2018江苏卷化学高考真题

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ਭᵨ2018᪥ᐰὃᔁᓄ⚗ὃᙠ⚪!"#▅%&⚗'ᔜ⚪⚪⌕*1.&ᔁ+ᑖ-120ᑖ.ὃ/0-100ᑖ1஺ὃ345.!6&ᔁ7⚪ᓱ9:;஺2.⚪.!<=6>?ḄABஹDὃEFᵨ0.5HIJ⁐LMḄNOPQᑏᙠᔁ'⚪ᓱḄSTUV஺3.!"#᪶XYὃᕒᙠ⚪ᓱ[ᡠ]^Ḅᩩ`ṹ[ḄABஹDὃEFb&cdᔲfg஺4.j⌱l⚪.=mᵨ2BnP6⚪ᓱ[Xo⌱⚗Ḅp᪾r+ஹrJs᝞◤ᦋw.!ᵨxyz{|5.}⌱rᐸᫀ஺j⌱l⚪.=mᵨ0.5HIJ⁐LMḄNOPᙠ⚪ᓱ[ḄᢣTUVj.ᙠᐸUVjᦔ஺5.᝞◤j.mᵨ2BnPஹᑏ.ᩩஹgFmJஹ஺ᵨᑮḄfXH1C12N14O16Na23Mg24Al27S32Cl35.5Ca40Fe56Cu64Ag108I127Ba137⌱l⚪ᓫ⚗⌱l⚪&⚪ᒹ10⚪.⚪2ᑖ.ᐳ20ᑖ஺⚪⌱⚗gᔠ⚪஺1.CO2d>ᯠ¡¢£¤¥Ḅ¦⌕ᱥ஺¨ᑡª«¬®ᜧ°¥CO2±[ᓣḄdA.ᐝᔠjᵨB.>ᯠ´µC.ᓄ¶·ᧇḄ·¹D.¢⏚»Ḅ¼½2.ᵨᓄᵨ¾⊤ÀNH3+HC1^=NH4஺¥ḄfᐵÂÃ.ᐸ¥ÄÅḄdA.¥ᦪ-8ḄÇsOB.HC1ḄᵯÉᵬË©ÍH-N-H^1728^7C.NH.3Ḅ3᪀ÉHD.Cf■Ḅ3᪀À
3.¨ᑡᨵᐵᱥឋbᵨ⌶ᐹᨵXoᐵÔḄdA.NaHCChÕÖ᧕ᑖØ.ᵨÙᑴÛ⏚¥7ᑺB.Si஺?ᰚßàáᜧ.ᵨÙᑴᐝâãä

1C.AI2O3dêឋëᓄᱥ.ᵨjὊíᩞᧇD.CaObMño.ᵨjòó{ôᑺ4.õí¨.¨ᑡᔜö÷ᙠᢣTøù¥ᜧᐳúḄdA.0.1mol-L'KINa+ஹK+,CIO">OH-B.0.1mol-LTFe2(SO4)3Cu2\NH+NO\SO2-434C.0.1molf'HClBa2\K*ஹCH3coeTஹNO-3D.0.1molL-NaOHMg2\Na\SO2->HCO~435.-ᑡᨵᐵ123456ỚḄ9:;ᳮ=>?@Aᑮ9:CḄḄD23ᮞ4EA.ᵨ>?ᵬJKL23B.ᵨ>?EMN23ᮞḄOPC.ᵨ>?QᑴᜓᵨTUᓄOP4WḄ஺2D.ᵨ>?YᔾᦈUᓄOP4W\ḄC12]^6.-ᑡᨵᐵᱥ`ឋ`ḄbcdefghḄDA.ᔣFeCk4klNH4SCNmno⁐B.KA1(SO4)2"2H2OTqrsᡂA1(OH)3uvC.NH4clwCa(OH)2xᔠlzr{ᡂN%D.CuwFeCh~r{ᡂCuCb7.-ᑡᢣe~ḄghḄDA.⛳=Na2cO3wCaSCUv~CO2+CaSO^=^CaCO4-SO2'3434B.⏚ᓄNalCh=NaiḄxᔠW+IC)3-+6H+^=l2+3H2OC.KC1OឋwFe(OHb~3cleT+2Fe(OH)3=2FeO42,3CW+4H++H2OᵯD.ᵯ⛳=q2cr+2H+^=C12T+H2T8.ᕜᐗXஹYஹZஹW;ᦪ¢£¤ᜧmXDᙢ¨4©ªᨬ¬ḄᐗmY;

