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1、Chapter1OverviewofChemicalReactionEngineering1.1ChemicalprocessillustrationEveryindustrialchemicalprocessisdesignedtoproduceeconomicallyadesiredproductfromavarietyofstartingmaterialsthroughasuccessionoftreatmentsteps.Figure1.1showsatypicalsituation.化学反
2、应工程化学反应工程Fig.1.1Typicalchemicalprocess化学反应工程Physicaltreatmentoffeed:Therawmaterialsundergoanumberofphysicaltreatmentstepstoputthemintheforminwhichtheycanbereactedchemically.Thentheypassthroughthereactor.Theproductsofthereactionmustthenundergofurtherphy
3、sicaltreatment—separations,purification,etc.—forthefinaldesiredproducttobeobtained.Designofequipmentforthephysicaltreatmentstepsisstudiedintheunitoperations.化学反应工程Inthisbookweareconcernedwiththechemicaltreatmentstepofaprocess.Economicallythismaybeaninc
4、onse’quential(不合理的)unit,perhapsasimplemixingtank.Frequently(常常),however,thechemicaltreatmentstepistheheartoftheprocess,thethingthatmakesorbreakstheprocesseconomically.化学反应工程Designofthereactorisnorou’tine(常规)matter,andmanyal’ternatives(二中择一,可供选择的办法)canb
5、eproposedforaprocess.Insearchingfortheoptimumitisnotjustthecostorthereactorthatmustbeminimized.Onedesignmayhavelowreactorcost,butthematerialsleavingtheunitmaybesuchthattheirtreatmentrequiresamuchhighercostthanal’ternativedesigns.Hence,theeconomicsofth
6、eoverallprocessmustbeconsidered.化学反应工程Reactordesignusesinformation,knowledge,andexperiencefromavarietyofareas:Thermody’namics(热力学)Chemicalki’netics(化学动力学)Fluidme’chanics(流体力学)Heattransfer,masstransfer(传热,传质)Eco’nomics(经济学)化学反应工程1.2Performanceequation:F
7、igure1.2Informationneededtopredictwhatareactorcando.化学反应工程ContactingPatternorhowmaterialsflowthroughandcontacteachotherinthereactor,howearlyorlatetheymix,theirclumpinessorstateofaggregation.Bytheirverynaturesomematerialsareveryclumpyforinstance,solids
8、andnoncoalescingliquiddroplets.Kineticsorhowfastthingshappen.Ifveryfast,thenequilibriumtellswhatwillleavethereactor.Ifnotsofast,thentherateofchemicalreaction,andmaybeheatandmasstransfertoo,willdeterminewhatwillhappen.化学反应工程Output=ƒ[inpu