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1、SPECTROSCOPYTextbookandreferenceTextbookKennethARubinson&JudithFRubinson,ContemporaryInstrumentalAnalysis(现代仪器分析),科学出版社GaryD.Christian,AnalyticalChemistry,3rdEd.,JohnWiley&SonsReference武汉大学化学系编，仪器分析，高等教育出版社,2001于世林、李寅蔚主编，波谱分析法（全国轻化工类高等学校工业分析专业系列教材）重庆大学
2、出版社，1994年第2版西北师院、陕西师大、河北师大、上海师大、华中师大、河北师院编，有机分析教程陕西师大出版社，1987年第1版苏克曼、潘铁英、张玉兰，波谱解析法华东理工大学出版社，2002.8Chapter1Introduction1.SpectroscopyWhatisspectroscopy?Atypicalspectroscopyexperimentisextremelysimpletodescribe.Electromagneticradiationatsomefrequencyisal
3、lowedtointeractwiththesampleofinterest.Thensomepropertyofthatradiationismeasured,forexampletheamountabsorbed,diffracted,emitted,scattered,etc.Thefrequencyofradiationtobeusedisdeterminedbytheenergylevelsassociatedwiththepropertyofthesampleweareintereste
4、dinsuchaselectroniclevels,rotationalmotion,vibrationalmotion,etc.SpectroscopyincludesUV-Visspectrometry(Ultraviolet/visibleAbsorptionSpectrometry),IRspectrometry(InfraredSpectrometry),NMR(NuclearMagneticResonanceSpectroscopy)andMS(MassSpectrometry)Rapi
5、dandpreciseanalyticalmethodsfororganiccompoundsOnlyappliedforpurecompoundHyphenatedtechniques(GC-MS,GC-IR,LC-MS,LC-NMRetc.)formixtureanalysis2.ElectromagneticspectrumThewaveisdescribedwithwavelengthandfrequencyElectromagneticradiationpossessacertainamo
6、untofenergy.Theenergyofoneunitoftheradiation,thephoton,isrelatedtothefrequencybyE=hvEistheenergyofthephotoninergs,hisPlanck’sconstant,6.62x10-27ergsecTheelectromagneticspectrumTheelectromagneticspectrumisverywideandcoversradiationfromgamma-raystovisibl
7、elighttoradiofrequencywaves.Thevisibleregionisthatnarrowregionoftheelectromagneticspectrumtowhichthecolorsensorsinoureyesaresensitive.Thisregion,whichcoverswavelengthsof300nmto800nm,hasenergieswhicharejustbelowthecarbon-carbonbondstrength.g-raysg-raysa
8、realsoknowntocausetissuedamage.Theseareveryhighenergyelectromagneticwavesandareoftengeneratedduringdecayofradioactivematerials.Usuallysomedensemateriallikeleadisnecessarytokeepthemcontained.Asidefromtheiruseinradioactivelabellingexperim
