制冷工程(食品的热力学特性)

制冷工程(食品的热力学特性)

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1、Chapter3: THERMALPROPERTIESOFFOODSNeededforheattransfercalculationsinequipmentdesignandestimationofprocesstimesforrefrigerating,freezing,heating,ordrying,Propertiesrequired:density,specificheat(显热),enthalpy,thermalconductivity.Freshfruitsandvegetables

2、alsogenerateheatviarespiration(呼吸)andlosemoistureviatranspiration(蒸发).1.FOODCONSTITUENTSCommonconstituents:water,protein,fat,carbohydrate,fibre,ash.2.THERMALPROPERTIESWellbehavedaboveinitialfreezingpoint.Varygreatlybelowduetocomplexfreezingprocesses.I

3、nitialfreezingpointsomewhatlowerthanpurewaterduotodissolvedsubstances(Fig.1).Atinitialfreezingpoint,aportionofwatercrystallises,remainingsolutionbecomesmoreconcentrated,thusreducingfreezingpointofunfrozenportion.Iceandwaterfractionsinfrozenfooddependo

4、ntemperature.Propertiesvarydramaticallywithtemperature.Propertiesaboveandbelowfreezingpointdrasticallydifferent.3.WATERCONTENTXwoWaterispredominantconstituent,inmostfoods,Xwosignificantlyinflencesproperties.Somevalues(%bymass):Cauliflower(波菜)91.9%;app

5、le83.9;salmon(鲑鱼)76.4;shrimp75.9;beef58.9;porkshoulder72.6;chicken66;wholeegg75.3;cheddarcheese36.8;strawberryicecream60;milk87.8;orangejuice89.4.INITIALFREEZINGPOINTtfNofoodsfreezecompletelysingleTbutoverarange.Foodswithhighsugarcontentorpackedinhigh

6、syrupconcentrationsmayneverbecompletelyfrozen,evenattypicalstorageT.Nodistinctfreezingpointforfoodsandbeverages.Initialfreezingpointindicatesstartofcrystallisation.Importantfordeterminingproperstorageconditionsandcalculationofthermophysicalproperties.

7、Forstorageoffreshfruitsandvegetables,Tmustbeaboveinitialfreezingpointtoavoidfreezingdamage.Asdrasticchangesinpropertieswhenfreez,initialfreezingpointisnecessarytoaccuratelymodelproperties.Somevalues(℃):(与前面一一对应)-0.8;-1.1;-2.2;-2.2;-1.7;-2.2;-2.8;-0.6;

8、-12.9;-5.6;-0.6;-0.4.5.ICEFRACTIONFooditems:water,dissolvedsolids,undissolvedsolids.Duringfreezing,someliquidwatercrystallises,solidsdissolvedinremainingliquidbecomeincreasinglymoreconcentrated,thusloweringfreezingtemperature.Miles(1974)equati

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