2016年浙江卷高考理科综合真题及答案

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2016
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11ூ]ᫀ௃cூ)᪆௃a⚪ᑖ᪆I᪷d⚪eᵯḄfFG4M+nO+2nHO=4M(OH),22n56ᙠ᩽gᵯW0ᵫ4ᨵ▢VWXᣚZ0᩽FGHL02+2%0+4€j=40l0]ᫀ⌱CoὃoIὃpqᵯCḄrsqᳮ஺12.tᵬ⏚w("S,|ᑏLNaA)~ᵨsᧇḄ■ῖᑺ஺Ẇ⊤tᵬ⏚(HA)Ḅᢓ
℉'4A,25࠷0HAḄ(=6.25x10-5,H2c஺3Ḅ/Ci=4.17xl0-7,a(2=4.90x10-11஺ᙠ⏚ᧇḄDEK0◀NaA᜜0◤ᐙᐭCO26஺ᑡḄ(L25࠷,ὃ⇋ᧇKᐸᡂᑖ)A.¢4£ᐙCO?Ḅᧇ0⏚ᧇḄᢓ
;¤B.&'CO2ᐙ60ᧇKc(A)¥C.¦pHL5.00ᧇK§=0.16D.⏚ᧇKᔜ>©WḄªᐵ¬LIc(H+)=c(HCOA)+c(C0A)+c(OH-)-c(HA)ூ]ᫀ௃Cூ)᪆௃

12D⚪ᑖ᪆A.᪷H⚪IJᵬ⏚(HA)ḄᢓMNOP℉RSA-,TSUᐙCOIḄWᧇY⏚WᧇḄᢓMNOZRA⚗┯B.[RCOIᐙ2\O᪷H]⏚ᑴ_⏚ᳮCOI-HIO-A-=HA-HCO=,Wᧇac(A-IbB⚗┯C.cpHd5஺eWᧇa"g=c(H)Ka=lQ-6.25xlO~MH6IC⚗;<D.Y⏚WᧇahᐭḄᔜᡂᑖ$lUmnoTZᔜpqḄrsᐵuD⚗┯=ᫀ⌱C0.ὃoIὃpÁᵯ)ḄᵯV஺13.LÂÓÅÆᐳÈ஻0ÉrᔆËÌᔠᜐᳮÏNH4.ÐÆÑrÒÐ6(Ó⌕ÏN2ஹCO>SO2ஹNOஹCO,ὃ⇋ᐸᡂ2ᑖ)0ÕÖ᝞ØEIᑡḄf-------1$ஹHIvwxAz{|}.||ᔩI—k-----f_____|n2^®—I,——.L“7A.à1KÓ⌕ÏᨵCa(OH)>CaCO>CaSO233B.X~áB60â◤DC.ᣓäᑺᡠᣓäḄ6Ó⌕COD.ᜐᳮÏNFVÐÆ0æFGḄVWçEHLINH4++NO==N2yt+2HO22ூ]ᫀ௃Bூ)᪆௃a⚪ᑖ᪆I61
èDéᮞëᔾᦈḄNOஹCOÑî60NOÑNO2ᢥ131Ḅ/
(NaOH*+FGᡂðñ⏚w0ᡠáX~áB60ò
D0]ᫀ⌱BoὃoIὃprÒÐÆஹÐ6Ḅᜐᳮóô஺

13õ⌱ö⚪÷ᑖ(ᐳ180ᑖ)26.(10ᑖ)ᓄᔠᱥXj>ᨵúᔠᡂKû0ZüýḄ'ᑖWᓄᔠᱥ0ÉẆþÿᵨ᝞ᔠᡂXZ஺জᓄᔠᱥAḄ᪀ᨵ2ᵬঝRCOOR'+R'CHzCOOR'*RCOCHCOOR8(1)ᑏᓄᔠᱥEḄ᪀,F!Ḅ"#$O(2)YTZḄᓄ&'($o(3)G9XḄᓄ&'($)*+,$(4)-C.ᨵB,ᵨᓄ&'/01BḄ2ᙠ(⌕6ᑏ78ஹ:;<)ூᫀ௃26.(1)CH=CHA22BᓄᑺnCH2GClCHCHCH,5ACHCHONa}2ZCH.CHCOOCIkCll-----------♦CHXHCOCCOOCILCH.♦CHClh=
Ht=3GC»,DE)*

