乙醇环己烷二组分系统废热沸点组成相图

乙醇环己烷二组分系统废热沸点组成相图

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时间:2019-05-11

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1、P.实验名称:__________________________姓名:____________学号:______________五、实验数据记录与处理:室温:25.5℃大气压:102.45kPa阿贝折光仪测量温度:30.0℃温良温度计露颈读数:53.7℃30℃100%乙醇折光率:1.357030℃100%环己烷折光率为1.4202表1环己烷(1)-乙醇(2)液态混合物的气-液平衡数据(一)环混合辅校正气相折射率校正液相折射率校正己物沸助后沸前气前液烷点温点12Average相组12Average相组加/℃度/℃成成入计量/℃/mL078.2728.678.691.35721.3571

2、1.35720.0021.35711.35721.35720.002175.8028.076.201.36491.36481.36480.0891.35931.35941.35940.028370.9128.071.271.38721.38721.38730.3741.36571.36561.36560.098368.1830.068.501.39101.39121.39110.4351.37171.37111.37140.165566.4027.666.731.39351.39401.39380.4791.37801.37801.37800.274565.6226.265.951.3

3、9631.39601.39620.5181.38371.38381.38380.326765.2027.565.521.39641.39671.39660.5251.38951.39011.38980.415765.1027.365.421.39731.39781.39760.5431.39431.39421.39420.485765.0025.265.331.39791.39821.39800.5501.39711.39721.39720.536464.9028.565.201.39841.39861.39850.5591.39901.39961.39930.572注:加入乙醇的量为

4、20mL表2环己烷(1)-乙醇(2)液态混合物的气-液平衡数据(二)乙混合辅助校正气相折射率气相液相折射率液相醇物沸温度后沸组成组成加点/℃计点/℃12Average12Average入/℃量/mL080.6024.981.071.42071.42091.42081.0001.42061.42101.42081.0000.277.0024.777.441.41381.41371.41380.8751.42031.42021.42031.0000.373.2524.873.661.40611.40651.40630.7021.41891.41951.41920.9770.568.2924

5、.268.661.39971.40021.40000.5851.41771.41791.41780.946166.1624.266.511.39911.39941.39930.5711.41441.41001.41220.866165.5126.265.841.39841.39901.39870.5621.41091.41141.41120.801365.0925.565.421.39821.39831.39830.5531.40601.40631.40620.698365.0024.865.341.39761.39831.39800.5501.40071.40111.40090.60

6、0注:加入环己烷的量为25Ml表3折光率校正:折光率实验值理论值乙醇1.35721.3570环己烷1.42081.4202表4制图数据得出x=实验值,y=校正值之后的校正方程:y=0.99371x+0.00834,数据校正如下:沸点校正后气相校正后液相沸点校正气相组校正后液相组(℃)折射率组成折射率组成(℃)后折成折射率成左右射率78.691.35700.0001.35700.00281.071.42021.0001.42021.00076.201.36460.0871.35920.02877.441.41320.8751.41970.98871.271.38690.3701.3654

7、0.09873.661.40580.7021.41860.96368.501.39070.4281.37110.16568.661.39950.5851.41720.93266.731.39340.4721.37770.27466.511.39880.5711.41170.81265.951.39580.5121.38340.32665.841.39820.5621.41070.79165.521.39620.5181.38940.41565.

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