高考总复习化学（人教版）高考总复习化学（人教版）培优训练1

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1:ᦪ⚗1.2018•Ẇ8
SO2ᔲᑮ᣸᪗"Ḅ$%&ᳮSO2+H2O+BaCh=BaSO4I+2HCLNA⊤)ᦪḄ*+ᑡ-.2/0Ḅ12A.0.1molBaChᨔ45ᡠ789ᦪ:0.1/VAB.25࠷;pH=lḄHC1<=5ᨵH+Ḅᦪ?:O.INAC.17gH2O25ᨵ@᩽ឋCᦪ?:0.5NAD.ᡂ2.33gBaSOEF;GHᵯJᦪ?:0.0INA4K᪆BaCbᨔ4ᵫNOJPQOJ᪀ᡂᦑ0.1molBaCLᨔ45ᡠ789ᦪ:0.3NA,A⚗┯UVWᨵXY<=4Z[.\]H+Ḅᦪ?B⚗┯UVH2O2H/
—0/Ḅ^᪀_:H,17gH2O2:0.5mol,ᨵ@᩽ឋCḄᦪ?:0.5NA,C⚗/0V᪷a$%SO+H2O+BaC12=BaSO4I+2HC1,ᡂ2.3322g0.01mol
BaSO4EF;GHᵯJᦪ?:0.02NA,D⚗┯U஺dᫀC2.2018•fgḐij᪥ὶmὶὃ5
oNA⊤)ᦪḄ*஺+ᑡpq┯UḄ12A.18gℍ⃔tᑖJ5vwxᦪ?:0.6NAB.ᨵ0.1molNHlḄyz5ᨵOITḄᦪ?ᜧ|O.INAC.}+5.6gFe~0.2molHNO3Ḅ<=ᐙᑖᵨᨬGHḄᵯJᦪ:0.15NAD.}+1LpH=9ḄCH3coONa<=5ᵯOḄzᑖJᦪ:1XIO^A^AK᪆1ℍ⃔tᑖJ5ᨵ5P118gℍ⃔t:0mol,ᑖJ5vwxᦪ?:0.6NA,A⚗/0Vᨵ0.1molNHIḄyz5ᵫNH."HzOᵯOḄNHPOHḄᦪ?ᔜ:O.INA,yz5zᵯOOH,ᦑᨵOHḄᦪ?ᜧ|O.INA,B⚗/0V⏚Ḅ}+ᙠHNO35ᓄC⚗┯UV}+1LpH=9ḄCH3coONa<=5OHᵫzᵯOᐸᦪ

1?:1X10-5NA,ᦑᵯOḄzᑖJᦪ:IXIO-NA,D⚗/0஺dᫀC3.NA:ᦪḄ*஺+ᑡ-./0Ḅ()A.4molHC1Ḅ®⏚~¯MnOᙠ´ᩩ¶+$%ᡂChḄᑖJᦪ:NA2B.ᔣ1LO.lmol-L1Qᓄ᪶<=5ᐭy½⁚<=:5ឋᑣNHÀḄᦪ?:O.INAC.ᔣ1L1mol-L-1FeBn<=5ᐭ¯Q½GHḄᵯJᦪ:3NAD.ÃÄÅᘤ51molN2~3molH2ᙠYᩩ¶+ᐙᑖ$%ᡂḄNH3ᑖJᦪ:2NAK᪆®⏚~MnCh$%ÈÉ5®⏚⌲ËÌÍ4molHClÎwÏᐰ$%ᡂḄC12ᑖJᦪÍ|NA,A⚗┯UV᪷aᵯ₹Òឤc(NH3)+c(H+)=c(CF)+c(OH),<=ᕈ5ឋᑣc(NH4)=c(Cr)=0.1moll-,NHÀḄᦪ?:0.1/VA,B⚗/0V¯Q½ÙÚÛÜᓄBr,ÚÛÜᓄFe2+,ÝÚÛ~zÜᓄÝ&$%ᦑGHḄᵯJᦪᜧ|3NA,C⚗┯UVN2~H2ᡂNH3Ḅ$%:Ú⌮$%ᦑ1molN2~3moiH2$%ᡂḄNH3ḄᱥáḄÍ|2mol,D⚗┯U஺dᫀB4.(2019•ã&ä)oNA:ᦪḄ*஺+ᑡ-.┯UḄ()A.}å+4gD2O5ᨵḄᵯJᦪ:2NAB.42gC2H4PC4H8Ḅèᔠ½5ᨵê&Jᦪ:6NAC.25࠷;pH=lḄH3P04<=5ᨵîᦪ:O.INAD.H20(g)ÈNa2O2(s)ñᐸòó8g;$%5GHḄᵯJᦪ:WVA/2K᪆DzO5ᨵḄᵯJᦪ:10,4gD2OḄᱥáḄ:0.2mol,ᐸ5ᨵḄᵯJᦪ:10X0.2NA=2NA,A⚗/0VC2H4PC4H8Ḅᨬõ_ᙳ:CH2,42gC2H4PC4H8Ḅèᔠᱥ53moicH2,ᐸ5ᡠê&Jᦪ:6NA,B⚗/0VWᨵXH3P04<=Ḅ4Z[.\]H+ᦪ?C⚗┯UV᪷a2Na2Ch+2H2O=4NaOH+02tNazChòó4g;ᡂ1mol஺2,GH2moiᵯJᑣ$%øù4áò஺g;GHᵯJᦪ:úVA/2,D⚗/0஺dᫀC