144GD〉GH᪵JHKLᐜᵨNaOHLNOᐭQᑴSTᓄUVWXLOYL-Z[Ẉ]⁐_`LᑣᨵB2ᙠ஺ூI᪆௃H⚪ᑖ᪆ᓄᔠᱥAe[fgTᓄhi[ᡂBஹC,ᑣAj⛳lᐗ⏣LAḄ᪀ᨵ2ᵬLᑣAjCH3LCHCH2OH,BjCMCHCHO,C^JACHCHCOOH,᪷32pঝLGjrLFj⏣L᪷pYḄstᦪvLDjwᯋLEjwyLFjw⏣஺=1G᪷pz{ᑖ᪆LEjwyL᪀jCH=CH,F22jw⏣LsᨵḄ!jA஺2
Z$|}Ḅ~ᑖᓄᔠᱥLYTZ$wyḄO)*Lᡠ)*Ḅᓄ&'($ᓄᑭnCH,=C»»+CH,CH-r0Lo3᪷HmঝG-XḄᓄ¡¢CHCAI,CH,5CHேCH,ONa2ClhCHCOOCH<1l3---*•CH.CHCOi.COOCli.CH,*CH.CH,OHSL᪷H¤¥ᱯ§¨¤¥Ḅ¤¥©ª«¬¤¥஺஺4Cd
CH/CHCOOH,Bd
CH/CHCHO,Ca$ᨵ3,®◤⌕±◅³´ᔲ(ᙠᓽ5ᓽ«〉lD᪵SD¹aᐜᵨ]¼a½hᐭ¾ᑴ¿%ᓄÀÁÂ{hÃÄÅÆÇÈ⁐ÊËᑣᨵB(ᙠ஺VὃὃᨵᱥḄᔠᡂLᨵ)*+,Lᨵᓄ&'(ḄᑏLḄ01஺27.I.6ᑖᓄᔠᱥMg5A6OH
H0G4v8,192

15ᩞᧇLYᢥ᝞ᓄ&'(ᑖ2Mg5AhOH
H0
|^=27HO/t+10MgO+3AIO1924223=IGᑏᓄᔠᱥ8ᑺḄᩩhp02Gᵨ'(⊤◀¡¢£ZᱥAIOḄ¤ᳮ233GMgOv¦JNHCIḄ§¦XLᵨᓄ&'(⊤4ᐸ¤ᳮoII.12ᑖ©ឋᩞᧇA$ᵫ¬ᐗ®ᡂḄᓄᔠᱥL¯Ẇ±²®ᢥ᝞³´(µ±ᐸ®ᡂJ2.400g]l⁐¶£௃/J¸⁐—XºKSCஹ»Xmᡭ⁐¦X1OPᓄ.ᱥ¾¿ÀI:_J2ZJ-~11'J------------Â,“ÅÆÀÇ⁐”£ºHQÉJL⁐²ÊXºI,ḄKI-JIÇ——F\FË᪗]⁐ுG⏚ÏÐÑ1
AḄ®ᡂᐗjᵨᐗÒÓ⊤Lᓄ&jo2
¦XCv¦UᱏLÕÖ)*Ḅl×▭*ᵨ=3
ᓄᔠᱥAÙÚÛ⏚)*L[ᡂl¬Ü¸⁐ݦᱥl¬¿£᪗ÞḄßàj1.518g-L1
,¿£ᑖḄᵯj—oᑏ)*Ḅ'(____________________________O=4GᑏF9G)*Ḅᓄ&'(oâã×1'ᫀµ±¦XGḄä⌕åæÝὃ⇋è0ஹH\

