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ID:797258
大小:1.49 MB
页数:49页
时间:2017-09-05
《nacl溶液在不同初始浓度、不同温度和不同基底时结晶的表面形貌毕业论文》由会员上传分享,免费在线阅读,更多相关内容在学术论文-天天文库。
1、摘要研究了NaCl溶液在不同初始浓度、不同温度和不同基底时结晶的表面形貌。利用原子力显微镜从介观尺度上对不同影响因素下NaCl溶液结晶样品进行了观察,利用图像处理软件Image-proPlus处理扫描图像,分析了这几种因素对NaCl溶液结晶过程的影响,并对其成形机制和分形维数进行了探讨。研究结果表明,初始浓度越低,结晶分形花样越倾向于生成由细小的晶体颗粒组成的树枝状结构。随着初始浓度的增大,结晶分形花样聚集程度越来越高,生成的枝叉状结构越来越大,并且结晶中有许多立方体结构。比较结晶花样的分形维数,发现较低初始浓度结晶的分形花样的分形维数与Koch曲线类似,较高初始浓度结
2、晶的分形花样的分形维数符合扩散受限聚集(Diffusion-limitedaggregation,DLA)模型的结果。随着结晶初始浓度的增大,分形维数逐渐增大。温度影响了结晶的速率,结晶速率大,则结晶中心增多,晶体长得细小,且往往长成针状、树枝状。反之,结晶速率小,晶体长得粗大。表面平整度影响着结晶的表面形貌。而且,表面的平整度会影响溶液的流动,从而影响NaCl晶粒的聚集行为,对分形花样的形成起到一定的作用。关键词:NaCl溶液;结晶;分形维数;扩散受限聚集机制AbstractThesurfacetopographyofsodiumchloridesolutionscr
3、ystallizationwasstudiedindifferentinitialconcentration,differenttemperatureanddifferentbasement.Thesurfacetopographyofsodiumchloridesolutionscrystallizationsampleswereobservedfrommesoscaleunderdifferentaffectingfactorsbyatomicforcemicroscope,andusingtheImage-proPlustoprocessingthescanima
4、ges.Analyzingtheinfluenceoftheseveralfactorstotheprocessofsodiumchloridesolutionscrystallization,theformingmechanismandthefractaldimensionwerediscussed.Theresultsofthestudyshowthattheloweroftheinitialconcentrationofthesodiumchloridesolutions,themoretendtogeneratedendriticstructurefractal
5、patternconsistingofsmallcrystalparticles.Alongwiththeincreaseoftheinitialconcentrationofthesodiumchloridesolutions,theaggregationdegreeofthefractalpatternofcrystallizationwasincreasedandformingbiggerdendriticstructure.Whatmore,thereismuchmorecubicstructureinthecrystallization.Comparingth
6、efractaldimensionofthecrystallizationpattern,anditisfoundedthatthefractalpatterndimensionofthelowerinitialconcentrationcrystallizationwassimilartoKochcurve,andthefractalpatterndimensionofthehigherinitialconcentrationcrystallizationwasconsistentwiththediffusion-limitedaggregationmodel.Ast
7、heincreaseoftheinitialconcentrationofthecrystallization,thefractaldimensionincreasesgradually.Thetemperatureinfluencesthecrystallizationrate.Thehigherthecrystallizationrate,themorethecrystallizationcenterandthemoretendencyofthecrystallizationtoformsmallacicularstructurean
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