25.(2019•ûᓭH11ᦟþὶmὶὃ6)oNA:ᦪḄ*+ᑡᨵᐵ
Ḅ()A.2.0gHi8O2.0gD2OᡠḄᦪᙳNAB.14gᑖC"H2"ḄᨵḄᦪNA/஻C.lOOgᑖᦪ17%ḄH2O2ᦪNAD.!"#$%56g&ᱏᢗᐭᑮ+Ḅ,-⏚/ᡂSOḄᑖᦪL5NA23᪆2.0gH^OᡠḄᦪ,4.1X(18—8)NAmo6i=NA,2.0gD2Ozug-moi2()gᡠḄᦪcn,1)X2+(16—8)]NAmol7=NA,A⚗:14zug,moi14»1gᑖGHz”Ḅ;<ḄᱥḄ஺ᔆᨵḄᦪNA/஻>ᑖC„H2„Ḅ?@A;B$᝞DEF$ᑣHᨵ$B⚗┯J:KLMNᓄᙳᨵ$100gᑖᦪ17%ḄH2O2ᦪPQNA,C⚗┯J:!"#$&ᙠ,-⏚Tᓄ$D⚗┯J஺VᫀA6.Ῑ(N2H4)Z[!ᵨḄ]^Bᧇ$!"#`$ᐸᳫcde᝞fᡠg஺h^NKi/jklN2H4+2H2O2=N2t+4HOoᵨNA⊤gnopqr!2ᦪḄs$#ᑡuvḄ()A.᪗xyz#$11.2LN2ᵯ|ᦪ5NAB.᪗xyz#$22.4LN2H4ᡠ|ᦪ6NAC.᪗xyz#$3.2gN2H4ᨵᐳḄ|ᦪ0.6NAD./ᡂ3.6gH2O,ᑣ
jkᵯḄᦪ0.2NA3᪆1N2ᑖᨵ14ᵯ$᪗xyz#$11.2LN2ḄᱥḄ0.5mol,ᑣᡠᵯᦪ7NA,A⚗┯J:᪗xyz#`$22.4LN2H4ḄᱥḄᜧQ1mol,ᦑᡠᦪᜧQ6NA,B⚗┯J:1ᑖᨵ5ᐳ,3.2gN2H4ḄᱥḄ0.1mol,ᑣᡠᐳḄᦪ0.5NA,C⚗┯J:jkN2H4+2H2O2=N2t+4H2஺$/ᡂ4molH2஺4moiᵯ$ᦑ/ᡂ3.6g(ᓽ0.2mol)H2஺$ᵯḄᦪ0.2NA,D⚗஺

