上海市某大学第二附属中学2021-2022学年高一下学期期末线上测试化学试卷（解析版）

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ᜧ▬2021-2022ᓄ⚪
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CuSCU?@ᓄB@ᡂḄD▬ḼᙠZnGHᡠI▭KὑZnḄ#$ᜧ&Zn᩽LMḄ#$D⚗1NOᫀD஺17.ᨬSᡃUVẆXᕒẆ?Z[ᐙᵯḄ“Na-CO?”ᵯ;ᨵᑭ&I_`aᡊᶍᐸᵯ;᝞fg4Na+3c஺2hi±2Na2cO3+C,fᑡkl1NḄgA.mᵯ)CO2nᐭᵯ;Ḅ0᩽B.ᐙᵯ)Na.ᙠ▢᩽?@C!C.ᵨNaClC84qrᵯs#D.᪗uf2.24LC஺vwx70.4NAyᵯ"ூOᫀ௃Bூs᪆௃ூᑖ᪆௃᪷ᵯ;mᵯ)gᜫᵯ"?@ᓄ!ᵯ;Ḅ0᩽ᑣᓄ`1᩽s⚪஺ூs௃A.ᵫᑖ᪆CO?nᐭᵯ;Ḅ1᩽A┯B.ᐙᵯ)6"ᑮᵯ"ᓫ#ᦑᐙᵯ)Na.ᙠ▢᩽?@C!B1NC.ᨵwq?@ᵨqrᵯs#C┯04D.᪷38294e,ᑣ᪗uf2.24LCO2wx7NAyᵯ"D┯3ᦑ⌱Bo18.ᨵHCO:ஹSOஹCO:ஹCH3coe4[▢6"஺ᔣᐸ-ᐭ$ḄNazCh+6"ᢝḄ¢Ꮇ¤¥¦ᓄ§A.CH3coeB.SO:C.CO:D.HCOூOᫀ௃Aூs᪆௃ூᑖ᪆௃ᔣ-ᐭ$Ḅ¨ᓄ¨ᓄq@ᡂ©ᓄaªᑖ᪆s⚪஺ூs௃A.CH3coO-©᪷6"aªᙳ6"ᢝA⚗ᔠ⚪¯B.@ᡂḄª°⏚᪷?@ᓄC!@ᡂ⏚᪷°⏚᪷6"LMB⚗ᔠ⚪jic.M

8C.@ᡂḄ©᪷6"`⏚©᪷6"@ᡂ`⏚᪷aq`⏚᪷6",ᜧC⚗ᔠ⚪¯D.@ᡂḄ©᪷6"`⏚©᪷6"@ᡂ`⏚᪷aq`⏚©᪷6"LMD⚗ᔠ⚪¯Oᫀ⌱A஺19.±gmX(g)+nY(?)=pQ(s)+2mZ(g),±±²³⊝)c(X)=0.3mol/L,ᐸµᩩ·¸¹ᘤ»¼ᑮ!ᩭḄc(X)=0.7mol/L,fᑡkl1NḄA.¾ᦪn>mB.ᔣ⌮ᔣ72m,ᑣn>m,ᦑA1NB.±²³⊝)c(X)=0.3moi/L,ᐸµᩩ·¸¹ᘤ»¼ᑮ!ᩭḄ᝞ÂᓄB³⊝7<c(X)=0.6mol/L,ÃI▭ÄŲᑮ³⊝)c(X)=0.7mol/L,kÆ-Ç+ᓄB³⊝⌮ᔣ7<ᦑB┯C.Êᔠ⚪¯1ª¥LMḄ᝞ÂYᡈᑣËÌÉm>2m,ÍᯠᡂÏᡠYЪᦑC┯D.᪷ᑖ᪆ᓄB³⊝ᔣÑ7<ZḄ¥ᑖᦪ,ᜧḄᦑD┯Oᫀ⌱A஺20.A+B—C(AH<0)ᑖÒÓÔÕgজA+B-X(AH>0)ঝX—C(AH<0)஺fᑡد1N⊤ب$ᓄḄA.¨¨