2Ḅᨬ᜜®¯ᨵd°ᵯmZ±Tᐗᕜ⊤HIAmWwX³T´d஺-ᑡµ¶ghḄDA.;·¸/r(Z)>r(Y)B.ᵫXஹY¼ᡂḄᓄᔠᱥ4ᙳf©ᐳ¿ÀC.YḄᨬÁ¿UᓄᱥḄqᓄᱥḄឋÂZḄÃD.XḄÄᓫ^᝱ÇᓄᱥḄzÈeឋÂWḄÉ9.ᙠÌeᩩÎ-m-ᑡ⌱⚗ᡠÒḄᱥ`ÓÔᓄᙳ@9ÕḄD,ஹÖ×⛳=ØᮞqmஹA.NaHCO(s)——►Na,CO(s)------------>NaOH(aq)33B.AKsy^tNaAKVaqy^^AKOHMs)C.AgNO(aq)^i[Ag(NH),]-(aq)-ⅅÚ(ÛmAg(s)33Al,HCl(aq),,ஹD.FeO(s>--Fe()-------^FeC^Caq)23rSÝiittL10.-ᑡµ¶ghḄDA.ÇUÞᧇᵯàáᵯâᓄã@ᐰåÔᓄæᵯ@B.~4Feম+3C)2(g)^=2Fe2O3(s)éê-rëìíîmï~æᔾz~C.3molÂw1molN2xᔠ~{ᡂNH3,ÔðᵯḄᦪCñT6x6.02x1()23D.ᙠ⏘ôᓄõöq~4mê÷øÁõöqù᳛øûfe⚗⌱ü⚪þ⚪ᒹ5⚪⚪4ᑖᐳ20ᑖ஺⚪ᨵᡈ⌱⚗ᔠ⚪஺ᫀᒹ⌱⚗⌱⚪!0ᑖ"ᫀᒹ#⌱⚗,⌱%Ḅ!2ᑖ⌱#%'Ḅ!(ᑖ)⌕⌱┯⚪,!0ᑖ஺11.ᓄᔠᱥY2ᵨ45ឋ2ᐝ8᪛ᾦḄᔠᡂ<ᵫᓄᔠᱥX?2-ᵬBCD⏒FᙠHᩩJKLMᑴ!OKᑡᨵᐵᓄᔠᱥXஹYḄSTḄUA.XᑖXYᡠᨵ[XHᙠ\]☢_B.Y?BnḄbᡂcᱥᑖXYdᨵeឋf[XC.XஹYᙳi2j⏚ឋKMnCUopq⁐D.XfYḄLMuvwLM

312.᪷yKᑡz{|}~ᡠ!ḄḄU⌱⚗z{|}~AᔣpYbNa2c஺3oppḄ⏚ឋ4H2c஺3Ḅ⏚ឋᔣỚYbᐭCC14,₩☟_12ᙠCC14YḄo£¤ᜧ4ᙠYḄB⁐K¡¢⁐o£¤CᔣCuSC>4opYbᐭ©ªᨵ¢⁐«᪆Fe?+Ḅ±ᓄឋ4Ct?+Ḅ±ᓄឋᔣNaClஹNaiḄµᔠ¶opYᐭ·¸¶DKsp(AgCI)>&p(AgI)AgNChopᨵ»⁐¼½¾ᡂ13.᪷yKᑡÅÆᡠ!ḄiḄUO-uz0CL5OTL04O。5473573673773873020406080o2.04.06.08.077Kt/s"lgc(SOr)ÇTA.ÅᵬUCO(g)+H2O(g)^^CO2(g)+H2(g)Ḅ]⊝Ëᦪ?LMͤḄᐵÎÏÐSÑLMḄAHOB.ÅÇUÒÍKH2O2Óᓄᑖ£Ô±ÕḄLMY஺(Ö஺2)×LMØᓄḄÏÐSÑ×ḼLMḄÚÛH2O2ᑖ£Ü᳛⌲ßàC.ÅCUÒÍKᵨ0.1000mollNaOHopH20.00mL0.1000molL-1äᐗ⏚HXḄHÏÐSÑHXUᐗ⏚D.ÅæUÒÍKᵨNa?SC)4◀èopYBaO+éᑮ¼½o£]⊝opYc(Ba?+)?c(SCV-)ḄᐵÎÏÐSÑopYC(scu2-)ìᜧc(Ba2+)ì14.H2c2஺4uíᐗî⏚Kal(H2c2஺4)=5.4x10-2,/C(HCO)=5.4x10'5,óH2c2O4opYa2224c(ô)=c(H2c2O4)+C(HCO")+C(CO2-)OÒÍKᵨNaOHopH25.00mL0.10002424molliH2c2O4opõö÷஺Høù!ᑮḄKᑡopYúûḄᱥüḄ¸ý¤ᐵÎHḄUA.0.1000mol-L1H2c2O4op:c(H+)=0.1000molL-|+c(CO2-)+c(OH-)-c(H2c2O4)24B.c(Na+)=c()Ḅ:c(H2c2O4)>c(CO2")>c(H+)24C.pH=7Ḅc(Na+)=0.1000molL-'+c(CO2-)-c(HCO)24224

