuiYᓄᑺᦑB┯9:C.CulᑮᵯijkHgᜫnᵯiYᓄᦑC┯9:D.ᵫopqrHst\]ᡂ64gCu,ᓽImolvwxImolᵯᵯᦪINA,ᦑD┯9:ᫀ⌱A஺18ஹBூ᪆௃᝞{HEMANVPUV&|t\]ᡂ}|ᱥA,|ᔠVo~ᑺḄ1.6<᳛ᨬ}஺ூ௃A.NVP22Ḅᐸ=2kḄ᜜ᙳC-HᦑAᐹᨵ(t᪀ᦑA┯9:B.-OH<}|ᱥAᨵ-OHᐹᨵḄ<ឋᦑBPQ:C.HEMANVPUV&|t\]ᡂ}|ᱥA,ᦑC┯9:D.ᑴᜓVo~ᑺ<᳛ᐵ᝞{|ᔠVo~ᑺḄ1.6<᳛ᨬ}A~ᑺḄ}ᦑD┯9:ᫀ⌱B஺ூ௃<1¡ஹ¢£஺¤¥¦B§¨©Ḅᱥ=ªᐹᨵḄ<ឋ஺19ஹBூ᪆௃pH«£ḄNaOHCMCOONaSTc(NaOH)

18ூ௃A.pHḄNaOHCJhCOONac(NaOH)⏚?@4pHᜧBCCH3COONa>NaOH,ᦑC┯&D.ᑖEF#$Ḅ0⏚GHាJGHKLὑḄ0⏚NONaOHஹCH3coONaḄᱥRḄSᡂ:n(NaOH)⏚LὑḄ<0⏚NOᜧᦑD┯&஺320ஹBூ᪆௃WX14#Y⏚Zᙠ;\ᩩ^_GH`ᡂSO2,`ᡂḄSO22ᐭWX24⏚ឋc═⏚ef`gᓄijGHklc═⏚em⁐WX34ZnSHC1O>HCO3,ᦑHC1OCCV-·FK»`⌱⚗B┯&C.¼S¬»`Ḅ0⏚½CO32-ᐰ¿GHᡂCO2N⌱⚗CD.4ឋKᵫᵯ₹Áឤlᑮc(Na+ÄC(C1O-)+C(C±)ᵫ5f`gᓄijGHᵫlᜫᵯÁឤlᑮC(CD=C(C1O-)+C(HC1O),7ÆὶÈÉlc(Na+)=2c(CKr)+c(HClO),⌱⚗D஺ᫀ⌱B஺

1922ஹBூ᪆௃A.³´Ḅᡂᑖµ¶µ¶ᨵCஹHஹOஹN£ᐗaᡠ7µ¶·¸vḄ¹ᱥ◀ºᨵCO2H2O]ᡂ,jᨵᐸ¼ᱥ]ᡂᦑA┯9:B.ᓬ¾¿Ḅ¾ᢣḄÁᱥ¾Áᱥ¾ᨵ22ᡈ22ÃBÄ⏚ឋḄ}Å⏚ÆSTÇ⁐BPQ:C.ṺÊḄᡂᑖⅅÊAÌÍ᜜ÌÍ<◤⌕ᙠ⏘ᡈÒ[⏚&ÓḄÔᵨÖ×BØÙC┯9:D.ÚÛḄᡂᑖÜÝaÜÝaÞÌÍßàᔠᱥáâãäAå¬ᑖ᪀D┯9ᫀ⌱B஺Xஹæ⌱ç⚪(ᐳ84ᑖ)ூ᪆௃AḄᑖpC2H4,Aëìᓽí᪀îpCH2=CH2,᪷ðñ⚪(1),DBÞMNòt\óDᑖôᨵ=YkᓽDᨵ=OH,DNõö✏øᓄᔠᱥᓽDᨵ4ùDḄ«ᑖWlxl6/13.1%=122,᪷ð4ëúûüDḄí᪀îp^Q^-CHICHIOH,᪷ðýúḄí᪀îpûüCḄí᪀îpHOCHCHOH,᪷22ðþÿ
