2022届高考化学模拟演练卷 全国乙卷

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2022
ὃᓄᔁᐰᔁᵨᑮḄH-lLi-7C-12N-140-16ஹ⌱⚪⚪ᐳ7!⚪"#!⚪6ᑖ஺ᐳ42ᑖ"ᙠ#!⚪'(Ḅ)⌱⚗+",ᨵ⚗./ᔠ⚪1⌕3Ḅ஺7.“789:”ᓅ=ᜧᐶ▭ABḄCD+"ᓄᩞᧇGᢵIJᜧKᵨ஺LᑡᨵᐵOPQRḄ.STA.ᡠᵨVA
WCXᵨYZ[\]^A_`ZᩞᧇB.ᡠᵨabcḄd⌕ᡂᑖZ[ᨵA
ᑖᩞᧇC.ᡠᵨf☘hij+Ḅf☘kl◀noḄpḄqrᱥD.ᡠᵨ◞◫vwx+Ḅvw.yz{|Ḅ}ᱥ8.~⏚ᵬ■◭ᑺ◭"kDMF஺DMFᨵ"ᨵῖ⇨ឋឋ"ᙠk_ᵨᱥ"ᙠSᒹ¡☢ᑴT+¤ᵨ஺ᨵᐵDMFLᑡOP┯¦Ḅ.STA.DMFᑖ§kCgHQ4B.DMFᑖ+ᡠᨵ¨ᐳ©☢C.DMFªGryᡂ{|«Gr¬{|D.lmolDMF®ᐰ¯°±²4molNa{|9.³´µ¶²·´¸᪆.ᓄº᪶¼½¾¿஺LᑡᱥឋÀÁ|{|ḄᓄÂ:§ÃᑏQRḄ.STA.ᔣ2moi/LKkmLNaAlO?ÆÇ+Èᐭ᪗ËÌÍL2.24LCOÎ2A10,+C0+2H,O=A1OH
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1ÞCu2++2Cf+Cu+2HC1(?^)—2[CuCl]+2H*:D.ßᱥḄFe(SO),Ba(OH),HNO,ÆÇhᔠ243Fe?++3SO+4OH+3Ba?*+H*=Fe(OHbJ+3BaSO&J+HQ10.àáâᑭᵨ᝞åæçᑴᜓéêëஹìíḄîÎ"Lᑡᑖ᪆QRḄ.()A.X.MnO,B.æçYᵨ[ᔾᦈ¯óÎC.æçD+bô|õöÓ÷øùúD.ûᝅæçýþÿᔾᦈ11.ᰚᑺᢣᱥḄᓄஹᰚᓄᡈᓄḄᱥ஺ᓄᔠᱥQᵨஹᔠ!"#ᰚᑺ$%᪀᝞(ᡠ*$XஹYஹZஹW+,-.ᦪ012ᜧḄ45ᐗ7$ᨬ᜜:ᵯ-ᦪᙳ+᜻ᦪ>-ᦪ?+22஺@ᑡBC┯EḄF()rxx1\/Z/\/\.XX.LwwJA.,-KLᜧMNY>Z>W>XB.ZḄTᓄᱥUVWḄTᓄᱥWXC.YW3OḄ,-ᙳPᑮ8ᵯ-RS%᪀D.NaYXFYZᵨ[,ᑺ412.Y\]ᵯ^_`a┞Ḅc,ᳮ᝞(ᡠ*$Oefgᵯ᩽ᩞᧇ(LiMnO/Li,^MnO)ᐹᨵ⌱nឋᵯᓄpᔾ▬/ῃs┞t-u஺cvwUᑖ+yz,2424|z+⌱nឋᔾ▬┞$|}z+~┞$vyzḄᵯ^vw$┞t-ᨬLiOHḄᑮ▢᩽f஺@ᑡO┯EḄF()

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⏚FeP204⏚NaClO,1t|I᯼.ᡈl▼12P2O4௃åæNজà᯼Ḅ4⌕ᡂᑖéêë᝞⊤ᡠ*ᱥV2O3vo2SiO2CaCO3FeS2A12O3êë/%3
42
355-6522
282
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3
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4
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ᑴ᳛ஹTUo〉dஹᓄᑺḄᨬ〉b஺3
ᵫ1ᐵᱥឋ4=ᱥFGᨴ☘ᜧ+ᦑᑖo=>ᙠᔠ$஺ᑖoḄᐹ$\]ᑖᧅ'ᙠᙌ/☟*ஹ+ᑖm,☢ᨎᯠᡭᑖᧅ!ᡭ"#$%ᑖᧅ&'()*ஹ+,☢."/01ᑗᓽ4ᐵ6"7/$%ᑖᧅ/0᎔(஺4
n+CaC"⚩ᐹᨵḄᔾ+ឋ4];<ᑺᔣ+^Ḅ=ᱥden+CaCl?⚩4◀¡ᨵ@=ᱥdḄ+ᑖv;<Ḅ]ᵨ஺5
ᙠ¢£^_d¤¥¢£FG¦§¨2335C,◤ᦈª233c«¬ḄᑖeC®¯°¥¢±o²◤ᦈª1157250cᑖᓽ4³ᑮ=>eCL´µ☢L¶ᐰ¸´µ☢ᨵ@ᱥ´¹BC᧕ᑖEeC®#³ᦈªᑮḄ=ᱥFGHIJ=᳛KL஺49஺x30%6
25.3g0.2mol
ºᓄ».NaCN¼´^=0.3mol
kᡂFGῖḄᳮÂ=Ã49gmolT▭=Ã223஺0.2mol23.4g
,ᦑ=᳛=x100%=x100%=95.3%஺ᳮÅ=Ã23.4g