4D.c(Na+)=2ᡈ)Ḅ:c(OH")-c(H+)=2c(HCO)+c(HCO~)2242415.'()*+,ᙠ./0123Ḅឤ0560ᘤ8ᢥ:3;<ᢗᐭ?@ᱥ,BC?@2so2EgG+O2EgGK^2so3EgGEK?@LMG,NO?@Ḅ2ᐵᦪR᝞+0ᘤ10ᘤ20ᘤ3?@)*77K700700800?@ᱥᢗᐭU2molSO2JmolO24molSO32molSO2JmolO2X⊝^(SO,)/mol-f'-s"1%vV32X⊝c(SO)/mol-L-1qcC332X⊝_`ab“PaPiPiPiᱥeḄX⊝fᓄ᳛a.(SO஺a2(SO3)a(SO2)3X⊝jᦪKKiK2+ᑡmnKoḄpA.ViKy,஻2>2஻3C.V\Q3(SO2)D.C2>2(73Q2(SC)3)+஺3(5஺2)<1r⌱t⚪16.E12ᑖGxyz{|}E~⌕ᡂᑖAI2O3ஹFeO,SiO,UFeS?z⏚G232ᧇ,Cᓄ{OFesOḄᑖ᝞+ஹUCaONaOHFeS2SO2E1Gᯏᙳ¡CSO,ᵨNaOHᔾᦈUSOḄ¥¦;<22E2G§¨l%CaO:§¨CaOḄ}©ᯏ,ᐸz«◀᳛)*®ᓄ¯°᝞⚪16±ᡠ示O8o%/6o线4o出愎2O02004006008001000ᯏ)*/࠷⚪16±´µ¶ᦪz⏚Ḅᑖ·)*¸y¹600°C

5ᯏ»}©8zᐗ½eUz«◀᳛=(1-xlOO%ᯏ¾}©8zᐗ½eUজ:§¨CaOḄ}©ᙠÁ¹500࠷ᯏÂ,«◀Ḅzᐗ½~⌕ᩭĹঝ70CTCᯏÂ,§¨l%CaOḄ}©z«◀᳛Ç:§¨CaOḄ}©z«◀᳛Á,ᐸ~⌕Èp஺(3)ᔣ“”OᑮḄ8ÌᐭUCCh,{ᐗ½ÎᙠḄÏ<ᵫ(ÑᓄÒ<)fᓄ(ÑᓄÒ<)஺(4)“”OᑮḄÓ8ÔᜧUḄFe2t)3஺FezChØFeS2Ùᔠ»ᙠÛᩩÝ+ᯏCᡂFe3CUSO,ᳮàáâᐰ?@äὑḄn(FeS)n(FeO)=஺222317.(15ᑖ)çè⏣pÎᙠ¹8êçè8Ḅ'ëᜩᯠᱥ஺ᔠᡂçè⏣Ḅᑖî°᝞+:(1)A8Ḅïðñòó(ᑏõë)஺(2)D---->EḄ?@÷øo(3)BḄᑖ¦ᑖᙳ@ᨵ2/ᓄB᛻ḄD஺

