Principles of Polymerization Fourth Edition Wiley

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1、PRINCIPLESOFPOLYMERIZATIONFourthEditionGEORGEODIANCollegeofStatenIslandCityUniversityofNewYorkStatenIsland,NewYorkAJOHNWILEY&SONS,INC.,PUBLICATIONCONTENTSPREFACExxiii1INTRODUCTION11-1TypesofPolymersandPolymerizations/11-1aPolymerCompositionandStructure/21-1bPolymeriza

2、tionMechanism/61-2NomenclatureofPolymers/91-2aNomenclatureBasedonSource/101-2bNomenclatureBasedonStructure(Non-IUPAC)/111-2cIUPACStructure-BasedNomenclatureSystem/111-2dTradeNamesandNonnames/161-3Linear,Branched,andCrosslinkedPolymers/171-4MolecularWeight/191-5Physica

3、lState/241-5aCrystallineandAmorphousBehavior/241-5bDeterminantsofPolymerCrystallinity/271-5cThermalTransitions/291-6ApplicationsofPolymers/321-6aMechanicalProperties/321-6bElastomers,Fibers,andPlastics/35References/36vviCONTENTS2STEPPOLYMERIZATION392-1ReactivityofFunc

4、tionalGroups/402-1aBasisforAnalysisofPolymerizationKinetics/402-1bExperimentalEvidence/412-1cTheoreticalConsiderations/432-1dEquivalenceofGroupsinBifunctionalReactants/442-2KineticsofStepPolymerization/442-2aSelf-CatalyzedPolymerization/462-2a-1ExperimentalObservation

5、s/472-2a-2ReasonsforNonlinearityinThird-OrderPlot/482-2a-3MolecularWeightofPolymer/502-2bExternalCatalysisofPolymerization/512-2cStepPolymerizationsOtherthanPolyesterification:CatalyzedversusUncatalyzed/532-2dNonequivalenceofFunctionalGroupsinPolyfunctionalReagents/542

6、-2d-1ExamplesofNonequivalence/542-2d-2Kinetics/572-3AccessibilityofFunctionalGroups/632-4EquilibriumConsiderations/652-4aClosedSystem/652-4bOpen,DrivenSystem/672-4cKineticsofReversiblePolymerization/692-5CyclizationversusLinearPolymerization/692-5aPossibleCyclizationR

7、eactions/692-5bCyclizationTendencyversusRingSize/702-5cReactionConditions/722-5dThermodynamicversusKineticControl/732-5eOtherConsiderations/742-6MolecularWeightControlinLinearPolymerization/742-6aNeedforStoichiometricControl/742-6bQuantitativeAspects/752-6cKineticsofN

8、onstoichiometricPolymerization/792-7MolecularWeightDistributioninLinearPolymerization/802-7aDerivationofSizeDistributions/80