BḄ᪀CMOH,ᑖ᪆ூ௃AḄᑖC2H4,Aᓽ᪀CH2=CH2,᪷⚪(1),DDᑖᨵ!"#ᓽD$ᨵOH,D%&✏(ᓄᔠᱥᓽD$ᨵ,-DḄ./ᑖ01lxl6/13.1%=122,᪷,2Ḅ᪀
DḄ᪀^Q^-CHCHOH,᪷32Ḅ᪀
CḄ᪀;HOCHCHOH,᪷45
BḄ᪀CH3OH,22(1)᪷67ᑖ᪆BḄ᪀CMOH,ᓽᑖCH,ODDᑖᨵ!"#,ᓽD$ᨵOH,D%&✏(ᓄᔠᱥᓽD$ᨵ,-DḄ./ᑖ01916/13.1%=122,᪷,2Ḅ

20᪀
DḄ᪀ீO)~cmCH20H;(2)CḄ᪀HOCH2cH2OH,$ᨵḄ<=>?@᪷ᔠᡂBCড>,⏣F"ᓄᡂ,2GH"ᓄ;(3)ঢ>,2HOCH2cH20HKᡂ32ᓽᓄLMN♦HjO(4)᪷45᪶PᐳRSTᨵ4UVWX>/Y᪀V☢[\]3221,WX^_ᓄL-᛻ḄS#0Ḅ!ᦪ]3221,bᔠᩩdḄ᪀HWIIn.vCH3'CH3c(5)eᓄᔠᱥE,ᵬ2Ḅ_gᱥ,./ᑖ01],ᵬ2ᜧ14,ᑣᐸᑖCHH,O,EḄ_ᑖk᪀lmFed.,1(nop⁐WX$ᨵr?@Ꮇt,-6ᨵOHஹC2H5v!wx@ᨵyz/{|᪀Ꮇt,-6ᨵOHஹ-CH3ஹCH3{!wx@v!ᵬ@ᙠy?@ᨵ2|᪀v!ᵬ@ᙠz?@ᨵ3|᪀v!ᵬ@ᙠ/,?@ᨵ1|᪀ᐳᨵ9|᪀(6)᪷ঝ
Kᡂ᪗ᱥ#ᧇ>᪷BCজᵨ஺2ᙠAgᓄᑺḄᩩdKᡂ-"CH3KḄḄ#ᧇ>CWKᡂᵨ2KᔠᡂBCCH30IICI0CO,/c\INaOH,«5/\CH3cHe%-----------►CH,—CHߟ>002CH3HC—CH-CH32ூ௃⚪Ḅ>_ᑖk᪀lḄᑨ᪷45ᑨ$ᨵḄ᝞⚪$ᨵ,-9,ᑏ,2Ḅ_ᑖk᪀l,2¢£_ᑖk᪀lᑣᨵCH2,bᔠVᨵ4|V☢[\]3221,ᯠ¥¦CH2cHO,§ᡂC%CHO,ᙠ,-6ᨵyஹzஹ/{|ᯠ¥᪷VVḄ☢[¨©ᑨª«bᔠ⌕஺24ஹBDy?@,ᵬ⏚ᡈ2-?@,ᵬ⏚°@HO-O-NO,

21OHOH5H+HOO^CHOஹÍ")ஹHJO^OQCH2OHOHCM.COOKmNHCOCH)______7x2+2-6ʬf`ËÌGH`ᡂA,ACa5F4⛳$Ò—--=5,᪷}ÕÖ×᪀ÙÆÚF4-ᨵÊÛ°gÜÝᡠ"FC!