16K\I)oூᫀ௃I.(1))*ᔾYêëìàL¢£Tᓄᱥ◞L§ï¿Úð¾¿஺(2)AIO+2OH-=2AIO+H02322(3)NHCI+HO0NHHO+HCI,MgO+2HCI4232=MgCI+HO22II.(1)S>FeFe3s4(2)ᑴᓺᑵᵯón-,s-n(3)õ•FeS-6H-^=3HSt-3Fe>-S+(4)HS0L2HI+«Ü{G,hᐭ}lBaClÜ{ÄÅÆÝ⁐ÊËᑣᨵSO.-",}Þß«Þ{àhH0Ü{ÄÅÆÝ⁐ÊËᑣᨵHSO”ூ᪆௃D⚪ᑖ᪆I.(Dᤥdᔾä¥Nãäå⚪¤¥ÅÆḄæ%ᓄᱥN◞èé2êëÅÆ7ì25íîïé2஺ᦑ=ᫀd¤¥ᔾÃãäñsæ%ᓄᱥ◞èé27ì2îïé2஺~(2)%ᓄ╅%ᓄóḄôᙠS%ᓄóNõ]ö¤¥÷%ᓄ╅øN%ᓄó]ö¤¥Æᡂùó⏚&7*¡¢dA19-20H--LK0--H0஺(3)!ᓄ╄Ü{aû᪷*7üNILCI-H9^NHHO-HC1,Üýd⏚ឋ%ᓄ╅7üÆᡂḄ&⏚¤¥Æᡂ!ᓄ╅¡¢dMgO-2HCl=MgCI-HOoII.(1)Èÿ⁐
3ᓄ⏚ᡂ⁐Cᓄᓄ;;ᓄ⊈⁐Dᓄ஺⁐⏚ឋỚᡂ⁐⏚ឋ!"#$⏚%⏚&ᐹᨵ)$ឋ*⏚ᑣ⁐,ᓄ஺ᑣ$ᓄᔠᱥ/0ᨵ1ᐗ3஺ᓄḄ562.400g,ᐸᱥ5Ḅ6,4஺016Q=Q.Q”moI,0$8Ḅᱥ5Ḅ9Q.030mo,ᑣḄ560.030X56=1.6S0g,ᑣᓄᔠᱥ/ᐗ3Ḅ562.960-1.6S0=1.280g,Ḅᱥ5Ḅ61.280/52=0.040mol,ᑣ123Ḅᱥ6Ḅ7890.030:0.040=3:4,ᑣᓄ;<9Fe3s4஺(2)>?C9@ᓄ

171AB>CᵨᩭᑴᓺᑵᵯJK஺(3)ᓄᔠᱥA23⏚NOPᡂRS⁐U>ᱥ93VWXYZ[YZḄ᥅]6791.518X22.4=34.00,ᑣ93ᓄ^஺3ᓄ^Ḅᵯ_<9[NOPᡂ3⏚`1V3V3ᓄ^ab<9:FeS+6H+=3HSf+3Fe2++S(4)`3⏚VỚᓫ6NOP342oᡂ3⏚V^Ớ⏚ab<9HSO+I+HO=HSO+2HIA232224>?Gfg⌕iᨵ3⏚᪷l_ᡈnᨵoNOpḄ`3⏚ᑖ_3⏚᪷l_ᵨrstu`3⏚ABᵨvᓄᑺvᓄᡂ3⏚᪷xtuᐹZz{a|9}>?G,~ᐭ7Ba">?P⁐ᑣᨵSO’?W}?,~%஺2>?P⁐ᑣᨵH2s஺3஺ὃl_tuᱥ6ᡂḄ28.(15ᑖ)ᓄCO?ᦔO⚪Ḅ⌕¡¢£W஺Ẇ¥⊤§ᙠCu/ZnOᓄᑺ©ᙠªCO2V«A¬P®¯⊝NOᑖ±PᡂCH30HVCO஺NOḄ²ᓄ;ab<᝞ªC0(g)+3H(g)-CHOH(g)+H0(g)2232AH!=-53.7kJ-mol1ICO(g)+H(g)-CO(g)+H0(g)A%II222´µu¶ᑴCO2V«·¸ᢗᧇ891:2.2,»¼½NO¾¿ÀÁ᝞ªµuᦪÃ

