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1、文献汇报硬膜板上催化作用下的自限性组装：用在锂硫电池中的中尺度石墨烯纳米壳汇报人：XXX目录SourceofthearticleResearchbackgroundAbstractIntroductionResultsandDiscussionConclusionsSourceofthearticleResearchbackgroundALi-Sbatteriy:hightheoreticalenergydensityof2600Wh/kg;S:naturallyabundant,economicallyeffective,andenvironmen
2、tallyfriendly;Grapheneandothernanostructuredcarbonmaterials:excellentconductivity,highspecificsurfacearea,accommodatelargevolumeexpansion;Issues:Li-Sbattery:poorcyclinglifeandrateperformanceS:largevolumetricexpansion，poorconductivityGraphene:couldn’tintegrateallthestructuralben
3、efits.TheconceptofHGNsmightbeapromisingstrategy,whichyetcallsfornewsyntheticmethodology.ResearchbackgroundB研究背景：中空纳米结构对提升电池性能有巨大优势，但传统方法难以制作研究目的：提升锂硫电池容量；提高电池稳定性解决方案：中空石墨烯纳米球壳结构，嵌入硫合成复合材料，作为电池正极AbstractHollownanostructures：表面积大；活性部位充分暴露；物质输运的动力学性能优良；表面通透性好Amesoscaleapproachtofa
4、bricategrapheneshells:催化剂作用下，在原位形成的纳米颗粒上实现纳米石墨烯的自限性组装Use:石墨烯纳米球壳作为基体与S复合，用作锂硫电池正极材料Properties:初始放电容量：1520mAh/g(0.1C)电流密度从0.1C提升至2.0C，70%容量保持1000次循环，每次衰减0.06%IntroductionHollownanostructures的优势Hollownanostructures的合成困境Hollownanostructures新的合成方案Hollownanostructures的优势Applications
5、：catalysis,adsorption,chemicalsensors,drug/genedelivery,andenergystorage/conversionsystemsHollownanocrystals：mesoscalehollowstructure,nanoscalequantumeffects,andatomic-scaleperiodicarrangementHollowgraphenenanoshells(HGNs)：favourableelectricalconductivity,goodsurfacefunctionali
6、ty,mechanical/chemicalstability,andbiocompatibilityHollownanostructures的合成困境Thetemplate-freeorself-templatingbottom-upapproaches：hardlyextendedtoHGNsynthesis；Atemplate-involvingtop-downstrategy：nocatalyticcapabilitytoregularlymanagethearrangementofcarbonatoms；Thus,controllables
7、ynthesisofHGNswithanengineeredhollowcavity,predeterminedlayernumber,smallsize,andhighlycrystallinefew-layergrapheneshellsisrarelyachievedHollownanostructures新的合成方案Amesoscalecatalyticself-limitedassemblyofhollowgraphenesphereswasproposed.Hardtemplatesandworkingcatalysts:insitufo
8、rmednickel-basedNPsCarbonsource:dodecylsulfate(DS)3Dme