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10(3)জ.Ch+4e-+2H2O=4OH-ঝ.aூZ᪆௃ூ\]1^Z௃ᵯ_`abḄᵯ᩽c᩽ᵫefghabᦑAc᩽hcB᩽jB᩽klm#$ᵯ᩽#$Cu2++2e=Cu,ᦑNᫀ=᩽jCu2++2e=Cujூ\]2^Z௃Cu+2Fe3+=Cu2++2Fe2+ᡂ᝞+ᡠḄᵯA#$_Cukl0ᓄ#$8ᵯḄ᩽ᡠ4AᩞᧇoCu,B᩽ᩞᧇogCupabḄqᵯᱥs᝞tuஹAgxᓽ3>?C_zᨵFe3+,᝞FeCh>?B᩽ᵯ᩽#$Fe3++e=Fe2+jᦑNᫀ=CujFe3++e=Fe2+jூ\]3^Z௃᪷|3}a᩽bB᩽ᙠឋ/01ᧇᵯ_/ᙠ᩽(a)+ᵯ=2H2-4e-+4OH=4HO,0ᙠB᩽(b)+ᵯ=O2+4e-+2H2O=4OH,C8D/0᪷ᔣ᩽(a)JKᦑNᫀ=஺2+42+2HO=4OH-ja஺222.ᡂ9ᑡ]⚪(1)ᜩᯠo&.⌕ᡂᑖᵬ(CHQ,}ᙠlOlkPaஹ273KD1gᵬ1lᡂCO2?᝱55.6kJḄ¢£ᑣᵬ1¢Ḅ¢ᓄ¤¥¦%______o(2)©ª9Al(s)¬FeO(s)kl¢#$Ḅ¥¦%_______,®lᡂ8.4gFe(s)Ḅ¢£kJ(°ᶇ&²\ᦪ)஺}=Fe(s)+^O(g)=FeO(s)AH=—272.0KJ.mo´232A1(S)+-O(S)=A1O(S)AH=-1675.7KJ-'mor'ூNᫀ௃(1)223CH(g)+2O(g)=CO(g)+2HO(g)AH=-889.6kJ/mol4222(2)জ.2Al(s)+3FeO(s)=AlO(s)+3Fe(s)AH=-859.7kJ/mol42,923ூZ᪆௃ூ\]1^Z௃}ᙠlOlkPaஹ273KD1gᵬ1lᡂCO2?᝱55.6kJḄ¢£ᵬḄ1¢o55.6xl6=889.6kJ/mol,⊤ᵬ1¢Ḅ¢ᓄ¤¥¦%=CH(g)+2O(g)=CO(g)+2HO(g)AH=-889.6kJ/molj4222ூ\]2^Z௃

1113জFe(s)+eC>2(g)=FeO(s)AH=-272.0KJ-moP1.ঝ2Al(s)+5026)=·203(5)AH=-1675.7KJ'.mor1.¸|¹º»¼ঝ-জx3½¾U:2Al(s)+3FeO(s)=AlO,(s)+3Fe(s)AH=-859.7kJ/mol,᪷|A¢ᓄ¤¥¦%3}ᓽlᡂ3moi¿284g¢859.7kJ¢£À8.4gFe(s)ḄᱥsḄ£11==^~~-=0.15mol,ᑣlᡂ8.4g¿D¢56g/mol0597klx0.15mol=42.985kJ,ᦑNᫀ=2Al(s)+3FeO(s)=A12C)3(s)+3Fe(s)AH=-859.7kJ/mol3mol42.9஺23.ᙠ&»ªÁ9Â2molA4molBᙠ2LÃÄÅᘤ_ÇᔠÉkl#$=A(g)+2B(g)=3C(g)+D(s),AH>OoÊË2minÌÍᑮÏ⊝ѽCḄÏ⊝ÒÁ0.6mol/L,ÓN9ᑡ]⚪=(1)ᵨᱥsA⊤Ḅ#$Ô᳛஺(2)2minDᱥsBḄÒÁBḄÏ⊝Öᓄ᳛-ߟ஺(3)Ø9ᑡÙÚ⚗pÜklÝᓄD⊤Þ+ß#$ÍᑮÏ⊝à᝱oA.ÇᔠḄáâB.ÇᔠḄÃÁC.ᓫ²DãᑁåὑImolBçDlᡂ1.5molCD.ÇᔠḄèᱥsḄ£E.ÇᔠḄÏᙳêëᑖs£F.ᵨAஹBஹC⊤ḄÔ᳛g1:2:3(4)ì©AÖᓄ᳛34íîḄïðᨵ_஺(5)°ᢝªÁஹòpÝÜᔣÅᘤ_ᐙᐭ2molA4molBõöÍᑮÏ⊝ᑣCḄÏ⊝ÒÁ_______(÷>ஹ=§K<)1.2mol/LoூNᫀ௃(1)O.lmobL-^min1(2)জ.ঝ.20%(3)BE(4)জ.ᓣ©ªÁঝ.úᜧBḄÒÁ(5)=ூZ᪆௃ூ\]I^Z௃Ï⊝DCḄᱥsḄ£0.6mol+Lüx2L=1.2mol,

