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1、Chem.Rev.2005,105,1025-11021025ChemistryandPropertiesofNanocrystalsofDifferentShapesClemensBurda,*,†,‡XiaoboChen,†RadhaNarayanan,§andMostafaA.El-Sayed*,§CenterforChemicalDynamicsandNanomaterialsResearch,DepartmentofChemistry,CaseWesternReserveUniversitysMillis
2、2258,Cleveland,Ohio44106,andLaserDynamicsLaboratory,SchoolofChemistryandBiochemistry,GeorgiaInstituteofTechnology,Atlanta,Georgia30332-0400ReceivedJuly22,2004Contents6.1.4.Electron-PhononRelaxationinGold1064Nanoparticles1.GeneralIntroductionandComments10256.1.
3、5.ShapeandSizeDependenceonthe10652.PreparationofNanostructuresofDifferent1027Electron-PhononRelaxationRateShapes6.1.6.PumpPowerDependenceofthe10662.1.Introduction:NucleationandParticleGrowth1027Electron-PhononRelaxationRate2.2.PreparationMethods10286.2.Nonradi
4、ativeRelaxationinSemiconductor10662.2.1.SolProcess1028NanostructuredSystems2.2.2.Micelles10316.2.1.II-VISemiconductorSystems10672.2.3.Sol-GelProcess10346.2.2.I-VIISemiconductorSystems10742.2.4.ChemicalPrecipitation10346.2.3.III-VSemiconductorSystems10742.2.5.H
5、ydrothermalSynthesis10366.2.4.GroupIVSemiconductorSystems10742.2.6.Pyrolysis10366.2.5.MetalOxidesSystems10752.2.7.VaporDeposition10386.2.6.OtherSystems10752.3.GrowthMechanismofNanostructuresof10406.3.HotElectronsandLatticeTemperaturesin1076DifferentShapesNanop
6、articles2.3.1.EffectofMonomerConcentrationonthe10406.4.PhononBottleneck1078ShapeoftheSemiconductorQDs6.5.QuantizedAugerRates10792.3.2.Vapor-Liquid-SolidGrowthforNanowire10416.6.TrappingDynamics1079byCVDandPVDMethods7.Nanocatalysis10812.3.3.Light-InducedShapeCh
7、angeMechanism10427.1.Introduction1081ofMetalNanorods7.2.HomogeneousCatalysis10813.SurfaceChemicalModificationofNanoparticles10427.2.1.ChemicalReactionsCatalyzedUsing10834.AssemblyofNanoparticles1042ColloidalTransitionMetalNanocatalysts5.Optical,Thermal,andElec
8、tricalPropertiesof10477.3.HeterogeneousCatalysisonSupport1086ParticlesofDifferentSizesandShapes7.3.1.LithographicallyFabricatedSupported10875.1.SemiconductorNanoparticles1047Transi