18T••W.•W•WIJA1“WJUI38.1I[ÆJki1Ç”஻É.£“\|3njᦈ]1ÐÑIÒÓ;Ô:-K}_______ᓄᑺCO,Õᓄ᳛(%)ᵬᓽ〉Úឋ(%)543Cat.1123413543Cat.210.972.7553Cat.I15.339.]553Cai.2|2,07].6ூᜓÝ௃Cat.l:Cu/ZnOÞßàCat.2:Cu/ZnOÞßᱏᵬ⏣⌱ÚឋÕᓄḄCO2fPᡂᵬäḄåᑖ8æçজCOVHḄ᪗éêë²ᑖ±9-283.0Hmol1V2-285.8kJ•mol1ঝH2O(I)=HO(g)AH=44.0kJ•mol123ìíî(Uὃ⇋ðñA4Ḅòó)(1)NOIḄ¯⊝ôᦪ⊤õ

19⏣ᑣSᡂᵬ⏣Ḅ
WSᙠX᩽Zᵯ᩽
[0,B'^’-------A
?@ூ`ᫀb(1)9ᵯ஺ᵪ^(e0)+41.2C(CO)C3(H)22(2)CD(3)⊤ᦪ⊤fg
hiᑮk⊝Ḅᓄᑺ"
IḄᓄBm/nᙠZgo"ᵬ⏣⌱&ឋᨵ+,஺Ꮙ(4)q?@(5)▢CO+6H++6e==CHOH+HO232ூR᪆௃

20>⚪ᑖ᪆B(1)᪷DE⊝GᦪḄIJᡂᱥḄKLMNOᱥKLḄPNOḄQRSᑏE⊝GᦪXCHQH){(H0஺ᨵUᓄVWXJB⌮&(g)-10^(g)=CO^(g)AH=-2S3.0kJ-mol\c(CO)c(H)2;:b:H^(g)--02(g)=H0(!)AH=-2S5.8kJ-mo?-c:H^OC)=HO(g)AJf^=44.0kJ-mo?-;:᪷D]^_`ᑖ᪆b-IaᓽcdUᓄVWXJBCO^(g)-H(g)—CO(g)-H0(g);;X^=-285.8-283.0-44=-41.2kJ-mol-o(2)I/AஹfᵨhᓄᑺE⊝jkljmnopᓄ᳛,┯tuBஹfᵨhᓄᑺE⊝jkljmnopᓄ᳛┯tuCஹvwxLE⊝yᔣklno,ᓄ{Ḅpᓄ᳛y|uDஹᢗᧇQjḄKLE⊝yᔣklno,ᓄ{Ḅpᓄ᳛y|uEஹᜧ,ᓄ{1ḄᢗᧇQmnoḄpᓄ᳛,ᓄ{Ḅvwᦑ┯t஺ᦑ⌱CD஺(3)⊤ᦪDᑖ᪆ᙠḄxLjḄhᓄᑺᐸ,ᓄ{Ḅpᓄ᳛j"#jḄhᓄᑺḄhᓄmj;hᓄᑺjḄxL,ᓄ{Ḅpᓄ᳛jxLoḄpᓄ᳛ᜧyU"#⊤/ᦪDᑮE⊝ᦪD஺ᡠaᫀB⊤/ᦪD⊤#g
hiᑮk⊝Ḅᓄᑺ"
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ßâãឮåÞ¿?ææO#¸ÞçXÙÚḄèÒéᓾÞ0࠷,᪆6ᨔìí?æ¯:ÔÕᔠÄᓄ╅îÎ஺ÌÍ4³ᵨïNRîÎéᓾÞ0࠷,᪆6ᨔì?æ,ðñ¯:Ô⏚ᔠòᓄ╅óÞ160࠷ᑖR¯7MMgBr?õÎ஺ö÷^জMgᑠ2
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(1)ᘤAḄo

