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时间:2020-03-25
《桂北沙子江花岗岩型铀矿床碳、氧、硫同位素特征及其成因意义.pdf》由会员上传分享,免费在线阅读,更多相关内容在行业资料-天天文库。
1、矿物岩石地球化学通报·研究成果·BulletinofMineralogy,PetrologyandGeochemistryV01.30No.1.Jan.2011桂北沙子江花岗岩型铀矿床碳、氧、硫同位素特征及其成因意义石少华,胡瑞忠,温汉捷,孙如良。,王加异,陈1.中国科学院地球化学研究所矿床地球化学国家重点实验室,贵阳550002;2.中国科学院研究生院,北京100049;3.广西310核地质大队,广西桂林541213摘要:测定了沙子江矿床及邻区矿床中与矿化密切有关的脉石矿物的稳定同位素,测知沙子江矿床方解石的8。C。值为~2.8%。~一l1.0%o,集中于~5Xo~9Xo;表明矿化剂C()主
2、要来自地幔,混有少量有机质和沉积碳酸盐物质。8”CPD与8OSMOW呈显著的负相关关系,暗示流体去气(CO。)是方解石沉淀的主控因素。铀沉淀为多因素耦合作用的结果;去气作用导致成矿流体中碳酸铀酰络离子的解体,有利于铀的沉淀。S作为还原剂对铀沉淀也起了很大的作用。沙子江矿床黄铁矿的8ScDT值为一18.36%0~~一8.92%o,可能主要来源于赋矿的花岗岩,而邻区孟公界和白毛冲矿床的6SDT值为一3O.51‰~~27.64‰,更多地继承了赋矿花岗岩源岩中沉积硫的特征。关键词:稳定同位素;方解石;黄铁矿;沙子江;苗儿山;桂北中图分类号:P619.14文献标识码:A文章编号:1007—2802(20
3、11)010088—09IsotopeCompositionsofCarbon,OxygenandSulfurintheShazijiangGranite-hostedUraniumoreDeposit,NorthernGuangxi,ChinaandTheirGeneticSignificanceSHIShao—hua一,HURui—zhong,WENHan—jie,SUNRu—liang。,WANGJia—sheng~,CHENHeng'。1.StateKeyLaboratoryof()rPDepositGeochemistry,InstituteofGeochemistry,Cbines
4、eAcademyofSciences.Guiyang550002,China;2.GraduateUniversityofChineseAcademyoSciences,Beijing100049,China;3.GuangxiGeologicalPartyNo.310,CNNC,Guilin,Guangxi541213,ChinaAbstract:Thestableisotopecompositionshavebeenrespectivelyanalyzedforcalcitesandpyrites,whicharecloselyrelatedtotheuraniummineralizati
5、oninShazijiangandinadjacenturaniumoredeposits.TheCPDBvaluesofthecalcitesfromtheShazijiangoredepositareintherangeof~2.8%0~一11.O‰,mostlyintherangeof一5‰~~90/00.Itindicatesthatthemineralizer,CO2,mainlyoriginatedfrommantleandthatonlyalittleoriginatedfromorganicmatterandsedimentarycarbonate.Thenegativecor
6、relationbetween6。CPDBand6。OsM()windicatesthatthedegassingofCO2isamajorcontrollingfactorforcalciteprecipitation,whileuraniumprecipitationmaybecontrolledbymultifactors.TheprocessofCO2degassingreducestheactivityofuranyl—carbonatecomplexes,thereforecausesuraniumprecipitation.S,oneofimportantreductionage
7、nts,alsocontributestoreductionofhexavalenturaniumandtouraniumprecipitation.ThemeasurementofSisotopeinpyritessuggeststhatthemostpartofsulfurintheShazijiangoredepositcamefromthehostgranite,theScDTvalues
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