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1、有机化学A1主讲教师:李艳梅教授清华大学化学系E-mail:liym@tsinghua.edu.cnURL:http://chem.tsinghua.edu.cn/liymChapter1Introduction第一章绪论OrganicChemistryA(1)ByProf.LiYan-MeiTsinghuaUniversityContentPartIOrganiccompoundsandorganicchemistry------History第一部分有机化合物与有机化学--历史简介PartII
2、FundamentalKnowledge第二部分基础知识●Structure,reaction&Classification●Formulas●Nomenclature●NMR,IR,UV&MS1.Organiccompoundsandorganicchemistry第一部分有机化合物和有机化学1.1Introductionandabriefhistory有机化学历史简介1.2Characteroforganiccompound有机化合物的特性1.3Researchfieldsinorganicc
3、hemistry有机化学研究领域1.4Themethodstostudyorganicchemistryandhowtolearnorganicchemistry有机化学研究方法及如何学习有机化学课程1.1Introductionandabriefhistory有机化学历史简介有机化学?有机化合物?Starch(淀粉)CmHnmvaluearound8Gasoline(汽油)SalicylicacidAcetylsalicylicacid乙酰水杨酸(阿斯匹林)Formalinaqueoussolu
4、tionofformaldehydeOrganicChemistryintheHistoryTomakehumanbodyintoamummy,formalinwasoftenemployedinancientEgypt.甲醛古埃及人利用有机化合物处理尸体WinewasinventedbeforeXiadynasty.ByZhoudynasty,winehasbecomeveryimportantinsacrificeevents.制酒«周礼»Vinegarproductionhasalready
5、becomeanexpecttechnologybyZhoudynasty.制醋DyeinghasbecomeamimportantindustrybeforeZhoudynasty.染色茜草ThedemiseofvitalismInancientages,mixturesoforganiccompoundswereabstractedfromnaturalproducts.Chinesetraditionaldrug,dye,andperfumeareofthiskind.Bythe18thce
6、ntury,somepureorganiccompoundswereobtained.Turtricacidwasobtainedfromgrapejuice,citricacidwasabstractedfromlemonjuice,andureawaspurifiedfromurine.1828,preparationofureafrominorganiccompoundsindicatesthedemiseof“vitalism”.In1806,famouschemist,Berzelius
7、J.firstusedtheword“organicchemistry”,andstates,organiccompoundscouldnotbeproducedwithout“vitalforce(生命力)”Thefactthatorganiccompoundscouldbeobtainedfrominorganiccompoundswithoutthehelpoforganismwasnotacceptedforalongtime.In1845aceticacidandin1854esterw
8、ereseparatelysynthesizedfrominorganiccompounds,indicatingthefinaldemiseofvitalism.兴趣阅读:Seeappendixfile0001:LetterbetweenWöhlerandhisadviser,Berzelius.Seeappendixfile0002:Wöhler’spaperonsynthesisofureaSeeappendixfile0003:Problemsandanswersonthe