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1、英文摘要Investigationandappficationofnanofibersasthematerialusingforseparationandconcentration.AbstractSansitive.preciseandaccuratemethodologiesm-efondamantaltoolsinliresciencesresearch.However,thedevelopmentofbioanalyticalproceduresis∞eofthemostformidablechallengesfaced
2、bytheresearchers.Typicalsamples∞11101tandfflorecomplexmLxlxtres,inwhichtheanalytesofinterestc%bepresentinreducedamounts.Despitethegreattcchnolo舀caladvances,mostaaab瞳icalinsa-umantscannothandlesamplematricesdirectlyan正asaresult,asample-preparationstepiscommonlyin仃oduc
3、ecLFororganictraceanalysis,thisstopmainlycomprisesextractinns,whichSarVetoisolatecompoundsofinterestfromasamplema心.Ultimately,theconcenWatinaoftargetcorapoundsisenhanoed(enrichment)andtl’epresenceofmatrixcomponentsisrcd._,wxxl(samplecleanup).Solid-phasea(t阿c6∞hasbeen
4、widelyusedfbri船highselectivityandgoodreproducibilityforsamplepreparation.However,conventionalsolid-phase£x'a'actionislaborintensive,useoforganiesolventantitimeconsuming.Onepotentialtechniqueforsolid-phaseextractiontOincreaseⅡ∞adsorptioneffectofthebedisl№ofsubstancesi
5、nnartometerorderasabsorbents.Althoughthesubmicrometer-sizedparticlesⅫgreatlyincreasethesurfacearea,impracticallyhighpressuresisn硎fortheliquidflOW,whichlimitstheapplication.However,nanomcterfibersbethecandidatesformaysorbents.Eleclxospanpolymersubmicrometerfibershaved
6、iametersinthenanometgTr'缸lgeandarearbitrarilylong.Iftheyarcp∽kedintothecolumn,thepressuredropwouldbelowerthanthecolumnpackedwithn跏me缸particles.Based锄1hishypothesis,itWaSrevealedtD∞thatnanofibersmaybehave印随enalytjcalpotemla
7、∞∞effectivesolid-phaseextractionsorbentforth
8、ealialyt鹤inthesamples.Itisas.‘Rulledthalthehugesurfacesofailumbcroffinenanofibersarecffectiveinadsorptionoftbeanalytes.beneficialtoincM日setheeffecincyofextraction.BasedOnthishypothesis。thenanofibersweremanufacturedbyelcccrospinning,andwereusedassolidphasesorbents.Com
9、p删totheconventionalsolid-phaseex=n-action,themethodismoreeffective,fast,andinlowcost,without∞iIIgpoisonousorganicsolvent.11kinvesti