ßH,ECHOT±)NH2DåஹHC1GH`ᡂE,×ᔠ⚪èéêÚD×᪀ÙÆCHOT')~NO,AGH`ᡂB,BNaOHf`GH`ᡂC,᪷}D×᪀ÙÆÚA#ë⏚f`ËÌGH`ᡂB,BCCIT;B)-N஺CCNaO—QlN஺}~஺ூ௃(1)A.ÕÖᨵ⏒Öðஹñð2òó·ôA┯&B.ÕÖᨵñð⍗ö¬ᓄå⁐BC.ÕÖḄᑖÆC÷CBHHNO,C┯&3D.⏒ÖðLὑImolNaOH,ñðᐳLὑ2moiNaOH,ImolÕÖᨬû3moiNaOHGHDüýᡠþBDᦑᫀC÷BD(2)FḄ×᪀ÙÆC÷ÿ◤”ᵬ⏚ᡈ2-ᵬ⏚BḄ᪀:'ஹ2!"!ᦑ$ᫀᵬ⏚ᡈ2-ᵬ⏚&&(3)ᵫᑖ᪆*+Dᦑ$ᫀHO—NO,(4)E,Fῃ./ᔠ1ᡂ345ᓄ789:;:.n-=SMT0H+HO2ᦑ$ᫀ<…OHOH0(5)F>"@AHB1CD89ᑣᑖF1G-CHO,2G-OH,ᡈὅ1GHCOO-,1G-OH,1G-CHO,2G-OHᐳᨵ61GHCOO-,1G-OHᐳᨵKL3ᐳ9ᐸFᑖᨵNOPᓄ7Q᛻ḄSḄᨵ3ᑖT:ᦑ$ᫀ:

22HO-^2^00CH5OCH,(ுCH3coOHῃ½3ᔠ¾ᩭ,(6)⌮ᔠᡂᑖ᪆´H.CO■\HCUCHஹ$⏒·@¸ᵫNH,ᦑÁᫀ:ூ௃ÄÅKÆÇḄ᪀ᨵ´-CHOஹHCOO-ஹHCONH-,HCOOHÈ஺25ஹ2NaC10+NaS0+HS0,(^)—2C10+2NaS0+H0ÉÊCIO2ḄËÌ■ÎCKhḄËÌÏоKᑖ323212242ÑÒÓᰦÕÖ½×■ÎC1O2⍎mC1O2ᐰÚÛÜÝÞC1O2Ḅ01noᵫß⁐àá⁐âᙠ30sᑁä⁐^Kàᓄ1.35xlO-2cVூÑ᪆௃I.(1)᪷⚪å45¸æ´NaCIChçè⏚ᙠ⏚ឋᩩdKᡂCKhè⏚Èᱥ0(2)"ᓄ(CIOêë11࠷,NaClChçè⏚ᙠ⏚ឋᩩdKᡂ"ᓄÈᱥ0CKhËÌÏÐì᧕KᑖÑÒÓᰦÕCKhḄëÊᵨÖ½¸îmC1O2ïðoln.(3)ᵨ½ñòᔾᦈõöḄ"ᓄ÷lâm┵ùᑁ᜜ûü.ÈÛÜÝ1(4)noᵫß⁐ាþàá⁐ÿᑖ
ᑁ⁐(5)᪷ᓄᑖ᪆ᨵᐵ2c஺5L10Na2s2O3n(ClO),᪷m=nMm(ClO)«22ூ"#௃I.(1)᪷⚪&'()*+NaCKh,-.⏚0ᙠ⏚ឋᩩ456ᡂCKh8.⏚09ᱥ;ᑣᓄ=>?@+./ᵪஹ50࠷2NaC10+NaS0+HS0(?^<)2cl02+2Na2so4+G0,ᦑIᫀ@+3232/J2NaCl(\+Na,S0q+H,S0”(L)N2C10,+2Na,S0,+H,0&