1328.ÇᫀNI.(1)C0(g)+3H,(g)=CH,OH(l)+HO(g)AW=-86.9kJ/mol(2ᑖ)220.0835x—"|xf0.08353.34)I3.34J(2)44%(2ᑖ)2ᑖ0Q835XÊx(0Q835xÌ3
ঝট2ᑖII.4
1201ᑖ1.5Iᑖ5h=᳛ÏЮÑḼÓᑮÔ⊝oz´Ö×Ø6hPC=᳛pqÙᢝgÛ¯ÜÝek=ᡂO³gÞᜫᔠᳮᓽ4³ᑖ2ᑖᡂOLnànánâã|äᑭᵨ᳛Ó100%1ᑖ5
ᜧædCO,ᣓèéIᓄᡈᜧædCO2ḄêªᡈCO,®ᦔḄᔾ▬ᢈîWᔾ▬ᩞᧇᡈὅCO2òᓄḄᩩôõöbÇᫀᔠᳮᑏ´øᓽ41ᑖE᪆N1᪷ú⚪ûᑏ(üæஹᵬ⏣ḄþÿḄᓄজH2g
+C2g=H2஺প஻=-285.8kJ/molஹ3ঝCH,OH(1)+-O(g)=CO(g)+2H,O(1)AH=-726.5kJ/mol22ঞHQ(g)=HQপAH=-44kJ-mor'᪷3xজ-ঝ-ঞ0COg
+3Hg
=CH,OHl
+H,Og
\H=-86.9kJ/mol22o2
᪷ᘤᑁḄ#$P%&'#$(Ḅ)*᪷+,-./0ᐸ234⊝67=0஺35,9&'-ᐭamolCO2;3.஺1<4⊝6=ᡂxmolC2H4⚪@PoᑡBC2C0,(g)+6H,(g)^=iCH(g)+4H,0(g)24&'(mol)a3a00DE(mol)2x6xx4x4⊝(mol)a-2x3஺-6xx4x

144஻F3JC——44%4⊝6=0.835,mx=0.22aḄG᳛=஺IX=0.22஽KᐭBC,4a-ᓽ2CO(g)+6H(g)ஹ_C2Hg)+4H,O(g)22&'(mol)a3a00DE(mol)0.44஺1.32஺0.22a0.88஺4⊝(mol)0.56஺1.68஻0.22a0.88஺DE4⊝OḄ#$PSTo”஺88UVT஺”0.22A0.0835x---x0.0835xF_/(HO)xp(CH)_(3.34)[3.34)224=0.1MPax0.835=0.0835MPa,Kpp6(H)xp2(CO)-|'nnmv1-68?0.56?220.0835x-----x0.0835x-----1ஹ3.34)13.34(3)Xᑮ4⊝6%=”,[ᢝ]^ᦑজ]`4⊝a᝱ᵫdDE`ᔾDEᙠghijklmn4⊝⌮ᔣqrKstuK]^6ᓽkl]^DEXᑮ4⊝,ᦑঝvᑨxঞyḼDE{ᔣ|}஻(CO?)st”(CO)~-DEjὅḄ^ᓄ)E`1:1,jḄ^ᓄ)P2:1,]ᔠ⚪@]ᑨxটMCOJ⌲st,ᨬO]^vᑨxDEXᑮ4⊝ঠDE`ᔾDEᙠghij{ᔣ|}klE`ᐜmnO]^vᑨxDEXᑮ4⊝ডDE`*]ᑨx⌮DE`ᔲXᑮ4⊝a᝱ᦑঝট஺(4)ᵫBஹCklP120࠷ஹ#$P1.5MPa6G᳛ᑮX᝞ᓣkᡈ-#ᡂ~ᜧ¡¢£G᳛¤¥]^ᵫD¦§ᑮ5hG᳛¨¡©yḼDEXᑮ4⊝IDE6ª|F«¬®6hOPCG᳛¤¥[ᢝ]^D¯°~-=Gᡂ]±ᜫ஺³DE`ᓄᔠDEGᱥḄµ¶ᑭᵨ᳛Xᑮ100%,DEᱥCO2`¹º»¼ᡂnDE½¾¿¾ÀÁ஺(5)ᜧ¼jCC)2Âᦈᑭᵨ6ÄᙠḼÅᜧÆlnḄÇ⚪ÈÉÊËÌÍᓄÎÏᙢᑭᵨ஺35.Òᫀ(1)3d84sঝ(1ᑖ)ÕÖᕜØÕVHBÙ(1ᑖ)(2)C(1ᑖ)CḄᵯÛឋ)OtCµ¶ÝÞßᵯ¶àḄáᔣÎᜧÎ᧕ãᡂäåæ(1

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