In Situ Synthesis of Poly(copper phthalocyanine) Nanostructures for Organic Nanodevices

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1、CL-140095Received:February11,2014

2、Accepted:April3,2014

3、WebReleased:April12,2014InSituSynthesisofPoly(copperphthalocyanine)NanostructuresforOrganicNanodevicesFeiWang,*1JiningWang,1ZhijianChen,2XiaopengLiu,1LixinXiao,2LijunJiang,1BoQu,2ShumaoWang,1andQihuangGong2

4、1DepartmentofEnergyMaterialandTechnology,GeneralResearchInstituteforNon-FerrousMetals,Beijing100088,P.R.China2StateKeyLaboratoryforMesoscopicPhysics,DepartmentofPhysics,PekingUniversity,Beijing100871,P.R.China(E-mail:wangfeiaa110@pku.edu.cn)Thechallengeforwell-

5、organizedorganicnanostructuresisthatthematerialsareusuallyflexibleandamorphous,andthesynthesismethodstendtobetemplatemethod,etc.Here,weNwillgiveamuchdifferentwaytosynthesizenanostructuredNCCNNNpoly(CuPc).Poly(CuPc)wassynthesizedwithspecialsealedΔ+CuONCuNCVDmethod

6、.Bycontrollingthegrowthconditions,perpendic-NNularnanowiresandevenlydistributednanowebswereprepared.NCCNPoly(CuPc)showsstrongabsorptionpropertyinthevisible-Nlightregion,whichwillmakeitpotentiallyusefulinOPVs,1,2,4,5-tetrabenzonitrilephotocatalyticdevices,andoth

7、erphotoelectricdevices.Poly-CuPcFigure1.Thereactionschemeofpoly(CuPc).Organicphotoelectricdevices,forinstance,organicthin-filmtransistors(OTFTs),1organicphotovoltaics(OPVs),2andorganicTwomainwaysareappliedtosynthesizeCuPc:thephthaliclight-emittingdiodes(OLEDs),3

8、arewidelyresearchedfortheiranhydridemethodandthephthalonitrilemethod.Theformerisflexible,portable,andeasilymodifiedcharacteristics.Inscience,basedonsolventorthemeltingmethodusingphthalicanhydridethedevicesarebeingmadeincreasinglysmallersoastodiscoverandcoppersalt

9、asrawmaterials,andthelatterinvolvesthetheinterestingmicrocosmicworlds.Inorganicnanostructuresreactionoccurringinthetrichlorobenzeneornitrobenzeneseemeasiertosynthesizewithmethodssuchaschemicalvaporsolution,witho-phthalodinitrileandcuprouschlorideasrawdeposition

10、(CVD),4hydrothermalsynthesis,5andsolgelmethod.6materials.AfewstudiesreportedsimilarmethodstosynthesizeThechallengeforwell-organizedorganicnanostructuresisthatthepoly(copperp