12A(g)+2B(g)U3c3)+D(s)ýþ£/mol2400/AஹAn0.4mol_n..dvvv'■Öᓄ£/mol0.40.81.20.41VAt2Lx2min⊝/mol1.63.21.20.4ᦑᫀ0.1mol«L1«min1ூ2௃ᵫপ2minᱥBḄc(B)=2=—^=L6mol/L,BḄ⊝!ᓄ᳛V2L$n(B)0.8mola(B)=—ᐶxlOO%=Jxl00%=20%,ᦑᫀ1.6mol-L“20%n(B)4mol0ூ3௃A.'()*+,,-./0ᔠ+,Ḅ23ᙠ'(567⊝8᝱:;<./ᦑA┯>B.'()*+,,-./?@/ᓄ0ᔠ+,ḄA./BC'(Dᑮ⊝8᝱ᦑBFGC.ᵫH6IὑImolBKL@ᡂ1.5molC,N'(OPḄ6QᐵᦑC┯>D.'()*+,,-./'(56+,SᱥḄT./ᡠV.WBC'(Dᑮ⊝ᦑD┯>E.'(56+,ᙠ/SᱥḄ./ᡠV0ᔠ+,ḄᙳYZᑖ\.]/ᓄWBC'(Dᑮ⊝ᦑEFGF.ᵨAஹBஹC⊤aḄb᳛c123,d⌕'(?@fᨵb᳛hc123,N'(OPḄ6QᐵᦑF┯>ᦑᫀBEூ4௃ijAḄ!ᓄ᳛VᓣjlᡈnᜧBḄp'(FᔣOPᦑᫀᓣjlnᜧBḄ;5௃sl:Ḅᓄt⊝uᦪK=/\ஹ2/y=----,]ᐙᐭᐙᐭ2molA74molB+,C(AW(B)(ߟ)x(—)225622A(g)+2B—-k-3Cg)-D(s)(g);/mol3.67.21.20.4AḄ/ᓄxmol,....,Dᑮ⊝,!ᓄ/molX2x3xX⊝/mol3.6-x7.2-2x1.2+3x0.4+x