22ᵨN2,2G᝞BᦋC2G,!"#$Ḅ%&=3G'(3)*+,-.◀0Ḅᱥ2o4Gᨵᐵ'(4Ḅ56)78ḄoA.!ᵨ95%Ḅ9⏣;<=>?B.@AᨔC!⌱ᵨ0࠷Ḅ;C.EFG160࠷ḄH⌕JḄ◀0;D.K'(ḄJḄ◀09LM!NᶇḄP=5GQRS?ḄTU)!ᵨEDTAVᑏY'
᪗Y

233G╅4GBD=5Gজ[RfEᐭuQZ,¡Ḽ£¤[Rf)¥ZCe¦ᑁ¨)ᯠ%ª«¬)®2-3,ঝ97.5%ூ=᪆௃>⚪ᑖ᪆B3zᘤA¡஺¢£¤⌕ᵨ╅§1¨ᡂ¨ᓄ╅ᡠa©ª/jmᨵm╅Ḅ«᝞ᡠajmᵨḄ®¯Ḅ°஺ᦑᫀB■²╅§ᡂḄ£⇩´µMg1BrḄ஺2z¶©ª3·©ªC,¸Ḅ°¹ᐭf»ᜧ,¶¼½¾»ᐭ¿⚠Á½ᜧ6UÃÄᙠÅᐰ◚È஺éªBᑭᵨḄ°¶ÊË®ᐭ¿⚠ÌÁ/caÍᑴ■²Ï½஺ДÒÓ3ÂÔÕÖḄjḄ╅§஺4ுAஹ95%ḄØ⏣/0ᨵ¨ᓄ╅ᨵ!ÚḄᔾឋ┯tB3ஹᐭÜḄḄ◀ÖØ⏚1Þßàᨔᵨ0âḄãcaäåæçḄèy|uCஹUé160âḄê⌕Ḅᑖè¿ØëᔠÊᓄ╅dᑮ¼ᓄ╅,jì◀ÖÜ┯tuDஹ·ÒÓì◀ÖØí1¨ᦑy|஺ᦑ⌱BD஺5zজï_ðñßï_¡◤⌕ï_¡óôᐭå6õö÷øùḼplï_¡fñûᑁýᯠÿ
3஺ঝ᪷ᑖ᪆ᓄ╅ḄᱥḄ0.0500X0.02650=0.001325moi,ᑣᓄ╅Ḅ0.001325X18472438g,ᓄ╅ḄḄ-0.24380.2500-97.5஺஺°ὃoᑴᜓ`ᫀḄÌÍ)ÎᔠᱥḄÍÐ)ᱥ2Ḅᑖ^MÑTḄÒᔠ]ᵨ2016ÓÔÕḕ×ØÙÚÛ᪥ÝÞ+ὃßᳮáÒᔠß⚪ᱥᳮz

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᳛ᜧC.ᵯᘤᵯCᵯᘤᡠᵯ₹QᡂD.ᙠᜫᙢᳫᱥḄ▭"ᵨ$%&'(ᓄூ+ᫀ௃Aூ"᪆௃$⚪ᑖ᪆&ᙠ☟ᵯ*+,Ḽᵯ*./ᔣᵯ1⌲345⌱⚗A89᪷:=<=>᜜@AᱥBᡠDḄEFGAHḄE᳛JKLFᜧ⌱⚗B┯OPᵯQᘤᵯQCSᵯQᘤᡠTᵯ₹஺VᐵXSYZḄ8A☢\ஹYZ^_`aYZ^Ḅᵯbᨵᐵ⌱⚗C┯OPᙠdeᜫgh+ᙢᳫAᱥBḄk▭mᵨ@oᨵpqrᓄXsᱥBḄtpqurᓄ⌱⚗D┯OPᦑ⌱AoKὃ/0ᵯ12
᳛2ᵯᘤ2ᜫ15.᝞5ᡠ6789ᵯḄ:43,ᵨ;<=>?ᢝABCDEFG஺I;ᵯ₹ḄᱥCJK4▬MNᙠ4ஹBPQḄRSTUVWf_______nA.EX4ᵯBYᵯB.EX4ᵯ1ZBᵯ1[C.\]C,Nᙠ4ஹBPQḄRSTU^ᔠ

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30
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