6/COOCH?^^.COOCH,0GHIJᧇᑴᜓ[ḄᔠᡂPQRST(VWXᑺGZ⏣\ᵨᔠᡂPQRST^_`a⚪⚪c)஺18.(12ᑖ)4d⏚e'(fᵨghiῃd஺klᔣnopḄd⏚e'(qᐭnsḄt⏚┛vw-.>xyz{ᑮ4d⏚e'(-.}SI(2-x)Al(SO)+3ACaCO3+3.YH2O^=2[(l-x)A12(SO4)3-xAl(OH)3]+3KaSO4i+3xCO2T243*ᡂᱥ(1-X)A12(SC)4)3XA1(OH)3x~Ḅᜧ4d⏚e'(Ḅῃdᦔ᳛஺(1)ᑴᜓ4d⏚e'(ᢝ-.lpG-./%~Ḅ}ᨵ(2)4d⏚e'(ᔾᦈSO2yS'(ḄpH(“ᜧ”ஹ“”ஹ“/”)஺(3)yn4d⏚e'(ᐵḄopnxḄ~n}᝞জ4d⏚e'(25.00mL,qᐭ⏚⏚ᓄḄysBaCb'(ᐙᑖ-.☟>yzஹ¡¢c£¤ឤ¦{§2.3300g஺ঝ4d⏚e'(2.50mL,¨©¤25mL,qᐭ0.1000mol-L'EDTA᪗«'(25.00mL,¬⁚'(pH®I4.2,¯°±ᓾ>ᵨ0.08000moll³CuSC)4᪗«'(´nysḄEDTA¤µ¶·ὑCuSO4᪗«'(20.00mL(¹ºA:ஹ+"EDTA-.ḄᓄB¼s½ᙳI11)஺¼¾(1-X)A12(SO4)3-XA1(OH)3Ḅx~(ᑏ¼¾yS)஺19.(15ᑖ)¿CLஹNaOHஹ(NH)CO(ÀÁ)GSO?IJᧇfᑴᜓN2H#Ã0(6ᔠÄ022GV6Na2so3,ᐸÆ⌕ÈÉRS᝞NaOH'(SO2ItICb►ÊËI—►ÊËn—TÊ;—Η►NajCOj►ÊËIV-----►NajSOj6ᔠ὏'(¹ºজC12+2OH^=C1O+CI+H2OÐÑÒ-.஺ঝN2HÓ½஺°¶®118࠷,ᐹᨵÖ×Jឋ!"NaClOᒓÙ-.*ᡂN2.(1)ÊËIᑴᜓNaClO'(ÚlpÛy40࠷,Cl"NaOH'(-.*ᡂNaClOj2GNaCl,ᐸ}SI2ÈÉÜᑴlp◀ᵨÞ6ß᜜×◤âḄãäÐo

7(2)ÊËnᔠᡂNHHOḄê᝞⚪19T-1ᡠ^஺NaClO4ឋ'("ÀÁ6'(ᙠ24240"C¿-.ô>õö÷ᓣl¤110࠷ùú-.஺ÈÉy´(ûᧅ´qḄ'(Ð;ýᵨ±þÿḄ
Ḅ⚪19-1(3)IVᵨH1ᑮḄNa2cChᑴᜓNa2so3("#$HSO.HSO)ஹ23SO+,pHḄᑖ/᝞⚪19-2ᡠ2,Na?SC)3Ḅ"5678᝞⚪19-3ᡠ2)஺50nso;403020100020406080100pH:6/࠷⚪19-2⚪19=-3জ?ᤅA?ᔣNa2c஺3"#$CᐭSO2ᑴᜓNaHSCh"#஺EF$GHIJKLCSOḄEFMNOo2ঝQ⊡ᐙT᦮ᵫNaHSCh"#ᑴᜓNa2s஺3ḄEFWᫀ+YᵨZ[\⏣^_Y`aYbcᒹe஺20.(14ᑖ)NO,(h⌕ᢣNOkNO?)ᜧmh⌕noᱥqr஺ᨵᦔu◀ᜧm$ḄNO*x᛻z{Ḅ|⌕}⚪஺(1)ᵨᔾᦈNO’ḄᐵᓄW᝞+2NO2(g)+H2O(l)+^=HNO3(aq)+HNC)2()AH=-116.1kJmof13HNO2(aq)^=HNO(aq)+2NO(g)+HO(l)AH=75.9kJ-moP1323NC)2(g)+H2Oপ^=2HNC)3(aq)+NO(g)Ḅ஻=kJ-mor1.