1312+3X\3c3(C)(227K=/ஹ'2/Q===—==x=0.4molCḄ⊝c(A)-c-(B)(3.6-X)X(7.2-2X)2256c=—=(L2+3x0-4)mo1j2mol/L,ᦑᫀ=஺=V2L24.¡¢£¤¥ஹ¦ஹ§ᔠ¨©ᧇḄ]ᑭᵨ¬Kt®Ḅ¯ᦈᑭᵨHᫀ᝞::³´BḄµ⌕ᡂᑖ¶·FḄµ⌕ᡂᑖ஺(2)¹º³·D¼ᔲ¤ᨵFe"ḄHÀ஺(3)Á³·DᑮÂÃᨔ,ÅOPḄÆÇஹஹ5³ÈÉஹÊË஺(4)ÌᑺYW஺A.NOB.OC.SOD.H0,222NTÓᵨÔ⏚NE'(ᑴᜓC11SO4YcᵨÙÔ⏚7ÌᑺYÚÛᔠ“Â⁐ᓄt”Ḅ⌕ß,àá¼(5)â+,XCO2,ãᑏ哳·A”N5+,X'(Ḅæ\H6஺ூᫀ௃(1)জ.CuஹFeঝ.AlCb(2)ë춷NÌíîᐭKSCN¶·,,ᑣ¤Fe"(3)জ.ñ?òঝ.óᓾõᨔ(4)জ.Dঝ..ö÷@øùᓄÔঞ.ÙÔ⏚Ḅῖ⇨ឋcÔ⏚Úîþᐰ(5)A10+2HO+CO=A1(OH)31+HCO22ூ᪆௃ூᑖ᪆௃ᔠA1NaOH!"ᡂ$ឋḄNaAlCh,CuFe,-NaOH.!/ᡠ12A3ᨵNaAlCh,25B7CuFe,B89⏚;ᔠ/Fe89⏚!"ᡂFeSCU,Cu89⏚.

14!/ᡠ125E7Cu,D3ᨵFeSCU,Cu89⏚ஹAᑺY"ᡂ9⏚D/Y7EFᓄᑺ/H.IJKLḄᩖN/OH2O2,NaAlChC02!"ᡂA1(OH)3,ᡠ1C7A1(OH)3,Al(OHO8P⏚!"ᡂAlCh,F3ᨵAICI3,1Rᩭ᪆஺ூUV1W௃ᵫ1Yᑖ᪆$Z25B3ᨵCuஹFe,F3ᨵAlCbூUV2W௃$ᵨKSCN^_`ab/O⁐/^_2D7ᔲ3ᨵFe3+ḄefOghij-Ak/lᐭKSCN//ᑣ3Fe3+ூUV3W௃oẆ3ᨵqᨔs/ᦑ⌕v2Dwᑮoyᨔz/{|K}Ḅ~_gஹᓾqᨔஹ2ஹூUV4W௃Cu89⏚ஹAᑺY"ᡂ9⏚D/Y7EFᓄᑺ/H.IJKLḄᩖN/OH2O2ᦑ⌱D89⏚Hz஺ᑴᜓ9⏚D/."Fᓄ9/᜜89⏚Ḅῖ⇨ឋ9⏚U/lᐰ/ᦑᫀOg."Fᓄ989⏚Ḅῖ⇨ឋ9⏚U/lᐰூUV5W௃⏚¡jFᓄ¢!"ᡂ£Fᓄ¢⏚£¡/!Ḅabe¤¥OgA10-+2HO+CO2=A1(OH)31+HCO„225.ᔠᡂ©ª«¬®¯°±²ᐹᨵ´⌕Ḅµ¶/ᐸ¸ᳮOgN+3H^2NH,ᙠz¼O2L223Ḅ¾ᘤ/ᙠ.ÀÁÂஹÃEÄÀÅᓄᑺᩩÇÈ/ᐙᐭN?ஹËᑖÌOO.hnolஹ0.3molÐ/Ñ⊝Ó;ᔠT/࠷Ô1ÈV⚪:

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16VA£N2¤VB£N2¤tூxy4zv௃A.᪷¦§¨ᓄ-./0᳛Ḅ©ªLᢣ᪵ᙠᑁLᦑA*+tB.«ᔠ§¨ᓄ-S⊝Ḅ©ªL¬ᵨᔠ〉Ḅ᜜¯ᩩJLS⊝ᔣ*./'ᔣghL#$᳛LᦑB*+tC.ᓄᑺ§¨./0᳛L°±§¨ᓄ-S⊝L±²ᦋ´Lµ²¶·ᑮQS⊝Lᑣ¸(#$᳛LᦑC┯ºtD.*+ᑭᵨᓄ-./0᳛L⌱¼b2LᙠḄ./0᳛Ḅ½#KL¾¿ᓄᑺÀឋᨬᜧL#$ᓄ67Ḅ8ᔠ:;ᦔ