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ID:57049879
大小:1.78 MB
页数:72页
时间:2020-07-28
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1、SurfacetensiondeterminationwiththemaximumdifferentialpressuremethodWangZengbao2012.11EXPERIMENT11.Experimentalpurposes(1)Mastertheprinciplesandmethodsofmaximumdifferentialpressuremethodforthedeterminationofsurfacetension.(2)Measurethesurfacetensionofn-butylalcohol
2、solution,andunderstandtheconceptofsurfacetensionandinfluencingfactors.(3)LearnGibbsequationanditsapplications.2.ExperimentalprinciplesPolyacrylamidecanbesynthesizedfromacrylamidetriggeredbyammoniumpersulfate:Polyacrylamidecanhydrolyzeinalkalinesolution,whichgenera
3、tespartiallyhydrolyzedpolyacrylamide:(1)—Theadditionalpressurewhichisformedwhenthewaterdropsdowninthewidemouthbottle—Thecurvatureradiusofthebubble—Thesurfacetension(N/m)2.ExperimentalprinciplesTherefore,atthesametemperature,oncetheΔP1,ΔP2aremeasured,andtheIFTofthe
4、liquid(water)whoseIFTisknownisfoundoutaccordingtothetemperaturetable,thenwecancalculatetheIFToftheunknownliquidfromtheformula。(1)2.Experimentalprinciples3.ApparatusandreagentsApparatusOnesetofdevicetomeasuretheIFTwiththemethodofmaximumdifferentialpressure,Bottle,r
5、ubberpipettebulb.ReagentsN-butylalcohol(analyticallypure),distilledwater.4.Experimentalprocedures(1)Washtheexternalcaseandthecapillarytubeoftheinstrumentusedtomeasuresurfacetensionwithlotion.Firstaddalittlelotionintotheexternalcase,rotationitinclinedsothatthelotio
6、ncancontactwiththeexternalcase(becarefulnottoletthelotionoutflowfromthesideofthetube).Theninsertthecapillarytubeandmaintaintheinclinedexternalcasestill.Rotatethecapillarytubetomakethelotioncontactwiththecapillarytube.Adsorbsomelotionwiththerubberpipettebulbtotheca
7、pillarytubetowashtheinsideofthecapillarytube.Pullthespentlotiontoitsoriginalbottleandwashtheexternalcaseandthecapillarytubewithrunningwaterfully.Finally,washtheexternalcaseandthecapillarytubewithdistilledwaterthreetimesrespectively.Thenwecangoonwiththefollowingexp
8、eriences.4.Experimentalprocedures(2)Putsomedistilledwaterintotheexternalcase(regardasliquidofknownIFT.SeeAppendixIItogetitssurfacetension).Insertthecapi
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