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஺3ᙠFeH2O6ᓄḄSChஹNO*ᑖ
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9'(ᙠᐸ*ᩩ,-./N»2(1)SO!1/23⍝Ḅᩖᓄ67#NO#Ḅ89᪀7(ᵨᦻ=>?)஺(2)Fe?+B᝱᪶᜜ᵯ2᣸HI஺(3)J஺3ᑖ2KLᵯ2MḄNO▢Q2(RᓄSI)஺(4)Nᑖ2oTJᐔTḄᦪWX"(G)!n(7t)=«2(5)Fe(H2(D)6JNOYZ[ᡂḄFe(NO)(H2(D)5]NO^N/2JFe?+_ᡂ`aT஺bᙠFe(NO)(H2O)5c᪀defḄgZah⊡RjkḄ`M஺Fe(NOXHO)c᪀def25B.lmᓄSn3,4-oᵬq
Brᵬ⏚tNOᵨ⌶vwḄᨵyᔠᡂ9M]{|}~]lm(ᵨKMnC>4
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Brᵬ"~]ᤅ]}7080࠷KMnCU|஺YZc]ᐭKOH|ឋ஺2!]]ᔠ"஺3!¡ᔠḄ|¢£ᜐᳮ஺4!¦]]§¨]©3,4-oᵬq
Brᵬ⏚ªM஺(1)1]YZc]«¬ᑮYZᕈ°±⁐]◤ᔣ|NaHSC>3|]HSO#´ᓄ(RᓄSI)#ᐭKOH|ឋḄWḄt

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11ᓄ⚪ὃᫀ⌱⚪(ᐳ40ᑖ)ᓫ⚗⌱⚪⚪ᒹ10!⚪"#!⚪2ᑖ"ᐳ$20ᑖ஺1.C2.C3.D4.B5.B6.A7.A8.D9.A10.C&'⚗⌱⚪⚪ᒹ5!⚪"#!⚪4ᑖ"ᐳ$20ᑖ஺II.BD12.B13.C14.AD15.CD(⌱⚪(ᐳ80ᑖ)16.(12ᑖ)(1)SO+OH----HSO-23(2)জFeS?ঝ*ᐗ,-ᓄ.CaSO4/ᶇᙠ234(3)NaA10A1(OH)23(4)1!1617.(15ᑖ)(1)55679:(2);<=>ব(1)〉@ABCaCChḄDᡈBFᤅHI᳛(2)K!2.3300g7(3)25mLLM4n(SO)=n(BaSO)=----VT=0.0100mol44233g•mol

122.5mL|!n(Al3+)=«(EDTA)-n(Cu2+)=0.1000mol-L'x25.00mLxlO3L-mLH-O.O8OOOmolL"'x20.00mLX1o-3L-mdooox1()Tolm25mL|!஻(A)=9.000x103mo[1mol(1-X)A1(SO4)3XA1(OH)23n(Al,+)=(2-x)mol#n(SO42")=3(1-jc)mol஻(AN)_2-x_9.00()x1(PmolnCSOp)ߟ3(1-x)-O.OlOOmolv=0-4119.(15ᑖ)(1)3C1+6OH=5C1+C1O~+3HOë᠒íᐭCl2322(2)NaClOឋ|îk~ᔠïḄᢵñ(3)জòó|ḄpH,«pHô4,õöíSO2ঝøᤅøᔣNaHSCh|NaOH|]òó|pH,pHô10ù]õöNaOH|]úû|ᨵᜧóᨔM᪆ÿᙠ34࠷ᩩ20.(14ᑖ)(1)-136.2(2)HNO-2e-+HO=^3H++NO"223(3)2HNO+(NH)CO---2N2T+CO2T+3H2O222(4)জ#7ঝ&'(ᓣ*+,ᓄᑺ/ឋ123ᓣ4ᜧ623ᓣᐳ89NO*;◀=>'᳛&'4ᜧ@(ᓣA᠒*C⌕+23ᓣEFḄNO,;◀=>'᳛4ᜧ,ᓄᑺ/ឋI@N%6஺2=>LᡂNNO21.O12ᑖPூ⌱S⚪௃A.[ᱥYZ᪀6ឋY]O1Psp3_☢OaPbcdO2P[Ar]3d6ᡈIs22s22P63s23P63d$O3PNO-2

13(4)1k2H,0B.mnoᓄpq(1)so2-s=>LᡂḄ⏚uᓄvwxឋḄy4(2)MnO2(3)ᔣx}~y⏚L(4)ᧅ