23(2)OᓄP(C1O2)Q@11࠷,NaClth,-.⏚0ᙠ⏚ឋᩩ456ᡂOᓄP9ᱥ;LRSTU᧕W6ᑖ#XYᰦ[\ᐭ^_`U᣸bC1O2ḄQdᵨfg)hiCKhjk@lmᦑIᫀ@+ndC1O2ḄLR■pCK)2ḄLRSTqW6ᑖ#XYᰦ[fgrH.(3)stuvᴻlxyḄzᵨ{■pC1O2⍎biCKhᐰ~C1O2Ḅ;ᦑIᫀ@+■pC1O2⍎biC1O2ᐰ~C1O2Ḅ;(4)ᐭ(ᨬ)᪗lUlᵫ⁐ា@⁐ᑖ
ᑁ⁐ᦑIᫀ@+lᵫ⁐@⁐ᙠ30sᑁ⁐W6ᓄ(5)VmLNa2s2O3lᨵNa2s2O3ᱥ;Ḅn(Na2s2()3)=V10-3Lxmol/L=c*V*103mol.j᪷ᐵ+C2C10G5I~lONa2s2O322210ᡠhn(CK)2'n(Na2s2()3)=LxcV103mol,ᡠhm(CK)2)=n(QO2)n(C10)c-V-10-3mol2•M=x.V*10Jmolx67.5g/mol=1.35cVx10-2g,ᦑIᫀ@+1.35cVxlO஺஺cூ௃⚪hP`ᐸᓄᔠᱥḄឋ;@ὃᱥ;Ḅ¡¢ឋ£¤¥`ᓄ=£¤¦§zஹḄᑨ©>ªஹᓄᙠuḄᵨ«¬⚪uḄ'(`*®¯°ᵨ@#IḄᐵ±஺26ஹ²³´µy¶·¸Fe+Cu2+=Cu+Fe2+CstuḄlm¹᎔»ᐭBst¼½¾¿ᑣªÀÁÂÃ⁐Äm{ᔲᨵg6ᡂூ᪆௃(1)£¤ÆÇ+Ã⁐ÄmÁÂÈᐰᑖ#Bstug.⏚²ᡂ⁐ᨵg6ᡂÉq)ᱥ;uᨵ´ஹᐗËCstuÌÍÎᮞgÐÑ6ᡂOᓄ³)ᱥ;uᨵ³ஹᐗ˲ᘤÓbÔḄÄmAstuÃ⁐Äm⌲Öᡂ×⁐ᑣ×⁐Äm)Ø{ᓄ²ÁᐭÙ.⏚.ÚÛᑮ×⁐Äm⌲Ö#lᡂ⁐×⁐Äm{ᓄ²Ämuᨵ²ஹᐗËᡠhÃ⁐Ämᱥ;uᨵ´ஹ³ஹஹ²ᦑIᫀ@²³´(2)জa{Ýᘤ@µybYÞᢝ8Äzᵨ@¶·¸ᦑIᫀ@µy¶·¸ঝᓄ²8.⏚6ᡂḄ⁐l@.⏚²láâÓã⁐läµyuåᐭ᪷æçḄ¶èÚÛᑮ¶è⊤☢ᨵë⁐ᱥ;᪆b{¶8.⏚²6ᡂḄ.⏚-¶8ë⁐Ḅ²ìí>?@+Fe+Cu2+=Fe2++CuᦑIᫀ@Fe+Cu2+=Fe2++Cuঞ■pï_uḄOᓄ³¾ÌÍÎᮞgð¤ñ☢6ᡂOᓄ³ḄòóᨬÁôõyᦑzᵨᔾᦈï_uḄOᓄ³Èᡂh᝞ùᐜ°û⏀ýþµyu_mÿ
Ḅ᎔ᔾᐭB஺ᦑᫀᔾᦈḄᓄᐜ⏀"#ᑣC%&᎔ᔾ'Bট᝞*+BஹC-./&01C23456789:;⁐=&>ᔲᨵAᡂᦑᫀ5C.

