Nitration and aromatic reactivity - Hoggett%2c Moodie%2c Penton %26 Schofield

《Nitration and aromatic reactivity - Hoggett%2c Moodie%2c Penton %26 Schofield》由会员上传分享，免费在线阅读，更多相关内容在学术论文-天天文库。

1、Nitrationand••aromaticreactivityJ.G.HOGGETT,R.B.MOODIEjJ.R.PENTON&K.SCHOFIELDDepartmentofChemistryUniversityofExeterCAMBRIDGEATTHEUNIVERSITYPRESS-1971PublishedbytheSyndicsoftheCambridgeUniversityPressBentleyHouse,200EustonRoad,LondonNWI2DBAmericanBranch:32East57thStreetNewYork,N.Y.10022©Cambri

2、dgeUniversityPress1971LibraryofCongressCatalogueCardNumber:76-138374ISBN:o52108029°PrintedinGreatBritainattheUniversityPrintingHouse,Cambridge(BrookeCrutchley,UniversityPrinter)ContentsPrefacepagevii1Introductionii.iTheimportanceofnitrationi1.2Nitratingagentsi1.3Nitrationandthedevelopmentofthe

3、oreticalorganic3chemistryReferences42Nitratingsystems:A.mineralacids62.1Introduction62.2Nitrationinconcentratedandaqueousnitricacid62.3Nitrationinconcentratedsolutionsofsulphuricacid132.4Nitrationinaqueoussolutionsofmineralacids192.5Nitrationsattheencounterrateinaqueoussulphuricand27perchloric

4、acidsReferences293Nitratingsystems:B.inertorganicsolvents323.1Thestateofnitricacidininertorganicsolvents323.2Thekineticsofnitration323.3Nitrationattheencounterrateininertorganicsolvents46References4.8ji4Nitratingsystems:c.miscellaneous504.1Introduction504.2Nitrationwithdinitrogenpentoxide514.3

5、Nitrationvianitrosation544.4Nitrationswithsolutionsofnitroniumsaltsinorganic61solventsReferences735Nitratingsystems:D.benzoylnitrateandsystemsformed76fromnitricacidandaceticanhydride5.1Introduction765.2Benzoylnitrate775.3Systemsformedfromnitricacidandaceticanhydride79References105Contents6Thep

6、rocessofsubstitutionPageIO76.1Introduction1076.2Nitrationswithnitroniumions:thegeneralcase1086.3Nitrations-withnitroniumions:specialcases1146.4Nitrationwithdinitrogenpentoxide1166.5Theroleofn-complexes117References1207Nitrationandaromaticreactivity:A.Thetheoretical122background7.1Introduction1

7、227.2Theoriesrelatingstructureandreactivity1257.3Quantitativecorrelationsofsubstituenteffects136References1438Nitrationandaromaticreactivity:B.Thenitrationofbases1468.1Introduction1468.2Recognitionofthereactingspecies147References1619Ni