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1、©2000TobyBroomNopartofthisdocumentmaybereproducedormodifiedwithouttheexpresspermissionofTobyBroom.tbroom@totalise.co.ukAbbreviationFullNameSomeUsesStructuresAcAcetylVerycommonprotectingOgroupforalcoholsandRphenolsAdAdamantylProtectinggroupforacids,Rthiolsandalcoho
2、lsADAsymmetricdihydroxylationOOsO4+NMO+OHOOHHNClHONAEAsymmetricepoxidationSharplessConditionsEtO2CCO2EttBuOOH+Ti(OiPr)OHO4+HOHOHHOHAIBN?,?'-AzoisobutyronitrileMakesradicalsNCNNCNAldrithiol®2,2'-DipyridyldisulphideThiolatingReagentNSSNAllAllylProtectinggroupforphen
3、ols,acidsandalcoholsRespeciallycarbohydratesAllocAllyloxycarbonylProtectinggroupforRalcohols,aminesOO9-BBN9-BorabicyclononaneHinderedreductantBBNHBBMSBorane-methylsulphidecomplexReducingagentBH3SMe2BINAP2,2'-Bis(diphenylphosphino)-1,1'-LigandforRucatalyticbinapthy
4、lhydrogenationandBuchwaldreactionPPh2PPh2BINAPOPhosphinousacid,diphenyl-[1,1'-LigandforRucatalyticbinapthalene]-2-2'-diylesterhydrogenationOPPh2OPPh2Boctert-ButoxycarbonylProtectinggroupforaminesOespeciallypeptidesROBOMBenzyloxymethylProtectinggroupforRalcohols,ph
5、enols,acidsOandaminesBOPBenzotriazol-1-PeptidecouplingreagentNyloxytris(dimethylamino)phosphonNPNiumhexafluorophospateNNPF6N©2000TobyBroomNopartofthisdocumentmaybereproducedormodifiedwithouttheexpresspermissionofTobyBroom.tbroom@totalise.co.ukBOP-ClBis(2-oxo-3-Pep
6、tidecouplingreagentOoxazolidinyl)phosphinicchlorideNPNOOClOOBnBenzylProtectinggroupforRalcohols,phenols,acids,amides,aminesandcarbonylsBrBrosylate,ActivatinggroupforOBromobenzenesulphonylalcoholsBrSROBTAFBenzyltrimethylammoniumFluoratingreagentfluorideNFBumt-butox
7、ymethylProtectinggroupforROamines,alcoholsBzBenzoylProtectinggroupforthiols,ORalcohols,phenolsmuchmorestablethanacetateBHTtert-ButylhydroxytolueneStablizerforethersOHCANCericammoniumnitrateOxidisingagent(NH4)2[Ce(NO2)6]CBSCorey-Bashki-ShibatChiralreducingagentforP
8、hPhcarbonylsNO+BH3BHCbzorZBenzyloxycarbonylVerycommonprotectingRgroupforaminesespeciallyOOinaminoacidsCODCyclooctadieneLigandfortransitionmetalcatalysts