24VᑣWXYZ[\]⁐_`aᔲᨵ.1ᡂ஺ூef௃h⚪j⌕LᱥmḄnᡂᡂᑖopqḄrstu᪷wrsxyᑖ᪆z{|}ᱥmḄnᡂᡂᑖrs~+☢>L71⌕ὃ+Ḅஹᳮஹஹᵨὃᑖ᪆ஹLஹᙠḄF9}ஹ஺27ஹ¢£¤Ḅ¥¦ឋHC12Fe3++2I-=2Fe2++l3Fe2++2[Fe(CN)6]3-=Fe[Fe(CN)6]21Br1*¨©23CL"ᓄᡂBn,ªO«©Fe3+"ᓄB"MnCh+ZFeCbWHzOeFeiOj+MnCh+Cht+ZHCl+llHiOூ᪆௃(1)rs¬✌ᐜ⌕pqḄ¯°a¢£¤Ḅ¥¦ឋ&(2)FeCb6H2O±\ᜫ³ᨔ.P.1ᡂHC1¥`HC1,H2Oᔠµᡂ¶⏚·¸¹&(3)ᵫº»*+FeCba¼ᐳ½ᓄᔠᱥ±\¾¿⁐¥`ᓄÀᐹᨵÂ"ᓄឋ*¨ÃỚÅ"ᓄỚᓫm&(4)ᵨÀÇᓄÈɸ¢sFe2+Ë1Ì⁐ÍÎ&Ïп⁐¥`FᨵCL,◤⌕◀³Fe3+ḄÒ᡾ÔBL*¨©CL"ᓄᡂB஺ªO«©Fe3+"ᓄB஺*⌱ÖNaBrɸ&(5)×"ᓄ═ÙFeCb6H2O891ᡂFe2O3ஹMnCLஹCLஹHC1.wÚᔠÛឤÝᑏᓄ7:;஺ூß௃(1)rs¬✌ᐜ⌕pqḄ¯°a¢£¤Ḅ¥¦ឋ&ᦑ$ᫀ¢£¤Ḅ¥¦ឋ&(2)FeC13«6HO±\ᜫ³ᨔ.P.1ᡂHC1¥`HC1,H2Oᔠµᡂ¶⏚·¸¹oµᡂàá&ᦑ$2ᫀHC1(3)ỚÅᐹᨵâឋ,ᓄÀᐹᨵÂ"ᓄឋ,äὅ89,ỚÅ©"ᓄỚᓫm,89Å:;:2Fe3++2I-=2Fe2++I2,ᦑ$ᫀ2Fe3++2L=2Fe2++b;(4)ᵨÀÇᓄÈɸ¢sFe2+Ë1Ì⁐ÍÎÅ:;a3Fe2++2[Fe(CN)6]J=Fe3[Fe(CN)6]2LÏп⁐¥`FᨵCL,ÃåæBᑁKLÎèɸéᣚNaBrɸëBFìíᑮïðñ⁐ò.Ḅó⁐ᑣYZᨵᱥmôÃBr•"ᓄᡂB",ÀÅO"ᓄöÅë÷¢ᑮFe2+,ᑣYZaCL"ᓄḄBiSoOaFe3+,ᦑ$ᫀ3Fe?++2[Fe(CN)6]^=Fe[Fe(CN)6]2lBL*¨©CL"ᓄᡂBn,ªO«©Fe3+"ᓄB33(5)×"ᓄ═ÙFeCb6H2O891ᡂFe2f)3ஹMnCLஹCLஹHC1.89:;MnO+2FeCly6H2OA2FeaOj+MnCh+Cht+ZHCl+llHiO,ᦑ$ᫀMnO+2FeCly6HOAFezCh+MnCL+CLT+ZHCl+UHzO஺22ᜫF4%28ஹ122Aû3+2S©2+4HC1=A4+2sMi4+2H2stAs2s3ᓄᡈ⏚Gᑮ4e-

25lOmolI᩽ூ᪆௃(1)᪷LMNᱥPAᡂᱥQAs2s3PSnCLᙠS⏚MNUᓄAs4s4PSnCLVW3H2s&XYG3ᓄZ[\]Q2As2s3+2SnCh+4HCI=As4s4+2SnC14+2H2STᦑAs2s3PHC1Ḅᱥ^Ḅ_`a12᪷LᵯcGᜫdឤf2moiAs2s3gᓄᑺGᑮ4molᵯci2moiSnCLgjkᑺᜫF4molᵯcᵨmn᫑p᪗3ᵯcUrᜫ46II2A3+2SI€1+4HCI=As4s4+aSk'+2""$2I__________J%ᑮ4e-(2)MNAsᐗtᓄᔠv
As2s3ᓄᑺMNwAḄ&H2s⏚ឋ&Xᵨyᓄz{%ᡈ}⏚~{%ᔾᦈ(3)ᵫMNAs2s3+10H++10NOX2113AsO4+3S+10NCM+2H2஺XfAsSgjkᑺUrᵯcᦪ2x(5-3)+3x(0+2)=10,ᑣAᡂ2mOIH3ASO4MNUrᵯcḄᱥ^Ḅ_10mo1,kᵯI᩽AjkMNᑣᐗtḄᓄᔠv
