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1、SupportingInformationNMRChemicalShiftsofTraceImpurities:CommonLaboratorySolvents,Organics,andGasesinDeuteratedSolventsRelevanttotheOrganometallicChemist,122GregoryR.Fulmer,*AlexanderJ.M.Miller,NathanielH.Sherden,HugoE.3322Gottlieb,AbrahamNudelman,BrianM.Stoltz,JohnE
2、.Bercaw,andKarenI.1Goldberg1DepartmentofChemistry,UniversityofWashington,Box351700,Seattle,Washington98195-1700;2ArnoldandMabelBeckmanLaboratoriesofChemicalSynthesis,andCaltechCenterforCatalysisandChemicalSynthesis,DivisionofChemistryandChemicalEngineeringCalifornia
3、InstituteofTechnology,Pasadena,California91125;3DepartmentofChemistry,BarIlanUniversity,RamatGan52900,Israel.CorrectionsandComments........................................................................................................S21HNMRData(TableS1)...........
4、.................................................................................................S313CNMRData(TableS2)...........................................................................................................S5IndividualSolventTables–NMRDataSortedby
5、ChemicalShift(TablesS3–S26)............S7References..................................................................................................................................S19S1CorrectionsandCommentsInthepreparationofthismanuscript,severalerrorswerediscover
6、edinthe11originalpaperandarereportedherein.WhilecomparingtheHNMRspectraldata1obtainedintoluene-d8tothatinC6D6,itwasdiscoveredthattheHNMRchemicalshiftsforaceticacid(CH3),acetonitrile(CH3)andtert-butylalcohol(OH)inC6D6hadeachbeenmisreportedat1.55ppmintheoriginalpaper;
7、thevalueshavenowbeencorrectlylistedas1.52,0.58,and0.63ppm,respectively.Theoriginalpaper'sassignmentsforBHT'sC(3,5)andC(4)inC6D6,(CD3)2CO,(CD3)2SO,CD3CN,andCD3ODwerereversedandarenowcorrected.Theresonancesfor1,2-dimethoxyethane(CH2)in(CD3)2CO,siliconegrease(CH3)inCDC
8、l3,and2-propanol(CH3)inCD3ODhavebeencorrectedandarereportedas72.47,1.04,and1.15ppm,respectively.Noothersignificantdifferenceswerediscovere
