有机化学习题有机试题2

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1、温州大学考试试卷沪那竝载考试科目OrganicChemistry考试成绩考卷类型考试形式考试对象IGivecommon(orsystematic)namesforeachofthefollowingcompounds(5problems,10points):CH.CH.$蒙IIWriteastructuralformulaforeachofthefollowingcompounds(2points):(1)Drawastableconformationofc/5-decalin(十氢蔡)(2)Drawastableconformationofthefollowingcompound:I

2、IIAssignR/SorZ/Econfiguration(8points)RorSRorS4_Clz,HOOCCOOHOHRorS三Q?/f'COOHHOOCOHRorS(完成反应式，15problems,30points)Hg(OAc)2NaBH4H2ALindlarPdNaNH3⑴HOHHgSO4H2SO4+I—ClF1415ch2i2Cu(Zn)KOHCHC13VShowhowyoumightsynthesize•••fromthecompoundsindicatedandanyotherneeded(orrequired)reagents(合成，4problems,16po

3、ints)OH4VIProposea(detailed)mechanismthataccountsforthefollowingreaction(机理，H.CH2problems,8points)+HHC1ClVIIWriteaschemeforsimplechemicalteststhatwoulddistinguishfollowing5compounds(鉴另U，6points)VHIGiveaO3A—=ZnHOHHHstructureforAandB+HBKMnO4H+OH+2CO2IXChoosealetterthatdesignatesthecorrectorderofth

4、eassignedproperties:(选择，12points)A(1)>(4)>(2)>(3)B(2)>(4)>(1)>(3)C(3)X1)>(4)>(2)D(4)X2)>(3)>(1)3Theorderofstab订itiesof(1)(2)(3)(4)is(I)⑵A(1)X2)>(4)X3)B(2)X3)>(1)>(4)C(3)X2)>(4)>(1)D(4)X1)>(3)>(2)3Theorderofstab订itiesof(1)(2)(3)(4)is(1)(2)A(1)X3)>(2)>(4)C(3)X2)>(4)X1)4(3)(2)XI)>(3)X4)(4)X3)>(1)X2

5、)Theorderoftheactivities(反应活性)of(1)(2)(3)(4)inthe)reactionswithHC1is(（i）⑵(1)>(4)>(2)>(3)B(2)X3)>(1)>(4)(3)X1)>(2)>(4)D(4)>(1)>(3)X2)4Whichofthefollowingcompoundsisamesocompound?()AbcHh5c—pciCl―CH.H5Whichofthefollowingpairsofthestrueturesrepresentsthesamecompounds?()FOHBFClCH.OHBrBrCl卡FCH.OH(JOOH

6、HSHDH-—nh.7COOHCH.SH出二NH.睦OrganicchemistryIGiwecommon(0『sysiemaHC)namesforeachoffhefo=owingcompounds(5prob-emss3poiss)：11,-ffl噌6N帼莎口盡25,咄锻一溉耶6务34$琳壘2・5<浇4务闿亞孕-420一2釐CHnHaIIwric?asiruciundformu-aforeachofthefo=owingcompounds-2poimsx(1)Drawastab-econform目ionofc苹deca-in(+固牺)(2)DrawasraseconformaHo

7、nof〔hefollowingcompound-RorSC1,/\COOHHOOCOHb6CH二CHorS1前S后2两个都s3左R,右S4前S后R5前尺后S6与3题同3Z,8ZIVGivestructuralformulasfortheproductortheproductsofthereaction（完成反应式，15problems,30points）4O

8、5678,OH加对映体Hg(OAc)2bh3h2oOHfill对映体H2NH3(1)