3VᫀD7.2018•ᓭ$8NAnopqr!ᦪḄs$#ᑡuvḄA.20gD2OᨵḄᦪ8NAB.3.36LNO2+ḄKᐙᑖjk¥$/ᡂ0.05NANOᑖC.lmol⏚ªL⏚ªḄ«ᔠᱥ⏚᪷®ḄᦪNAD.3molᓫFe²ᐰBF´Fe3O4,ᜫ·8NAᵯ3᪆20gD2OᨵḄᦪ20X10NAmo6=IONA,A⚗┯J:¹ᢣ»¼`ᡠᜐyz$B⚗┯J:NaHCChÁ`?ÂᙠCO3,C⚗┯J:3molᓫFeᙠN¼²ᐰ´Fe3O4,FeḄᓄᔠ´+2ஹ+3$ᜫ·8NAᵯ$D⚗஺VᫀD8.2019•ÆÇḕÉÊË᪥ÍÎ`Ï#ᑡ
ḄA.ÐÑᩩÓ#$N2L03«ᔠ¼Ô`ÕḄN2ᡠᦪÐÔB.ÔᱥḄḄᵬ×@CH3LØ×@0HᡠᵯᦪÐÔC.!"!Ù#28gCO22.4L0ᡠᑖᦪÐÔ2D.16gCH418gNHlᡠᦪÐÔ3᪆Ú⚪ὃÝnopqr!ᦪḄÞß஺A.àNᵫ3N᪀ᡂ$ᑣÐÑᩩÓ#$N2L03Ḅ«ᔠ¼Ô`ÕḄN2ᡠᦪ?ÐÔ$A┯J:B.ᵬ×L×ᙳᨵ9ᵯ$ᑣÔᱥḄḄᵬ×@CH3×@OHᡠᵯᦪÐÔ$B:C.!"!Ù#22.4L02ḄᱥḄ?1mol,28gCOᓽ1molCOᨵḄᑖᦪ?ÐÔ$C┯J:D76gCH418gNHlᡠᦪ?ÐÔ$ᑖã10molஹ11mol,D┯J஺Vᫀ⌱B஺VᫀB9.NAå⊤nopqr!ᦪḄs஺#ᑡuvḄA.ᙠ᪗xyz#$11.2LCH2CI2ᑖçᦪNAB.14gLiᢗᐭ100mLlmoLL7é⏚ᵯᦪ0.INAC.lL0.1mol-L1H2SH'ᦪ0.2NAD.2.0gDOLHi80Ḅ«ᔠᱥᦪNA2

43᪆A⚗$ᙠ᪗xyz#$CH2c12ᕈ᝱$?^᪷ð¼`᥅ò`ÕÞßᐸᱥḄᡈᦪ$┯J:B⚗$LiᐜHC1jk$¥Kjk$ᦑLi^²ᐰjk$ᵯᦪ2NA,┯J:C⚗$H2söᑖᵯ®$H+ᦪ÷Q0.2NA,┯J:D⚗$D2OஹHø0ḄÐùᑖú20,ûüú10$ᦑ2.0gý«ᔠᱥḄᱥḄ0.1mol,ᦪNA஺VᫀD10.2018ᓅḕÿ᪥ὶὃ*ஹ2Ḅᑖᐵ᪷ீ᪷=0.5MZ,!ᑡ#$%&Ḅ'A.)ᦪ+,Ḅ-ᨬᜧḄ'ZB.1ᩩ3!-1Ḅ-45ᨬ6Ḅ'XC.9:;ᩩ3!-<ᙳ2.24L,ᑣBCḄᱥḄ:;ᙳ0.1molD.1J!-<1ḄKLᘤᑖNᐙᐭ2gYS1gZ-ᑣᐸUVW2X1Y᪆᪷[\]-ᙠ1ᩩ3!-ᑖ_6-ᑣ45_6-ᡠa45ᨬ6Ḅ'X,ᦑB⚗%&dA⚗-ᵫfᔜᑖhḄ)ᦪi]-j)ᦪ+,k-ᑖᦪl:;,-ᨬᜧḄl:;Z,ᦑA⚗┯ndC⚗-ᙠ᪗pqr!,2.24LḄᱥḄ0.1mol,sᙠᐸBᩩ3!l:;0.1mol,ᦑC⚗┯ndD⚗-1J1