ᵫMNXfNᐗtḄᓄᔠvᵫ+5
ᑮ+4,ᑣN(hjkwᱥᙠI᩽Aᡂ஺429ஹ+247.1ᓣV—MgOᩩᔠᡂw᳛HI10.2mol/(L•min)9ூ᪆௃(1)L8g(2)CH4(g)+CO2(g)=^2CO(g)+2H2(g)MNᔾ:L᜜.ᓄZMN᳛ᓄZ⊝Ḅᔠᩭᑖ᪆¢ᔠ⊤¤ᦪLLᓣ.ᱥ^&¥ᑖᦪḄᦔ*ᑨ¨©ᑭᵨᵬ¬COḄ⊝&¥ᑖᦪ®¯°3UᓄḄᵬ¬Ḅᱥ^Ḅ_ᑡ3²³]᪷L⊝´ᦪḄ⊤µ]¯°¶(3)L⊤¤ᦪL⌱¸ᔠᡂCOPy_ᨬºḄᱥ^g»&(4)᪷LP¼.⊝Ḅ¢ᔠ⊝½᝱ḄᱯÀÁ(5)¢ᔠ⊤¤²ÂᦪÃᑡ3²Ä[\¶[\ÂᓽXÆ3nḄéᑡ3²³]ᑖÇÆ3c(CO)c(hh)ḄÃ,2ᐭ0]ÆGvI஺ூ௃(1)জCH4(g)+H2O(g)^^CO(g)+3H2(g)AHi=+205.9kJ-moF1(2)CO(g)+HO(g)^^CO2(g)+H(g)H=-41.2kJ-moF1222জ-ঝXGᑮCH4(g)+CO2(g)=^2CO(g)+2H2(g),ᑣ᪷L8XfH=+205.9kJmoÌ-(Î41.2kJmoÌi)=+247.1kJ-moF1,ÏMNᔾ:MN⌕ÑÒÏMNµᑮ⊝ḄÓVÔ3Ḅw᳛XÕÖḄ×Øᓣᦑᫀ+247.1ᓣ(2)ÙÎÄᱥ^ᙠ5ÙḄᡠᓰḄ&¥ᑖᦪ5ÙCH4(g)+CO2(g)^^2CO(g)+2H(g)H=+247.1kJ-moF1,2

26)*+,ᔾ.*+/ᑣᓣ234ᑣᨵᑭᵨ8⊝ᔣ;*+<ᔣ=>/?@CHaḄBCᑖᦪFG/COḄBCᑖᦪᓣ2஺IJb>a>c,᪷LM⊤OPQJ/TI/ᑁ_ᓄḄ2/P3/_ᓄinḄ"n2/ᦑᑮ8⊝/ᦑbᫀ,in(5)U1hc(CO)=0.24mol/L,c(H)=0.48mol/L,Y᳛v;=0.361mol/(L-min)ᑣL;_᝕;¢£஺)-©/!!?)2QJ/জ0.361mol/(L-min)=k;'(0.24mol/L)mx(0.48mol/L)11ᳮ/᪷L⊤ªᦪLQ%ঝ0.720mol/(L-min)=kix(0.24mol/L)mx(0.96moVL)nঞ0.719mol/(Lmin)=kiX(0.48mol/L)mx(0.48moVL)nᑣঝ/জQ%2=21ᓽn=lঞ/জ%2=2"\ᑣm=l¯ᐭজ%kiE=3.134L/miirmoL)34R8⊝CH4(g)+CC)2(g)=^2CO(g)+2H2(g),±1Ḅs᳛,25%,UVᓄḄCH4Ḅᱥ³ḄW4,ymol/L,´µ|CH(g)WO(g)^^2CO(g)+2H()422gXYW4(mol/L)0.240.4800VᓄW4(mol/L)yy2y2y8⊝W4(mol/L)0.24-y0.48-y2y2yᑣ”---$-TTTAO-----X-n------=25%,ᑣy=0.12,´1|c(CO)=2y=0.24mol/L,c(H2)=2y=0.24mol/L,k;S3(0.24-y)+(0.48-y)+2y+2y4ᨵᐵḄ᳛^ᦪ/¹ᢝ}»/ᑣL¼½¾Q%v;=1;¿(0)«112)=3.1341/min«molx0.24mol/I^x0.24mol/L=0.180~0.2mol/(Lmin),ᦑbᫀ,10.2mol/(L*min)o