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1、OrganosiliconCompoundsTamejiroHiyama1·EijiShirakawa21DepartmentofMaterialChemistry,GraduateSchoolofEngineering,KyotoUniversity,Sakyo-ku,Kyoto606-8501,JapanE-mail:thiyama@npc05.kuic.kyoto-u.ac.jp2JapanAdvancedInstituteofScienceandTechnology,Asahidai,Tatsunokuchi,Ishikawa923-1292,JapanE
2、-mail:shira@jaist.ac.jpOraganosiliconcompoundsreactwithawidevarietyoforganicelectrophilesinthepresenceofapalladiumcatalystandaLewisbaseactivatorsuchasafluorideorhydroxyiontogivethecorrespondingcoupledproducts.Thereactionisapplicabletosynthesisofdiynes,enynes,arylacetylenes,alkenylaren
3、es,biaryls,allylarenesandalkylarenesinadditionto1,3-,1,4-and1,5-dieneswithtoleranceforvariousfunctionalgroups.Keywords.Palladiumcatalyst,Organosilicate,Fluorideion,Functionalgrouptolerance1Introduction...............................622VariousCarbon–CarbonCouplingReactions............6
4、42.1CouplingbetweenspCarbonCenters.................652.1.1Diyne...................................652.2Couplingbetweenspandsp2CarbonCenters............652.2.1Enyne..................................652.2.2Arylacetylene..............................662.3Couplingbetweensp2CarbonCenters..
5、..............672.3.1Alkenylarene..............................672.3.21,3-Diene................................712.3.3Biaryl...................................722.4Couplingbetweensp2andsp3CarbonCenters............762.4.1Allylarene................................762.4.2Alkylarene......
6、..........................792.4.31,4-Diene................................812.5Couplingbetweensp3CarbonCenters................822.6CarbonylativeCoupling........................823SyntheticApplications.........................834References................................84TopicsinCurre
7、ntChemistry,Vol.219©Springer-VerlagBerlinHeidelberg200262T.Hiyama·E.ShirakawaAbbreviationsdbadibenzylideneacetoneDMFN,N-dimethylformamideDMIN,N-dimethylimidazolidinonedppb1,4-bis(diphenylphosphino)butanedppe1,2-bis(diphenylphosphino)ethanedppp1,3-bis(diphenylphosphino)propaneeeenantio
8、meric