53H2஺\]-A⚗%&d·0hḄᦪ10,W¸hḄᦪ11,ᦑ1molHO2SH2F+Ḅ¦ᔠᱥhᡠ¨ᦪᙠIONAºUNAv¼-B⚗┯nd2cH3cH2OH+O2½¾2cH3cHO+2H2O,j2moi⏣Àªᓄk-ᨵ1mo஺ÀÁ)-®¯4molᵯ-«ᡂ2moi-ᦑÂÃÄ«ᡂ1molk®¯ᵯᦪ2NA,C⚗┯nd46g⏣ḄᱥḄ1mol,s1Å⏣ᑖh¨ᨵ8Åᐳ³´-ᦑ1mol⏣hᡠ¨ᐳ³´Ḅᦪ+8NA,D⚗┯n஺ᫀA12.2018•ÆÇḕᓄ:hஹÉÊ:hஹË:hÌὶὃᵨNA⊤ÎᦪḄ-!ᑡÏz%&Ḅ'A.Ðᐭ1molCbḄÒᑴÓh-HC10ஹClஹC1CTÕᦪvS2NAB.᪗pqr!-22.4LCC14hᡠ¨ᑖᦪNAC.J!-1LO.lmol-L-1ḄNa2co3×Øh¨ᨵḄÙÚᦪ0.3NAD.0.1molFeSÜḄÝÞ⏚ᐙᑖÃÄ-®¯ᵯᦪ0.3NA᪆AÐᐭImolCbḄÒᑴÓh-ÓSà«Ḅ'\⌮ÃÄ-âᨵ:ãᑖÓ®ᓄHC10ஹCäஹCIO,ᡠaHC10ஹCäஹCICFÕᦪvS6f2NA,Al%&dB.᪗pqr!-CC14l'-ᡠa22.4LCC14l'1mol,ᡠ¨ᑖᦪl'NA,Bl%&dC.J!-1LO.lmol-L-'ḄNa2c஺3×Øh×Yæ0.1molNa2co3,tç⏚᪷à«Y-COF+H2OV^HCOI+OH^,ᡠa¨ᨵḄÙÚᦪᜧf0.3NAdD.0.1molFeSÜḄÝÞ⏚ᐙᑖÃÄé«ᡂ0.1molFe3+,®¯ᵯᦪ0.3NA,D%&஺}ᫀ⌱D஺ᫀDëìíî14Xᨵïᔠᡂºðñ1.ò⏚óªôyõö\ᵨf■øùúû⏥ýøᶭÿ⊈
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ᡂ67y3
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10C7H8஺|—■ᩩ²C7H6஺2Br2C7H5O2BrCH3ONaBFcBqCCOOH/H,C\COOHÛÜFÝᓄÞᵨ×Ø/tÚ3✏ᐲᕸ||IE⏚oFàrজR—BFâãaR—0CH3COOH/ḮØஹtÚঝR-CHO+H,C------------>R—CH=CH\COOHCOOH#$ᑡ&⚪:(1)AḄ34-,B5ᡂCḄ6789-(2)ᕸᖹ⏚Ḅ)᪀+,-o(3)F./01234-஺

11ভᑏYFJèÈNaOH67ḄᓄQéê,(5)G-✏ᐲḄ@ᑖB᪀C1ëFeCbìí⁐tRîᨵ

12*ᑮA(),1஺✏ᐲ/01⚪ঝ*ᑮD,ᡠDCH=CHC()()HOCII2cHz()Hoᨬ45ECH=CHC()()HIOHOH6ᓄ*ᑮF,ᡠECH.V(1)Aᡠ89:ᵬ<=>ᡈὅ4-ᵬ<=>஺ᵫCHOB(rj)ᑮ©(|ஹ||)ḄEF஺

13CFI=CHC()()HOHফᕸᖹ⏚EKLH஺3᪷&FḄM᪀O)*ᑮᐸQRSTUḄ89K>LVV<_[Rᓄ\`Wa᜜6XW[Rᓄ\cᡠde)H()23Na()H--fOHCH=CHC()ONaCHCHOH22A+f+2H஺஺ONaONa5G✏ᐲ/Ḅgᑖh᪀iTjFeCbklmn⁐pqᨵ>V<=s#tᨵ]^EFV<᜜ᐸvḄ]^CW]^஺wᙠa^EF<#yᨵ6X஺ᡠzᔠ⌕|Ḅgᑖh᪀iᨵ9}~COOCHCH()OCHOOCCH7OHOHOHKᔜᨵ:}gᑖh᪀iL஺ᐸ`᪶ᐳ[ᨵ4}gs᛻Ḅ[,

14COOCH,OOCCH5W0HOil☢3~2~2~1ḄGḄM᪀O)~6
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16XHNaOH/HO2ঝCHO+H—C—C——H-------:-------H()OHOHᔠᡂᕸᖹ⏚=Ë6ḄÚÛ᝞Ý:জNa()H/H,()HJ)ClজNa()H/Hz()2----------------------------->C—*r)ঝH+ᐝ᯿ঝH+CHCHOåæklஹUH3-------èᕸᖹ⏚NaOH/HOAH+23-äË<=ᕸᖹ⏚=Ë6éê¤Ýᑡᔜ⚪~(1)ᱥìAḄ890(2)ᵫB1ᡂCWC1ᡂDḄïðᑖñ

17(3)EḄM᪀O)oভᕸᖹ⏚1ᡂᕸᖹ⏚=Ë6Ḅᓄóde)(5)õ✏ᓄᔠᱥXG(C9H8஺3)Ḅgᑖh᪀iXT⛳WØ⏚[\klû!CO2,yüᑴCu(OH)21ᡂþÕ⁐ÿ
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18CH=CHC()()HUᓄᑺ------►OHCH2cH3+nCOOHCHOQ)Na()U/H()2ঝH+5CH3cH2cH()Cu/ANa()H/H()^2

19CH3CH=CCH()OH4.(2018•WXḐᓅ[\]ὶὃ
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20(5)CḄᑖ᪀}ᑡᩩvḄᨵ
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